A new and effective strategy was proposed for preparing new organic-inorganic composite biosorbent with spherical silica as supporting core and chitosan（CS）-based hybrid layer as shell based on sol-gel reaction and ...A new and effective strategy was proposed for preparing new organic-inorganic composite biosorbent with spherical silica as supporting core and chitosan（CS）-based hybrid layer as shell based on sol-gel reaction and simple treatment with sodium hydroxide（NaOH）. The coating layer was covalently bound on the supporting silica through polysaccharide incorporated sol-gel process starting from CS and inorganic precursor γ-glycidoxypropyltrimethoxysiloxane（GPTMS）. GPTMS had epoxide groups and cross-linked amine groups of CS to avoid its acidic solubilization. The composite biosorbent had coarse surface due to the wet phase-inversion by treating in NaOH solution. The prepared biosorbent could be used in treating electric plating wastewater.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.20775039 and 20602009)the Natural Science Founda-tion of Shandong Province of China(No.ZR2009BM031 and Q2008B05)+1 种基金the Public Welfare Project of Marine Science Research of China(Nos.200705011 and 200805039)the Science Research Fund of the First Institute of Oceanograph of China
文摘A new and effective strategy was proposed for preparing new organic-inorganic composite biosorbent with spherical silica as supporting core and chitosan（CS）-based hybrid layer as shell based on sol-gel reaction and simple treatment with sodium hydroxide（NaOH）. The coating layer was covalently bound on the supporting silica through polysaccharide incorporated sol-gel process starting from CS and inorganic precursor γ-glycidoxypropyltrimethoxysiloxane（GPTMS）. GPTMS had epoxide groups and cross-linked amine groups of CS to avoid its acidic solubilization. The composite biosorbent had coarse surface due to the wet phase-inversion by treating in NaOH solution. The prepared biosorbent could be used in treating electric plating wastewater.
