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CaO和MnO2双修饰的γ-Al2O3催化再生乙基蒽醌工作液 被引量:3
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作者 程义 梁希慧 +3 位作者 朱朝莹 王韩 徐锦龙 李希 《化学反应工程与工艺》 CAS CSCD 北大核心 2018年第5期431-439,共9页
针对蒽醌法生产工艺中广泛使用的γ-Al2O3对蒽醌降解物再生效率低的不足,以γ-Al2O3为载体,采用浸渍法制备了不同CaO负载量的CaOγ-Al2O3催化剂,考察了CaO含量对乙基蒽醌工作液再生的影响,筛选出最佳的CaO负载量为3.0%(3.0CaO/γ-Al2O3... 针对蒽醌法生产工艺中广泛使用的γ-Al2O3对蒽醌降解物再生效率低的不足,以γ-Al2O3为载体,采用浸渍法制备了不同CaO负载量的CaOγ-Al2O3催化剂,考察了CaO含量对乙基蒽醌工作液再生的影响,筛选出最佳的CaO负载量为3.0%(3.0CaO/γ-Al2O3)。在此基础上,进一步制备了CaO和MnO_2双修饰的催化剂,考察了MnO2负载量对3.0CaOγ-Al2O3催化乙基蒽醌工作液再生的影响,表明Mn O2负载量为0.5%的催化剂(3.0CaO0.5MnO2/γ-Al2O3)性能较好。采用X射线荧光光谱、氮气低温物理吸附和X射线粉末衍射等表征手段对三个代表性催化剂的物理化学性质进行了研究。结果表明,与γ-Al2O3和3.0CaO/γ-Al2O3相比,双修饰的3.0CaO0.5MnO2/γ-Al2O3催化剂不仅明显促进了工作液中四氢-2-乙基羟基蒽酮(OXOH4e AQ)和四氢-2-乙基蒽醌环氧化物(EPOXH4e AQ)的再生,而且加速了四氢-2-乙基蒽醌(H4e AQ)向2-乙基蒽醌(eAQ)的转化。经优化得到的3.0CaO0.5MnO2/γ-Al2O3具有一定的工业应用前景。 展开更多
关键词 蒽醌 氧化铝 过氧化氢 降解物
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Review of local mean decomposition and its application in fault diagnosis of rotating machinery 被引量:5
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作者 LI Yongbo SI Shubin +1 位作者 LIU Zhiliang liang xihui 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2019年第4期799-814,共16页
Rotating machinery is widely used in the industry.They are vulnerable to many kinds of damages especially for those working under tough and time-varying operation conditions.Early detection of these damages is importa... Rotating machinery is widely used in the industry.They are vulnerable to many kinds of damages especially for those working under tough and time-varying operation conditions.Early detection of these damages is important,otherwise,they may lead to large economic loss even a catastrophe.Many signal processing methods have been developed for fault diagnosis of the rotating machinery.Local mean decomposition(LMD)is an adaptive mode decomposition method that can decompose a complicated signal into a series of mono-components,namely product functions(PFs).In recent years,many researchers have adopted LMD in fault detection and diagnosis of rotating machines.We give a comprehensive review of LMD in fault detection and diagnosis of rotating machines.First,the LMD is described.The advantages,disadvantages and some improved LMD methods are presented.Then,a comprehensive review on applications of LMD in fault diagnosis of the rotating machinery is given.The review is divided into four parts:fault diagnosis of gears,fault diagnosis of rotors,fault diagnosis of bearings,and other LMD applications.In each of these four parts,a review is given to applications applying the LMD,improved LMD,and LMD-based combination methods,respectively.We give a summary of this review and some future potential topics at the end. 展开更多
关键词 local mean decomposition(LMD) SIGNAL processing GEAR ROTOR BEARING
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蒽醌法制备H_(2)O_(2)工艺中溶剂对γ-Al_(2)O_(3)再生蒽醌降解物的影响 被引量:1
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作者 梁希慧 程义 +2 位作者 程浩峰 孔振飞 汤亚文 《化学反应工程与工艺》 CAS 北大核心 2020年第6期562-570,共9页
为研究蒽醌法制备H_(2)O_(2)工艺中使用的溶剂对活性氧化铝(γ-Al_(2)O_(3))再生蒽醌降解物的影响,采用溶剂预处理γ-Al_(2)O_(3)和向工作液中加入溶剂两种方法,考察了重芳烃(Ar)、磷酸三辛酯(TOP)、2-甲基环己基醋酸酯(MCA)、四丁基脲(... 为研究蒽醌法制备H_(2)O_(2)工艺中使用的溶剂对活性氧化铝(γ-Al_(2)O_(3))再生蒽醌降解物的影响,采用溶剂预处理γ-Al_(2)O_(3)和向工作液中加入溶剂两种方法,考察了重芳烃(Ar)、磷酸三辛酯(TOP)、2-甲基环己基醋酸酯(MCA)、四丁基脲(TBU)和二异丁基甲醇(DIBC)共5种溶剂对γ-Al_(2)O_(3)再生蒽醌降解物的影响。结果表明:Ar,TBU和DIBC对γ-Al_(2)O_(3)再生蒽醌降解物的性能几乎没有影响,但TOP和MCA均会显著降低γ-Al_(2)O_(3)对蒽醌降解物的再生能力。推测是因溶剂分子与γ-Al_(2)O_(3)的碱性位之间相互作用强弱不同引起的。 展开更多
关键词 过氧化氢 氧化铝 蒽醌 再生 溶剂
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