Yb 3+ complexes with two nitrilotriacetic acid molecules were prepared and their compositions were determined as K 3[Yb(nta) 2(H 2O)]·5H 2O and Na 3[Yb(nta) 2]·6H 2O by elemental analyses. Their structures w...Yb 3+ complexes with two nitrilotriacetic acid molecules were prepared and their compositions were determined as K 3[Yb(nta) 2(H 2O)]·5H 2O and Na 3[Yb(nta) 2]·6H 2O by elemental analyses. Their structures were characterized by single crystal X ray diffraction analyses. In complex K 3[Yb(nta) 2(H 2O)]·5H 2O, the YbN 2O 7 part forms a nine coordinate monocapped square antiprismatic structure. In complex Na 3[Yb(nta) 2]·6H 2O, the YbN 2O 6 part forms an eight coordinate square antiprismatic structure. It can be seen that the outer cations (K + and Na +) greatly affect the coordination number and coordinate structure from these results.展开更多
基金Supported by the Natural Science Fund of L iaoning Province and Shenyang City Science and Technology Comm ittee
文摘Yb 3+ complexes with two nitrilotriacetic acid molecules were prepared and their compositions were determined as K 3[Yb(nta) 2(H 2O)]·5H 2O and Na 3[Yb(nta) 2]·6H 2O by elemental analyses. Their structures were characterized by single crystal X ray diffraction analyses. In complex K 3[Yb(nta) 2(H 2O)]·5H 2O, the YbN 2O 7 part forms a nine coordinate monocapped square antiprismatic structure. In complex Na 3[Yb(nta) 2]·6H 2O, the YbN 2O 6 part forms an eight coordinate square antiprismatic structure. It can be seen that the outer cations (K + and Na +) greatly affect the coordination number and coordinate structure from these results.
