A new metal-organic framework(MOF) based on metal clusters as secondary building units(SBU),has been synthesized and structurally characterized.The reported MOF presents an interesting 8-connected self-penetrating...A new metal-organic framework(MOF) based on metal clusters as secondary building units(SBU),has been synthesized and structurally characterized.The reported MOF presents an interesting 8-connected self-penetrating coordination network based on dinuclear cadmium cluster with a 4^(24)·5·6~3 topology. Moreover,the thermal stability and luminescence property of this compound have been investigated.展开更多
基金supported by the National Science Foundation of China(No.51073079)the Natural Science Fund of Tianjin,China (No.10JCZDJC22100)the Fundamental Research Funds for the Central Universities
文摘A new metal-organic framework(MOF) based on metal clusters as secondary building units(SBU),has been synthesized and structurally characterized.The reported MOF presents an interesting 8-connected self-penetrating coordination network based on dinuclear cadmium cluster with a 4^(24)·5·6~3 topology. Moreover,the thermal stability and luminescence property of this compound have been investigated.