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MnFe_(2)O_(4)-CR的制备及其活化过一硫酸盐降解盐酸四环素性能
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作者 陈丛瑾 黄丽斌 +3 位作者 范辉 张强煦 廖金戈 陈紫霞 《精细化工》 EI CAS CSCD 北大核心 2024年第7期1570-1580,共11页
利用水热法将Mn Fe_(2)O_(4)负载在生物质汽化炭渣(CR)上,得到了负载型复合催化剂Mn Fe_(2)O_(4)-CR,通过SEM、XRD、XPS、BET和VSM对Mn Fe_(2)O_(4)-CR进行了表征,将其用于活化过一硫酸盐(PMS)降解盐酸四环素(TC)。考察了不同反应体系、... 利用水热法将Mn Fe_(2)O_(4)负载在生物质汽化炭渣(CR)上,得到了负载型复合催化剂Mn Fe_(2)O_(4)-CR,通过SEM、XRD、XPS、BET和VSM对Mn Fe_(2)O_(4)-CR进行了表征,将其用于活化过一硫酸盐(PMS)降解盐酸四环素(TC)。考察了不同反应体系、Mn Fe_(2)O_(4)与CR质量比、PMS用量、催化剂用量、温度、pH、阴离子(HCO_(3)–、H_(2)PO_(4)^(–)、Cl^(–)、NO_(3)^(–))和腐植酸(HA)对MnFe_(2)O_(4)-CR/PMS体系降解TC的影响,探究了Mn Fe_(2)O_(4)-CR的稳定性和循环使用性,并探讨了Mn Fe_(2)O_(4)-CR/PMS体系中TC可能的降解机理。结果表明,Mn Fe_(2)O_(4)与CR质量比为1∶2时制备的Mn Fe_(2)O_(4)-CR催化效果良好,在30℃、30 mg MnFe_(2)O_(4)-CR、40 mg PMS、90 min的条件下,100 mL质量浓度为50mg/L自然pH的TC溶液中TC的降解率达到91.32%。Mn Fe_(2)O_(4)-CR可利用其磁性回收,经过5次循环利用,催化PMS降解TC的降解率仍能达到82.90%,表明MnFe_(2)O_(4)-CR具有良好的稳定性和重复使用性。Mn Fe_(2)O_(4)-CR/PMS体系中,硫酸根自由基(SO_(4)^(-)·)、·OH、单线态氧(^(1)O_(2))和过氧自由基(O_(2)^(-)·)是降解TC的主要活性氧物种,并提出了相应的催化降解机理。 展开更多
关键词 Mn Fe_(2)O_(4)-CR 盐酸四环素 高级氧化技术 复合催化剂 过一硫酸盐 降解 催化技术
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Hot Tearing Behavior of Mg-Gd-Y-X Alloys
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作者 liao jinge LI Chengxing +6 位作者 ZOU Wenbing KANG Jing SONG Jiangfeng JIANG Bin ZHAO Hua YANG Zhiyuan PAN Fusheng 《上海航天(中英文)》 CSCD 2022年第1期92-101,共10页
Mg-Gd-Y-Zr alloy castings are widely used in the aerospace field owing to their high strength and excellent creep resistance.The castability of these alloys is also an important consideration for engineering applicati... Mg-Gd-Y-Zr alloy castings are widely used in the aerospace field owing to their high strength and excellent creep resistance.The castability of these alloys is also an important consideration for engineering application.Thus,the hot tearing susceptibilities(HTSs)of Mg-10Gd-1Y-1Zn-0.5Zr(VW91)alloy and Mg-10Gd-2Y-1Zn-0.5Zr(VW92)alloy are investigated with a constrained rod casting(CRC)mold.The microstructures and fracture surface are characterized by optical microscope and scanning electron microscope.The results unveil that the HTS of VW92alloy is lower than that of VW91 alloy.The microstructures indicate that obvious tears can be observed in VW91 alloy,while the tears in VW92 alloy are tiny.The tear feeding and healing by eutectic are also observed in VW91 and VW92alloys.Therefore,the lower hot tearing susceptibility of VW92 alloy is mainly attributed to the high amount of eutectic which feeds and heals tears.Besides,the effects of the coefficient of thermal expansion(CTE)and the fluidity of VW91 and VW92 alloys on their HTSs are discussed. 展开更多
关键词 VW91 alloy VW92 alloy hot tearing susceptibility(HTS) FLUIDITY coefficient of thermal expansion(CTE) EUTECTIC
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