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Excellent electrocatalytic activity of benzil for direct reduction of CO2 as well as indirect reduction of pyridine:A kinetic view of the electrocarboxylation process 被引量:1
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作者 kobra ghobadi Hamid R.Zare +1 位作者 Hossein Khoshro Abbas A.Jafari 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2017年第3期569-573,共5页
Benzil,1,2-diphenylethane-1,2-dione, was used as an excellent electrocatalyst for reduction of carbon dioxide, CO. The reduction overpotential of COwas reduced about 900 m V in the presence of a benzil mediator. The c... Benzil,1,2-diphenylethane-1,2-dione, was used as an excellent electrocatalyst for reduction of carbon dioxide, CO. The reduction overpotential of COwas reduced about 900 m V in the presence of a benzil mediator. The chemical reaction of the product of the electrocatalytic reduction of CO,(activated CO,CO) with pyridine at a glassy carbon electrode, GCE, surface and in an acetonitrile-ButNClOsolution was investigated by cyclic voltammetry, chronoamperometry and controlled potential coulometry.By chronoamperometry, the catalytic rate constant, k, for the electron transfer between benzil and COwas obtained as 8.1 ± 0.4 Ms. The results indicate that pyridine has a strong interaction with the activated CO. The coulometry method was used to obtain the product of the pyridine chemical reaction with CO. The spectral characterizations of FTIR,H andC NMR of the coulometry experiment product proved that the pyridine anion radical, Py, was carboxylated by CO, and isonicotinic acid is the final major product. 展开更多
关键词 Carbon dioxide BENZIL Pyridine electrocarboxylation Catalytic rate constant Isonicotinic acid
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