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污泥与高碱煤协同燃烧中碱金属与重金属竞争机制研究 被引量:2
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作者 李耀德 杨冬 +2 位作者 周熙宏 董乐 王思洋 《动力工程学报》 CAS CSCD 北大核心 2020年第5期349-355,364,共8页
在CFB锅炉燃烧温度下研究了低品质燃料(高碱煤)与生物质燃料(污泥)协同燃烧中重金属元素Pb、Ni和As的迁移特性。结果表明:燃烧温度对重金属元素热力学平衡分布起到重要的作用,温度越高,Pb、Ni和As在气相中的摩尔分数越高;当温度超过1 30... 在CFB锅炉燃烧温度下研究了低品质燃料(高碱煤)与生物质燃料(污泥)协同燃烧中重金属元素Pb、Ni和As的迁移特性。结果表明:燃烧温度对重金属元素热力学平衡分布起到重要的作用,温度越高,Pb、Ni和As在气相中的摩尔分数越高;当温度超过1 300℃时,Pb将全部以单质形态迁移至气相中,在CFB锅炉燃烧温度区间里大部分以PbCl2(g)、少量以PbCl的形态固集于飞灰颗粒上;当温度高于1 800℃时,系统中主要成分为Ni(g);在整个燃烧温度区间,As以单质的形态存在于系统中,其摩尔分数随着温度的升高而上升;碱金属Na主要竞争燃料中的Cl和O元素,实现重金属化合物形态的转化;与Na相比,K的竞争是微弱的,在700℃时K竞争Ni化合物中的CrO4^2-,导致NiO摩尔分数下降,而在850℃时,K与Ni竞争系统中的O元素,这与700℃的反应过程不同。 展开更多
关键词 CFB锅炉 重金属 碱金属 竞争机制
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Coupling Effect of Heat Transfer and Flow Resistance in the Rifled Tube Water Wall of a Ultra-Supercritical CFB Boiler 被引量:5
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作者 li yaode YANG Dong +2 位作者 OUYANG Shijie liU Dan WANG Wenyu 《Journal of Thermal Science》 SCIE EI CAS CSCD 2019年第5期1078-1088,共11页
The coupling factor is used in this study to characterise the combined effect of the heat transfer and resistance characteristics of a rifled tube. Boundary layer theory is utilised to investigate the relationship bet... The coupling factor is used in this study to characterise the combined effect of the heat transfer and resistance characteristics of a rifled tube. Boundary layer theory is utilised to investigate the relationship between the comprehensive coefficient and Reynolds number in two regions, namely, higher and lower than pseudo-critical enthalpy. Results indicate that mass flux exerts a decisive negative influence on the coupling effect, and the impacts of pressure and heat flux are weak. The overall effect decreases rapidly as the mass flux increases, but it increases in the area behind the quasi-critical enthalpy. The coupling effect is also affected by specific heat ratio, thermal acceleration and buoyancy. The correlations of heat transfer and friction resistance are deduced with high precision according to experimental data. 展开更多
关键词 SUPERCRITICAL pressure HEAT TRANSFER frictional resistance coupling effect
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Heavy Metal Migration Characteristics of Co-Combustion between Sewage Sludge and High Alkaline Coal on Circulating Fluidized Bed 被引量:2
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作者 li yaode YANG Dong +3 位作者 ZHOU Xihong DONG Le SUO lihui SUN Wenbo 《Journal of Thermal Science》 SCIE EI CAS CSCD 2022年第6期2178-2188,共11页
The migration characteristics of heavy metals in co-combustion of sewage sludge and high alkali coal in circulating fluidized bed were studied by experiments and simulations. Temperature plays a crucial role in thermo... The migration characteristics of heavy metals in co-combustion of sewage sludge and high alkali coal in circulating fluidized bed were studied by experiments and simulations. Temperature plays a crucial role in thermodynamic equilibrium distribution and migration characteristics of heavy metals. At the temperature range of 700℃-1200℃, Hg is completely gaseous and the proportion of Pb, Ni, and Cd in the gas phase is also high. As is mainly elemental in the system, and the proportion of Cr in the solid phase is large. Zn compounds are diverse and mostly solid materials. The volatility of Cu is not strong, and it will become gaseous when the temperature exceeds 1700℃. The proportion of heavy metals in the gas phase decreases as the excess air ratio increases. In an oxygen-rich atmosphere, most of Zn and Ni are converted to oxides;Pb and Cd are converted to crystalline silicate;Cu is converted to partial aluminate;Cr compound is decomposed to form Cr_(2)O_(3);they are good for the solidification and controlling of heavy metals. The elemental Hg is converted to HgCl_(2) and the elemental As is converted to AsCl_(3). Temperature also has a great influence on the volatilization rate of heavy metals. The higher the temperature, the shorter the time they reach the maximum volatility. 展开更多
关键词 CO-COMBUSTION heavy metal migration circulating fluidized bed sewage sludge high alkali coal
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