Under different reaction conditions, the expected and unexpected reaction products (of which X-ray crystallographic structure was presented) of etherification of 2-per(poly)fluoroethyl 4-substituted phenol with β-hal...Under different reaction conditions, the expected and unexpected reaction products (of which X-ray crystallographic structure was presented) of etherification of 2-per(poly)fluoroethyl 4-substituted phenol with β-haloethanol can be obtained respectively.展开更多
Perfluoroalkylglycine was obtained through perfluoroalkylation of 2-phenyl-5-etho-xyoxazole using RFI-Na2S2O4 reagent system, followed by acid hydrolysis of the intermediates, 2-phenyl-4-perfluoroalkyl-5-ethoxyoxazole...Perfluoroalkylglycine was obtained through perfluoroalkylation of 2-phenyl-5-etho-xyoxazole using RFI-Na2S2O4 reagent system, followed by acid hydrolysis of the intermediates, 2-phenyl-4-perfluoroalkyl-5-ethoxyoxazole and 2-phenyl-4-perfluoroalkyl-2-oxazolin-5-one.展开更多
基金Project supported by the National Natural Science Foundation of China
文摘Under different reaction conditions, the expected and unexpected reaction products (of which X-ray crystallographic structure was presented) of etherification of 2-per(poly)fluoroethyl 4-substituted phenol with β-haloethanol can be obtained respectively.
文摘Perfluoroalkylglycine was obtained through perfluoroalkylation of 2-phenyl-5-etho-xyoxazole using RFI-Na2S2O4 reagent system, followed by acid hydrolysis of the intermediates, 2-phenyl-4-perfluoroalkyl-5-ethoxyoxazole and 2-phenyl-4-perfluoroalkyl-2-oxazolin-5-one.
