Hydroxyapatite(HA)nanoparticles impart outstanding mechanical properties to organicinorganic nanocomposites in bone.Inspired by the composite structure of HA nanoparticles and collagen in bone,a high performance HA/ge...Hydroxyapatite(HA)nanoparticles impart outstanding mechanical properties to organicinorganic nanocomposites in bone.Inspired by the composite structure of HA nanoparticles and collagen in bone,a high performance HA/gelatin nanocomposite was first developed.The nanocomposites have much better mechanical properties(elongation at break 29.9%,tensile strength 90.7 MPa,Young’s modulus 5.24 GPa)than pure gelatin films(elongation at break 9.3%,tensile strength 90.8 MPa,Young’s modulus 2.5 GPa).In addition,the composite films keep a high transmittance in visible wavelength range from 0%to 60%of the HA solid content.These differences in properties are attributed to the homogeneous distribution of HA nanoparticles in the gelatin polymer matrix and the strong interaction between the particle surfaces and the gelatin molecules.This protocol should be promising for HA-based nanocomposites with enhanced mechanical properties for biomedical applications.展开更多
基金Funded by the Natural Science Foundation of Hubei Province(No.2018CFB710)the Opening Fund of Hubei Provincial Key Laboratory of Green Materials for Light Industry(No.202107B07)Hubei University of Technology。
文摘Hydroxyapatite(HA)nanoparticles impart outstanding mechanical properties to organicinorganic nanocomposites in bone.Inspired by the composite structure of HA nanoparticles and collagen in bone,a high performance HA/gelatin nanocomposite was first developed.The nanocomposites have much better mechanical properties(elongation at break 29.9%,tensile strength 90.7 MPa,Young’s modulus 5.24 GPa)than pure gelatin films(elongation at break 9.3%,tensile strength 90.8 MPa,Young’s modulus 2.5 GPa).In addition,the composite films keep a high transmittance in visible wavelength range from 0%to 60%of the HA solid content.These differences in properties are attributed to the homogeneous distribution of HA nanoparticles in the gelatin polymer matrix and the strong interaction between the particle surfaces and the gelatin molecules.This protocol should be promising for HA-based nanocomposites with enhanced mechanical properties for biomedical applications.
文摘为解决某循环流化床锅炉效率低、分离器立管温度高、运行参数不合理等问题,在300 MW和250 MW负荷下,分别进行了变氧含量工况调整试验,在最佳氧含量的基础上,进行了变一次风率、变床压调整试验,优化了氧含量、一次风率、床压等关键参数。试验结果显示:300 MW负荷下,氧含量3.3%、一次风率38%、床压8.2 k Pa锅炉效率达到91.36%;250 MW负荷下,氧含量4.75%、一次风率40%、床压7.7 k Pa锅炉效率达到90.22%。通过增加立管润滑风系统、播煤风风源移位等技术改造措施解决了立管温度高、二次风裕量不足的问题。适当降低床压、一次风率运行,可以在节能降耗的同时提高锅炉效率,研究结果可应用于300 MW等级CFB锅炉的燃烧优化调整。
