The effect of grain morphology and precipitates on mechanical properties and corrosion behavior of two commercial 7 N01 alloys was studied using transmission electron microscopy(TEM) and scanning electron microscopy(S...The effect of grain morphology and precipitates on mechanical properties and corrosion behavior of two commercial 7 N01 alloys was studied using transmission electron microscopy(TEM) and scanning electron microscopy(SEM) equipped with electron backscatter diffraction(EBSD). Results showed that the recrystallization degree of the outer surface of 7 N01-I alloy was lower than that of 7 N01-II alloy. The main strengthening precipitates of two alloys were mainly η’ phases. The grain boundary precipitates(GBPs) of 7 N01-I alloy distributed discontinuously, while those of 7 N01-II alloy distributed continuously. The strength of two 7 N01 alloys was similar, but the maximum corrosion depth of 7 N01-I alloy was less than that of 7 N01-II alloy, because the discontinuous GBPs and the lower recrystallization degree of outer surface of 7 N01-I alloy were favorable for improving corrosion behavior. Different models of strengthening mechanism were discussed, and the corrosion behavior was correlated with microstructure.展开更多
The effect of various retrogression and re-aging(RRA)treatments on mechanical properties and corrosion behavior of a new type Al-Zn-Mg-Cu-Er-Zr alloy was investigated by microhardness testing,tensile testing,intergran...The effect of various retrogression and re-aging(RRA)treatments on mechanical properties and corrosion behavior of a new type Al-Zn-Mg-Cu-Er-Zr alloy was investigated by microhardness testing,tensile testing,intergranular corrosion(IGC)and exfoliation corrosion(EXCO)testing.The results show that the RRA treatment can effectively improve the IGC and EXCO resistance with less strength sacrificing because the grain interior precipitates and the grain boundary precipitates are similar to that of T6 temper and T73 temper.Meanwhile,as the microhardness of the retrogressed alloy reaches the peak value during the retrogression at 170℃,the corresponding RRA-treated alloy possesses the better strength,but the corrosion resistance is poor in comparison with that of the retrogression at 190℃.The optimal combination of strength,IGC and EXCO resistance is obtained after retrogression at 180℃for 60 min.Moreover,for different heat treatment tempers,the corresponding micros true tural evolution of the precipitates including Al_(3)(Er,Zr)particles was also discussed in detail.展开更多
Al-Mg-Zn-Er-Zr alloy was compressed in temperature range from 300 to 500℃to investigate the microstructure evolution.Molecular dynamics simulations were used to study the mechanical behavior and dislocation evolution...Al-Mg-Zn-Er-Zr alloy was compressed in temperature range from 300 to 500℃to investigate the microstructure evolution.Molecular dynamics simulations were used to study the mechanical behavior and dislocation evolution.The results showed that mobile dislocations are widely distributed in alloys and make important contributions to coordinate compressive deformation.The sessile dislocations hinder the deformation,and the content is about 1/20 of that of mobile dislocations.Continuous dynamic recrystallization(CDRX)is considered to be the main recrystallization mechanism.The accumulation of dislocations can provide element diffusion channels and driving force forτ(Mg_(32)[Al,Zn]_(49))phase precipitation,resulting in the forced precipitation of discontinuousτphase to replace the continuousβphase(Al_(3)Mg_(2)),which reduces the corrosion potential,resulting in increased corrosion resistance.展开更多
基金the National Key Research and Development Program of China (Nos. 2021YFB3704204, 2021YFB3700902, 2021YFB3704205)Beijing Natural Science Foundation, China (No. 2202009)+2 种基金the National Natural Science Foundation of China (No. 51621003)Basic Research Program of Jiangsu Province (Natural Science Foundation), China (No. BK20191148)Beijing Lab Project for Modern Transportation Metallic Materials and Processing Technology and Jiangsu Key Laboratory for Clad Materials, China (No. BM2014006)。
文摘The effect of grain morphology and precipitates on mechanical properties and corrosion behavior of two commercial 7 N01 alloys was studied using transmission electron microscopy(TEM) and scanning electron microscopy(SEM) equipped with electron backscatter diffraction(EBSD). Results showed that the recrystallization degree of the outer surface of 7 N01-I alloy was lower than that of 7 N01-II alloy. The main strengthening precipitates of two alloys were mainly η’ phases. The grain boundary precipitates(GBPs) of 7 N01-I alloy distributed discontinuously, while those of 7 N01-II alloy distributed continuously. The strength of two 7 N01 alloys was similar, but the maximum corrosion depth of 7 N01-I alloy was less than that of 7 N01-II alloy, because the discontinuous GBPs and the lower recrystallization degree of outer surface of 7 N01-I alloy were favorable for improving corrosion behavior. Different models of strengthening mechanism were discussed, and the corrosion behavior was correlated with microstructure.
基金financially supported by the National Key Basic Research&Development Plan Project(No.2012CB619503)。
文摘The effect of various retrogression and re-aging(RRA)treatments on mechanical properties and corrosion behavior of a new type Al-Zn-Mg-Cu-Er-Zr alloy was investigated by microhardness testing,tensile testing,intergranular corrosion(IGC)and exfoliation corrosion(EXCO)testing.The results show that the RRA treatment can effectively improve the IGC and EXCO resistance with less strength sacrificing because the grain interior precipitates and the grain boundary precipitates are similar to that of T6 temper and T73 temper.Meanwhile,as the microhardness of the retrogressed alloy reaches the peak value during the retrogression at 170℃,the corresponding RRA-treated alloy possesses the better strength,but the corrosion resistance is poor in comparison with that of the retrogression at 190℃.The optimal combination of strength,IGC and EXCO resistance is obtained after retrogression at 180℃for 60 min.Moreover,for different heat treatment tempers,the corresponding micros true tural evolution of the precipitates including Al_(3)(Er,Zr)particles was also discussed in detail.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB 3704202)the General Program of Science and Technology Development Project of Beijing Municipal Education Commission(No.KM 202110005010)the Innovative Research Group Project of the National Natural Science Fund(No.51621003)。
文摘Al-Mg-Zn-Er-Zr alloy was compressed in temperature range from 300 to 500℃to investigate the microstructure evolution.Molecular dynamics simulations were used to study the mechanical behavior and dislocation evolution.The results showed that mobile dislocations are widely distributed in alloys and make important contributions to coordinate compressive deformation.The sessile dislocations hinder the deformation,and the content is about 1/20 of that of mobile dislocations.Continuous dynamic recrystallization(CDRX)is considered to be the main recrystallization mechanism.The accumulation of dislocations can provide element diffusion channels and driving force forτ(Mg_(32)[Al,Zn]_(49))phase precipitation,resulting in the forced precipitation of discontinuousτphase to replace the continuousβphase(Al_(3)Mg_(2)),which reduces the corrosion potential,resulting in increased corrosion resistance.