Hydraulic valve block is an important part of the hydraulic system.The traditional hydraulic valve block is made by turning and milling,drilling and boring,which leads to many right-angle bending and closed cavity str...Hydraulic valve block is an important part of the hydraulic system.The traditional hydraulic valve block is made by turning and milling,drilling and boring,which leads to many right-angle bending and closed cavity structure of process holes in its internal flow channel,seriously affecting the flow performance of oil.Based on the new design space provided by additive manufacturing technology,the internal hydraulic flow channel of valve block is optimized by using B-spline curve.Computational fluid dynamics analysis is carried out on the hydraulic flow channel to determine the optimal flow channel structure with the smallest pressure drop.The weight reduction of hydraulic valve block is carried out through topology optimization.According to the results of topology optimization,using the method of selective laser melting(SLM),the printing of the hydraulic valve block is completed.The optimized hydraulic channel reduces the pressure loss by 31.4%compared with the traditional hydraulic channel.Compared with the traditional valve block,the hydraulic valve block manufactured by SLM with topology optimization reduces the weight by 33.9%.Therefore,the proposed flow channel optimization and valve block lightweight method provide a new reference for the performance improvement of the internal flow channel of hydraulic valve block and the overall lightweight design of valve block.展开更多
The electronic structures and spectroscopic properties of heteroleptic cyclometalated iridium（Ⅲ） complexes were investigated. The geometries, electronic structures, and the lowest-lying excited states of （DBQ）2Ir...The electronic structures and spectroscopic properties of heteroleptic cyclometalated iridium（Ⅲ） complexes were investigated. The geometries, electronic structures, and the lowest-lying excited states of （DBQ）2Ir（acac） and （MDQ）2Ir（acac） were investigated via density functional theory-based approaches. A series of designed models of （DBQ）2Ir（dpis）, （DBQ）2Ir（tpip）, （MDQ）2Ir（dpis） and （MDQ）2Ir（tpip） was also calculated for comparison. The structures in the ground and excited states were optimized via B3LYP method. The lowest absorptions and emissions spectra were evaluated via TD-B3LYP and TD-PBE1PBE methods, The computational results reveal that the emission peaks of the designed complexes are at around 585-640 nm, which belong to the orange-yellow wavelength. The frontier molecular orbital properties indicate that the Ir（Ⅲ） complexes have low efficiency roll-off.展开更多
基金supported by the National Natural Science Foundation of China(No.51775273)the Jiangsu Province Science and Technology Support Plan Project(No.BE2018010-2)+2 种基金the National Defence Basic Scientific Research Program of China(No.JCKY2018605C010)the Frontiers of Science and Technology Program of China (No.1816312ZT00406301)the Aeronautical Science Foundation of China(No.2020Z049052002)
文摘Hydraulic valve block is an important part of the hydraulic system.The traditional hydraulic valve block is made by turning and milling,drilling and boring,which leads to many right-angle bending and closed cavity structure of process holes in its internal flow channel,seriously affecting the flow performance of oil.Based on the new design space provided by additive manufacturing technology,the internal hydraulic flow channel of valve block is optimized by using B-spline curve.Computational fluid dynamics analysis is carried out on the hydraulic flow channel to determine the optimal flow channel structure with the smallest pressure drop.The weight reduction of hydraulic valve block is carried out through topology optimization.According to the results of topology optimization,using the method of selective laser melting(SLM),the printing of the hydraulic valve block is completed.The optimized hydraulic channel reduces the pressure loss by 31.4%compared with the traditional hydraulic channel.Compared with the traditional valve block,the hydraulic valve block manufactured by SLM with topology optimization reduces the weight by 33.9%.Therefore,the proposed flow channel optimization and valve block lightweight method provide a new reference for the performance improvement of the internal flow channel of hydraulic valve block and the overall lightweight design of valve block.
基金Supported by the National Natural Science Foundation for Creative Research Group, China（No.21003057）, the China Post- doctoral Science Foundation（No.2013M541286） and the Science and Technology Planning Project of Jilin Province, China（Nos. 20101512, 20110320, 201201078, 20140520109JH and 20150414003GH）.
文摘The electronic structures and spectroscopic properties of heteroleptic cyclometalated iridium（Ⅲ） complexes were investigated. The geometries, electronic structures, and the lowest-lying excited states of （DBQ）2Ir（acac） and （MDQ）2Ir（acac） were investigated via density functional theory-based approaches. A series of designed models of （DBQ）2Ir（dpis）, （DBQ）2Ir（tpip）, （MDQ）2Ir（dpis） and （MDQ）2Ir（tpip） was also calculated for comparison. The structures in the ground and excited states were optimized via B3LYP method. The lowest absorptions and emissions spectra were evaluated via TD-B3LYP and TD-PBE1PBE methods, The computational results reveal that the emission peaks of the designed complexes are at around 585-640 nm, which belong to the orange-yellow wavelength. The frontier molecular orbital properties indicate that the Ir（Ⅲ） complexes have low efficiency roll-off.
