In a 0. 10 mol/L HAc-NaAc buffer solution (pH = 4. 59), a sensitive reduction peak of bleomycin was observed by linear sweep voltammetry at a Co/GC ion implantation modified electrode. The peak potential was-0. 73 V(i...In a 0. 10 mol/L HAc-NaAc buffer solution (pH = 4. 59), a sensitive reduction peak of bleomycin was observed by linear sweep voltammetry at a Co/GC ion implantation modified electrode. The peak potential was-0. 73 V(iw. SCE). The peak current was proportional to the concentration of bleomycin over the range of 5.0 × 10-8-1.0× 10-6 and 1.0× 10-6-1. 0 × 10-5 mol/L with a detection limit of 2.0 × 10-8 mol/L. The electrochemical behavior of the reduction peak of bleomycin at the Co/GC modified electrode was studied by linear sweep and cyclic voltammetry and applied to the determination of bleomycin in urine. This method is simple, rapid and reliable. The reduction process is quasi-reversible. The experiments of AES and XPS showed that Co was surely implanted into the surface of GCE and the depth distribution of Co was in good agreement with Gooses normal distribution; the implanted Co at GCE improved the electrocatalytic activity.展开更多
Statistical analysis of turbulent and gusty characteristics in the atmospheric boundary layer under weak wind period has been carried out.The data used in the analysis were from the multilevel ultrasonic anemometer-th...Statistical analysis of turbulent and gusty characteristics in the atmospheric boundary layer under weak wind period has been carried out.The data used in the analysis were from the multilevel ultrasonic anemometer-thermometers at 47 m,120 m,and 280 m levels on Beijing 325 m meteorological tower.The time series of 3D atmospheric velocity were analyzed by using conventional Fourier spectral analysis and decompose into three parts:basic mean flow(period > 10 min),gusty disturbances(1 min < period < 10 min)and turbulence fluctuations(period < 1 min).The results show that under weak mean wind condition:1)the gusty disturbances are the most strong fluctuations,contribute about 60% kinetic energy of eddy kinetic energy and 80% downward flux of momentum,although both the eddy kinetic energy and momentum transport are small in comparison with those in strong mean wind condition;2)the gusty wind disturbances are anisotropic;3)the gusty wind disturbances have obviously coherent structure,and their horizontal and vertical component are negatively correlated and make downward transport of momentum more effectively;4)the friction velocities related to turbulence and gusty wind are approximately constant with height in the surface layer.展开更多
基金National Science Foundation of China(No.98002709)and Doctoral Program Foundation ofInstitution of Higher Education.
文摘In a 0. 10 mol/L HAc-NaAc buffer solution (pH = 4. 59), a sensitive reduction peak of bleomycin was observed by linear sweep voltammetry at a Co/GC ion implantation modified electrode. The peak potential was-0. 73 V(iw. SCE). The peak current was proportional to the concentration of bleomycin over the range of 5.0 × 10-8-1.0× 10-6 and 1.0× 10-6-1. 0 × 10-5 mol/L with a detection limit of 2.0 × 10-8 mol/L. The electrochemical behavior of the reduction peak of bleomycin at the Co/GC modified electrode was studied by linear sweep and cyclic voltammetry and applied to the determination of bleomycin in urine. This method is simple, rapid and reliable. The reduction process is quasi-reversible. The experiments of AES and XPS showed that Co was surely implanted into the surface of GCE and the depth distribution of Co was in good agreement with Gooses normal distribution; the implanted Co at GCE improved the electrocatalytic activity.
基金supported by the national natural Science Foundation of China(40830103 and 41375018)the national Basic Research Program of China(2010CB951804)the Research Program of the Chinese Academy of Sciences(XDA10010403)
文摘Statistical analysis of turbulent and gusty characteristics in the atmospheric boundary layer under weak wind period has been carried out.The data used in the analysis were from the multilevel ultrasonic anemometer-thermometers at 47 m,120 m,and 280 m levels on Beijing 325 m meteorological tower.The time series of 3D atmospheric velocity were analyzed by using conventional Fourier spectral analysis and decompose into three parts:basic mean flow(period > 10 min),gusty disturbances(1 min < period < 10 min)and turbulence fluctuations(period < 1 min).The results show that under weak mean wind condition:1)the gusty disturbances are the most strong fluctuations,contribute about 60% kinetic energy of eddy kinetic energy and 80% downward flux of momentum,although both the eddy kinetic energy and momentum transport are small in comparison with those in strong mean wind condition;2)the gusty wind disturbances are anisotropic;3)the gusty wind disturbances have obviously coherent structure,and their horizontal and vertical component are negatively correlated and make downward transport of momentum more effectively;4)the friction velocities related to turbulence and gusty wind are approximately constant with height in the surface layer.
