High speed, high resolution infrared thermography, as a non contact, full field, and nondestructive technique, was used to study the temperature variations of a cobalt based ULTIMET alloy subjected to cyclic fatigue. ...High speed, high resolution infrared thermography, as a non contact, full field, and nondestructive technique, was used to study the temperature variations of a cobalt based ULTIMET alloy subjected to cyclic fatigue. During each fatigue cycle, the temperature oscillations, which were due to the thermal elastic plastic effects, were observed and related to stress-strain analyses. The change of temperature during fatigue was utilized to reveal the accumulation of fatigue damage. A constitutive model was developed for predicting the thermal and mechanical responses of ULTIMET alloy subjected to cyclic deformation. The model was constructed in light of internal state variables, which were developed to characterize the inelastic strain of the material during cyclic loading. The predicted stress-strain and temperature responses were found to be in good agreement with the experimental results.展开更多
Nanostructured silver was obtained by potentiostatic electrolysis.The effects of ionized surfactant(sodium dodecanesulphonate)and the substrate(Cu and Ti)on the morphology of depositions were investigated.It is found ...Nanostructured silver was obtained by potentiostatic electrolysis.The effects of ionized surfactant(sodium dodecanesulphonate)and the substrate(Cu and Ti)on the morphology of depositions were investigated.It is found that morphologies of silver nanostructures can be simply controlled via change of the substrate.Spherical Ag nanoparticles with narrow size distribution were obtained by electrodeposition in Ag NO3-SDS aqueous solution on copper substrate.In the case of titanium substrate,silver dendrite structures were obtained.Despite of different morphologies,XRD and TEM results showed that the as-prepared samples belong to face-centered cubic silver structure with good crystallinity.The formation mechanism of different silver nanostructures was discussed.展开更多
A simultaneous high-resolution x-ray backlighting and self-emission imaging method for laser-produced plasma diagnostics is developed in which two Kirkpatrick–Baez imaging channels for high-energy and low-energy diag...A simultaneous high-resolution x-ray backlighting and self-emission imaging method for laser-produced plasma diagnostics is developed in which two Kirkpatrick–Baez imaging channels for high-energy and low-energy diagnostics are constructed using a combination of multilayer mirrors in near-coaxial form.By using a streak or framing camera placed on the image plane,both backlit and self-emission images of a laserproduced plasma with high spatial and temporal resolution can be obtained simultaneously in a single shot.This paper describes the details of the method with regard to its optical and multilayer design,assembly,and alignment method.In addition,x-ray imaging results with a spatial resolution better than 5μm in the laboratory and experimental results with imploding capsules in the SG-III prototype laser facility are presented.展开更多
To accelerate the exploration,screening,and discovery of structural high-entropy alloys with targeted properties,the newly developed High-Throughput Hot-Isostatic-Pressing based Micro-Synthesis Approach(HT-HIP-MSA)is ...To accelerate the exploration,screening,and discovery of structural high-entropy alloys with targeted properties,the newly developed High-Throughput Hot-Isostatic-Pressing based Micro-Synthesis Approach(HT-HIP-MSA)is employed to efficiently synthesize and characterize 85 combinatorial alloys in a 13-principal element alloying space.These Co Cr Fe Ni-based high entropy alloys span 1 quaternary,9 quinary,and 36 senary alloy systems,and their composition-structure-property relationships are characterized and analyzed experimentally and computationally.From the single-phase FCC CoCrFeNi alloy base,with Mn,Cu,Ti,Nb,Ta,Mo,W,Al,and Si as principal element alloying additions,we find(1)the extended Mn solubility in the single-phase FCC CoCrFeNi-Mn_(x) alloys,(2)the destabilizing behavior for most of the quinary and senary alloys,and(3)the distinctive solid-solution-strengthening effects in the alloys.In combining the computational methods,the HT-HIP-MSA can be systematic and economic to explore and refine the compositions,structures,and properties of structural high-entropy alloys.展开更多
Metallic glasses(MGs)appear as promising anti-corrosion coating materials due to their microstructural and physicochemical advantages.Herein,we proposed magnetron sputtered NiNb thin film MG coatings(MGCs)with differe...Metallic glasses(MGs)appear as promising anti-corrosion coating materials due to their microstructural and physicochemical advantages.Herein,we proposed magnetron sputtered NiNb thin film MG coatings(MGCs)with different structures and compositions for corrosion protection of 316 stainless steel in an aggressive saline environment.The properties of monolayered Ni_(50)Nb_(50) and Ni_(60)Nb_(40),as well as the multilayered Ni_(50)Nb_(50)/Ni_(60)Nb_(40)(at.%)MGCs,were characterized in terms of morphology and microstructural properties,as well as the anticorrosion behavior.All the NiNb MGCs presented compact structure and the monolayered coatings exhibited preferable adhesion properties in comparison with the multilayered coating.The electrochemical tests and XPS results imply that the monolayered Ni_(50)Nb_(50) MGC with high Nb content resisted corrosion mainly due to the formation of stable passive film that contained abundant Nb_(2)O_(5) species,whereas the Ni_(60)Nb_(40) MGC with high Ni content showed week corrosion protection performance during long-term service due to the dissolution of Ni cations and the devastation of the coating structure.Though with bit worse adhesion and more vulnerable Ni_(60)Nb_(40) layers,the multilayered Ni_(50)Nb_(50)/Ni_(60)Nb_(40) MGC possessed comparable corrosion resistance with the monolayered Ni_(50)Nb_(50) MG coating,which remained stable even after 32 days of exposure.Such performance should be ascribed to the combined eff;ect of the repassivation property for the sub-layers,the hindrance of propagation paths of micro-defects,and the obstruction of corrosive species by interfaces in the multilayered coating.展开更多
文摘High speed, high resolution infrared thermography, as a non contact, full field, and nondestructive technique, was used to study the temperature variations of a cobalt based ULTIMET alloy subjected to cyclic fatigue. During each fatigue cycle, the temperature oscillations, which were due to the thermal elastic plastic effects, were observed and related to stress-strain analyses. The change of temperature during fatigue was utilized to reveal the accumulation of fatigue damage. A constitutive model was developed for predicting the thermal and mechanical responses of ULTIMET alloy subjected to cyclic deformation. The model was constructed in light of internal state variables, which were developed to characterize the inelastic strain of the material during cyclic loading. The predicted stress-strain and temperature responses were found to be in good agreement with the experimental results.
基金supported by the National Foundations of China-Australia Special Fund for Scientific and Technological Cooperation(grant No.20711120186)the Natural Science Foundations of China(grant No.20873184)+2 种基金the Natural Science Foundations of Guangdong Province(grant No.8151027501000095)the Science and Technology plan Projects of Guangdong Province(grant No.2008B010600040)the Instrumental Technique Research Foundation of Instrumental Analysis and Research Center,Sun Yat-sen University(grant No.2009006)
文摘Nanostructured silver was obtained by potentiostatic electrolysis.The effects of ionized surfactant(sodium dodecanesulphonate)and the substrate(Cu and Ti)on the morphology of depositions were investigated.It is found that morphologies of silver nanostructures can be simply controlled via change of the substrate.Spherical Ag nanoparticles with narrow size distribution were obtained by electrodeposition in Ag NO3-SDS aqueous solution on copper substrate.In the case of titanium substrate,silver dendrite structures were obtained.Despite of different morphologies,XRD and TEM results showed that the as-prepared samples belong to face-centered cubic silver structure with good crystallinity.The formation mechanism of different silver nanostructures was discussed.
基金supported by National MCF Energy R&D Program(Grant No.2019YFE03080200)the National Natural Science Foundation of China(Grant No.11805212)the Fundamental Research Funds for the Central Universities(Grant No.22120200405).
文摘A simultaneous high-resolution x-ray backlighting and self-emission imaging method for laser-produced plasma diagnostics is developed in which two Kirkpatrick–Baez imaging channels for high-energy and low-energy diagnostics are constructed using a combination of multilayer mirrors in near-coaxial form.By using a streak or framing camera placed on the image plane,both backlit and self-emission images of a laserproduced plasma with high spatial and temporal resolution can be obtained simultaneously in a single shot.This paper describes the details of the method with regard to its optical and multilayer design,assembly,and alignment method.In addition,x-ray imaging results with a spatial resolution better than 5μm in the laboratory and experimental results with imploding capsules in the SG-III prototype laser facility are presented.
基金financially supported by the National Key Research and Development Program of China(2016YFB0700300)the financial support from National Natural Science Foundation of China(No.52001271)+2 种基金the supports from the National Science Foundation(DMR-1611180 and 1809640)the US Army Research Office(W911NF-13-1-0438 and W911NF-19-20049)the Swiss National Science Foundation for support of this work by project"Harnessing atomicscale randomness:design and optimization of mechanical performance in High Entropy Alloys"(Project 200021_118198/1)。
文摘To accelerate the exploration,screening,and discovery of structural high-entropy alloys with targeted properties,the newly developed High-Throughput Hot-Isostatic-Pressing based Micro-Synthesis Approach(HT-HIP-MSA)is employed to efficiently synthesize and characterize 85 combinatorial alloys in a 13-principal element alloying space.These Co Cr Fe Ni-based high entropy alloys span 1 quaternary,9 quinary,and 36 senary alloy systems,and their composition-structure-property relationships are characterized and analyzed experimentally and computationally.From the single-phase FCC CoCrFeNi alloy base,with Mn,Cu,Ti,Nb,Ta,Mo,W,Al,and Si as principal element alloying additions,we find(1)the extended Mn solubility in the single-phase FCC CoCrFeNi-Mn_(x) alloys,(2)the destabilizing behavior for most of the quinary and senary alloys,and(3)the distinctive solid-solution-strengthening effects in the alloys.In combining the computational methods,the HT-HIP-MSA can be systematic and economic to explore and refine the compositions,structures,and properties of structural high-entropy alloys.
基金L.Jiang acknowledges thefinancial support from the Natural Science Foundation of Suzhou University of Science and Technology(No.XKQ2019009)the Basic Research Program of Nantong(No.JC2019085)+3 种基金Z.Q.Chen acknowledgesfinancial support from the Fundamental Research Funds for the Central Universities(No.021314380118)the Natural Science Foundation of Jiangsu Province(No.BK20180266)the Basic Research Program of Nantong(No.JC2019083)X.K.Meng acknowledges thefinancial support from the National Natural Science Foundation of China(No.51771090).
文摘Metallic glasses(MGs)appear as promising anti-corrosion coating materials due to their microstructural and physicochemical advantages.Herein,we proposed magnetron sputtered NiNb thin film MG coatings(MGCs)with different structures and compositions for corrosion protection of 316 stainless steel in an aggressive saline environment.The properties of monolayered Ni_(50)Nb_(50) and Ni_(60)Nb_(40),as well as the multilayered Ni_(50)Nb_(50)/Ni_(60)Nb_(40)(at.%)MGCs,were characterized in terms of morphology and microstructural properties,as well as the anticorrosion behavior.All the NiNb MGCs presented compact structure and the monolayered coatings exhibited preferable adhesion properties in comparison with the multilayered coating.The electrochemical tests and XPS results imply that the monolayered Ni_(50)Nb_(50) MGC with high Nb content resisted corrosion mainly due to the formation of stable passive film that contained abundant Nb_(2)O_(5) species,whereas the Ni_(60)Nb_(40) MGC with high Ni content showed week corrosion protection performance during long-term service due to the dissolution of Ni cations and the devastation of the coating structure.Though with bit worse adhesion and more vulnerable Ni_(60)Nb_(40) layers,the multilayered Ni_(50)Nb_(50)/Ni_(60)Nb_(40) MGC possessed comparable corrosion resistance with the monolayered Ni_(50)Nb_(50) MG coating,which remained stable even after 32 days of exposure.Such performance should be ascribed to the combined eff;ect of the repassivation property for the sub-layers,the hindrance of propagation paths of micro-defects,and the obstruction of corrosive species by interfaces in the multilayered coating.