A tin film of 320 nm in thickness on Cu foil and its composite film with graphite of-50 nm in thickness on it were fabricated by magnetron sputtering. The surface morphology, composition, surface distributions of allo...A tin film of 320 nm in thickness on Cu foil and its composite film with graphite of-50 nm in thickness on it were fabricated by magnetron sputtering. The surface morphology, composition, surface distributions of alloy elements, and lithium intercalation/de-intercalation behaviors of the fabricated films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), electron probe microanalyzer (EPMA), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma atomic emission spectrometry (ICP), cyclic voltammetry (CV), and galvanostatic charge/discharge (GC) measurements. It is found that the lithium intercalation/de-intercalation behavior of the Sn film can be significantly improved by its composite with graphite. With cycling, the discharge capacity of the Sn film without composite changes from 570 mAh/g of the 2nd cycle to 270 mAh/g of the 20th cycle, and its efficiency for the discharge and charge is between 90% and 95%. Nevertheless, the discharge capacity of the composite Sn/C film changes from 575 mAh/g of the 2nd cycle to 515 mAh/g of the 20th cycle, and its efficiency for the discharge and charge is between 95% and 100%. The performance improvement of tin by its composite with graphite is ascribed to the retardation of the bulk tin cracking from volume change during lithium intercalation and de-intercalation, which leads to the pulverization of tin.展开更多
TiO2-coated SnO2 (TCS) hollow spheres, which are new anode materials for lithium ion (Li-ion) batteries, were prepared and characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), transm...TiO2-coated SnO2 (TCS) hollow spheres, which are new anode materials for lithium ion (Li-ion) batteries, were prepared and characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), cyclic voltammetry (CV), and galvanostatic charge/discharge tests. The results obtained from XRD, SEM, and TEM show that TiO2 can be uniforrrdy coated on the surface of SnO2 hollow spheres with the assistance of anionic surfactant. The cyclic voltammograms indicate that both TiO2 and SnO2 exhibit the activity for Li-ion storage. The charge/discharge tests show that the prepared TCS hollow spheres have a higher reversible coulomb efficiency and a better cycling stability than the uncoated SnO2 hollow spheres.展开更多
卵巢癌是女性生殖系统常见的一种恶性肿瘤,因早期症状不典型、进展迅速,盆腔种植转移早,其病死率一直高居妇科肿瘤之首。人附睾蛋白4(human epididymis protein 4,HE4)是一种新型肿瘤标志物,近年来研究发现其不仅对卵巢癌的早期筛查和...卵巢癌是女性生殖系统常见的一种恶性肿瘤,因早期症状不典型、进展迅速,盆腔种植转移早,其病死率一直高居妇科肿瘤之首。人附睾蛋白4(human epididymis protein 4,HE4)是一种新型肿瘤标志物,近年来研究发现其不仅对卵巢癌的早期筛查和诊断具有重要意义,而且对于评估卵巢癌的治疗效果及预后方面也有应用价值。另外,肿瘤标志物的联合检测能够提高卵巢癌诊断的灵敏度和特异度,而基于肿瘤标志物联合检测的计算模型在预测盆腔包块良恶性上更具预测价值。本文对卵巢癌肿瘤标志物HE4在卵巢癌的诊断、病情评估、治疗效果及预后方面的应用作一综述。展开更多
基金the National Nature Science Foundation of China (Nos. 50771046 and 20373016) the Natural Science Foundation of Guangdong Province (No. 05200534)the Key Projects of Guangdong Province and Guangzhou City, China (Nos. 2006A10704003 and 2006Z3-D2031)
文摘A tin film of 320 nm in thickness on Cu foil and its composite film with graphite of-50 nm in thickness on it were fabricated by magnetron sputtering. The surface morphology, composition, surface distributions of alloy elements, and lithium intercalation/de-intercalation behaviors of the fabricated films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), electron probe microanalyzer (EPMA), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma atomic emission spectrometry (ICP), cyclic voltammetry (CV), and galvanostatic charge/discharge (GC) measurements. It is found that the lithium intercalation/de-intercalation behavior of the Sn film can be significantly improved by its composite with graphite. With cycling, the discharge capacity of the Sn film without composite changes from 570 mAh/g of the 2nd cycle to 270 mAh/g of the 20th cycle, and its efficiency for the discharge and charge is between 90% and 95%. Nevertheless, the discharge capacity of the composite Sn/C film changes from 575 mAh/g of the 2nd cycle to 515 mAh/g of the 20th cycle, and its efficiency for the discharge and charge is between 95% and 100%. The performance improvement of tin by its composite with graphite is ascribed to the retardation of the bulk tin cracking from volume change during lithium intercalation and de-intercalation, which leads to the pulverization of tin.
基金financially supported by the National Natural Science Foundation of China (No.20873046)the Specialized Research Fund for the Doctoral Program of HigherEducation (No.200805740004)Natural Science Foundation of Guangdong Province (No.10351063101000001)
文摘TiO2-coated SnO2 (TCS) hollow spheres, which are new anode materials for lithium ion (Li-ion) batteries, were prepared and characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), cyclic voltammetry (CV), and galvanostatic charge/discharge tests. The results obtained from XRD, SEM, and TEM show that TiO2 can be uniforrrdy coated on the surface of SnO2 hollow spheres with the assistance of anionic surfactant. The cyclic voltammograms indicate that both TiO2 and SnO2 exhibit the activity for Li-ion storage. The charge/discharge tests show that the prepared TCS hollow spheres have a higher reversible coulomb efficiency and a better cycling stability than the uncoated SnO2 hollow spheres.
文摘卵巢癌是女性生殖系统常见的一种恶性肿瘤,因早期症状不典型、进展迅速,盆腔种植转移早,其病死率一直高居妇科肿瘤之首。人附睾蛋白4(human epididymis protein 4,HE4)是一种新型肿瘤标志物,近年来研究发现其不仅对卵巢癌的早期筛查和诊断具有重要意义,而且对于评估卵巢癌的治疗效果及预后方面也有应用价值。另外,肿瘤标志物的联合检测能够提高卵巢癌诊断的灵敏度和特异度,而基于肿瘤标志物联合检测的计算模型在预测盆腔包块良恶性上更具预测价值。本文对卵巢癌肿瘤标志物HE4在卵巢癌的诊断、病情评估、治疗效果及预后方面的应用作一综述。