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Generation of subwavelength inverted pin beam via fiber end integrated plasma structure 被引量:1
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作者 Zhengchuan Cai Zhiqiang Quan +2 位作者 libo yuan Jian Wang Houquan Liu 《Advanced Photonics Nexus》 2024年第2期18-25,共8页
A pin-like beam is a kind of structured light with a special intensity distribution that can be against diffraction,which can be seen as a kind of quasi-nondiffracting beam(Q-NDB).Due to its wide applications,recently... A pin-like beam is a kind of structured light with a special intensity distribution that can be against diffraction,which can be seen as a kind of quasi-nondiffracting beam(Q-NDB).Due to its wide applications,recently,numerous researchers have used optical lenses or on-chip integrated optical diffractive elements to generate this kind of beam.We theoretically verify and experimentally demonstrate an all-fiber solution to generate a subwavelength inverted pin beam by integrating a simple plasma structure on the fiber end surface.The output beams generated by two kinds of plasma structures,i.e.,nanoring slot and nanopetal structure,are investigated and measured experimentally.The results show that both the structures are capable of generating subwavelength beams,and the beam generated using the nanopetal structure has the sidelobe suppression ability along the x-axis direction.Our all-fiber device can be flexibly inserted into liquid environments such as cell cultures,blood,and biological tissue fluids to illuminate or stimulate biological cells and molecules in them.It provides a promising fiber-integrated solution for exploring light–matter interaction with subwavelength resolution in the field of biological research. 展开更多
关键词 iinverted pin beam fiber-integrated plasma structure subwavelength resolution
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The Driving Forces of CO2 Emission in China: 2002-2007
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作者 libo yuan Yinchuan Xu 《Chinese Business Review》 2013年第4期298-304,共7页
This paper provides a computation on both the China's aggregate CO2 emission volume and the emission of each sector over the period of 2002-2007, based on the input-output analysis. Further analysis is also given on ... This paper provides a computation on both the China's aggregate CO2 emission volume and the emission of each sector over the period of 2002-2007, based on the input-output analysis. Further analysis is also given on the various determinants of the change in the emission volume, with the aid of structural decomposition analysis (SDA) based on a residual-free method. Based on the input-output table of China in 2002 and 2007, the merge of sectors and the adjustment of price change have been made during the study. The emissions of carbon dioxide in China increased from 2,887.3 million ton to 5,664.6 million ton during 2002-2007. The average rate of increase is 13.3%, faster than the average rate of gross domestic product (GDP) growth 11.6% slightly. According to the process of SDA, the changes in emission are analyzed in terms of four different factors. Among the four factors studied in the paper, it is found that the change of emission intensity and structure of demand are the main reason of the decrease of emission, while production technology and scale effect increase the emission volume. The paper also finds that although the direct emission intensity decreased during the study period, the total emission intensity increased with the annual rate of 3.8%, which reflects the result of energy policy is not equal in different sectors. 展开更多
关键词 carbon emissions input-output table hybrid units structural decomposition analysis trading structure emission intensity
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A Smart Graded-index Multimode Fiber Based Sensor Unit for Multi-parameter Sensing Applications
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作者 Shuo Fang Baoyong Li +3 位作者 Dawei Song Jianzhong Zhang Weimin Sun libo yuan 《Optics and Photonics Journal》 2013年第2期265-267,共3页
We demonstrate a smart optical fiber sensor unit to realize a multi-parameter sensing, including temperature, curvature and strain or displacement. The sensor unit is composed of a Bragg grating in graded-index multim... We demonstrate a smart optical fiber sensor unit to realize a multi-parameter sensing, including temperature, curvature and strain or displacement. The sensor unit is composed of a Bragg grating in graded-index multimode fiber and a Fizeau cavity. 展开更多
关键词 FIBER OPTIC SENSOR FIBER BRAGG Grating FIBER Fizeau Cavity
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Thermo-optical tweezers based on photothermal waveguides
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作者 Fuwang Li Jian Wei +6 位作者 Xiaomei Qin Xue Chen Dawei Chen Wentao Zhang Jiaguang Han libo yuan Hongchang Deng 《Microsystems & Nanoengineering》 CSCD 2024年第5期95-103,共9页
Field-controlled micromanipulation represents a pivotal technique for handling microparticles,yet conventional methods often risk physical damage to targets.Here,we discovered a completely new mechanism for true nonco... Field-controlled micromanipulation represents a pivotal technique for handling microparticles,yet conventional methods often risk physical damage to targets.Here,we discovered a completely new mechanism for true noncontact manipulation through photothermal effects,called thermal-optical tweezers.We employ a laser self-assembly photothermal waveguide(PTW)for dynamic microparticle manipulation.This waveguide demonstrates superior photothermal conversion and precision control,generating a nonisothermal temperature field.The interaction of thermal convection and thermophoresis within this field creates a microfluidic potential well,enabling noncontact and nondestructive particle manipulation.By varying the path of PTWs in lithography and manipulating laser loading modes,diverse manipulation strategies,such as Z-shaped migration,periodic oscillation,and directional transport,are achievable.Our innovative noninvasive micromanipulation technology minimizes not only physical damage to target objects but also enables precise and diverse manipulation of micro entities,opening up new avenues for the photothermal control of cells and biomolecules. 展开更多
关键词 WAVEGUIDE LITHOGRAPHY PRECISE
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Embedded whispering-gallery mode microsphere resonator in a tapered hollow annular core fiber 被引量:5
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作者 JIAWEI WANG XIAOBEI ZHANG +7 位作者 MING YAN LEI YANG FENGYU HOU WEN SUN XIAOTONG ZHANG libo yuan HAI XIAO TINGYUN WANG 《Photonics Research》 SCIE EI 2018年第12期1124-1129,共6页
We propose and demonstrate a tapered hollow annular core fiber (HACF) coupler for excitation of whisperinggallery modes (WGMs) of an embedded microsphere resonator. The coupler is simply fabricated by fusion splicing ... We propose and demonstrate a tapered hollow annular core fiber (HACF) coupler for excitation of whisperinggallery modes (WGMs) of an embedded microsphere resonator. The coupler is simply fabricated by fusion splicing of a segment of HACF with the single-mode fiber (SMF), and then improved by tapering the splicing joint to reduce the cone-apex angle. Therefore, the coupling efficiency from the SMF to the HACF is enhanced to excite various WGMs via evanescent field coupling. Normal positive, negative symmetrical Lorentzian and asymmetric Fano line shapes can be obtained by varying the resonator size and location. Another interesting phenomenon is observed that a higher Q-factor mode in a lower Q-factor mode has a contrast as high as 58. Temperature sensing with good stability is also demonstrated. This embedded WGM microsphere resonator in the tapered HACF is expected to promote environmental adaptability in practical applications due to its simplicity and 展开更多
关键词 Single MODE FIBER (SMF) cavity EMBEDDED WGM MICROSPHERE RESONATOR
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Loop Topology Based White Light Interferometric Fiber Optic Sensor Network for Application of Perimeter Security 被引量:6
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作者 libo yuan Yongtao DONG 《Photonic Sensors》 SCIE EI CAS 2011年第3期260-267,共8页
A loop topology based white light interferometric sensor network for perimeter security has been designed and demonstrated. In the perimeter security sensing system, where fiber sensors are packaged in the suspended c... A loop topology based white light interferometric sensor network for perimeter security has been designed and demonstrated. In the perimeter security sensing system, where fiber sensors are packaged in the suspended cable or buried cable, a bi-directional optical path interrogator is built by using Michelson or Mach-Zehnder interferometer. A practical implementation of this technique is presented by using an amplified spontaneous emission (ASE) light source and standard single mode fiber, which are common in communication industry. The sensor loop topology is completely passive and absolute length measurements can be obtained for each sensing fiber segment so that it can be used to measure quasi-distribution strain perturbation. For the long distance perimeter monitoring, this technique not only extends the multiplexing potential, but also provides a redundancy for the sensing system. One breakdown point is allowed in the sensor loop because the sensing system will still work even if the embedded sensor loop breaks somewhere. 展开更多
关键词 Optical fiber sensors quasi-distributed sensing system perimeter security white light interferometry
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Tunable fiber-tip lens based on thermo-optic effect of amorphous silicon 被引量:3
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作者 Ping Li Jing Liu +4 位作者 Peng Huang Xingyu Zhang Jinhui Shi libo yuan Chunying Guan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2020年第3期17-20,共4页
We theoretically demonstrate a compact all-dielectric metasurface fiber-tip lens composed of sub-wavelength amorphous silicon on the end face of a multimode fiber.The full 2πphase control was realized by varying the ... We theoretically demonstrate a compact all-dielectric metasurface fiber-tip lens composed of sub-wavelength amorphous silicon on the end face of a multimode fiber.The full 2πphase control was realized by varying the widths of resonant units.The tunable focal length is achieved by using the thermal-optic effect of amorphous silicon.The focal length increases from 309μm to 407μm when the temperature changes by 300 K.The temperature controlled all-fiber integrated lens is compact and with high efficiency and provides an excellent platform of a fiber-tip lab.Meanwhile,the proposed fiber lens does not have any structural changes during dynamic tuning,which improves the durability and repeatability of the devices. 展开更多
关键词 fiber-tip LENS TUNABLE FOCUS length all-dielectric metasurface thermal-optic effect
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Multi-focus optical fiber lens based on all-dielectric metasurface 被引量:5
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作者 Xingyu Zhang Chunying Guan +6 位作者 Keda Wang Lin Cheng Jing Yang Jinhui Shi Hongchao Liu Zhihai Liu libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2021年第5期6-11,共6页
A multi-focus optical fiber lens is numerically demonstrated based on an all-dielectric metasurface structure.The metasurface consists of an array of rectangular silicon resonators with varying widths in order to obta... A multi-focus optical fiber lens is numerically demonstrated based on an all-dielectric metasurface structure.The metasurface consists of an array of rectangular silicon resonators with varying widths in order to obtain the required phase distribution.The core diameter of the multimode fiber is large enough to contain sufficient resonance units.The spatial distribution of the dielectric resonators is dictated by spatial multiplexing,including interleaving meta-atoms and lens aperture division,to achieve multi-focus properties.The proposed optical fiber metalens can produce two or three focal points along the longitudinal direction with high focusing efficiency.The size of every focal point is close to the diffraction limit,and the relative intensity on each focus can be controlled by adjusting the number of the respective resonators.The proposed optical fiber lens will have a great potential in the fields of integrated optics and multifunctional micro/nano devices. 展开更多
关键词 multi-focus lens optical fiber metasurface
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Optical-fiber-based powerful tools for living cell manipulation [Invited] 被引量:3
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作者 Xiaotong Zhang Shitai Yang libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2019年第9期15-26,共12页
By using a specialty optical fiber, a series of powerful microparticle manipulation tools, including optical tweezers, a micro-optical hand, and an optical gun, are developed and demonstrated. In this paper,a review o... By using a specialty optical fiber, a series of powerful microparticle manipulation tools, including optical tweezers, a micro-optical hand, and an optical gun, are developed and demonstrated. In this paper,a review of our research activities on the optical manipulation of microparticles is presented. In particular,we will describe a kind of specialty optical fiber designed and fabricated for building optical trapping and manipulating tools. The performances of annular core fiber-based optical tweezers, a multicore fiber-based micro-optical hand, and a coaxial dual waveguide fiber-based optical gun are demonstrated as examples of applications and discussed in detail. The fiber can be used in cell manipulation in life science and drug response in medicine. 展开更多
关键词 Optical-fiber-based LIVING cell micro-optical
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Recent Progress of In-Fiber Integrated Interferometers 被引量:3
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作者 libo yuan 《Photonic Sensors》 SCIE EI 2011年第1期1-5,共5页
A brief review of recent progress made in a range of in-fiber integrated interferometers for measuring is presented,with particular attention paid to the multi-core based in-fiber integrated techniques,which have the ... A brief review of recent progress made in a range of in-fiber integrated interferometers for measuring is presented,with particular attention paid to the multi-core based in-fiber integrated techniques,which have the potential to be exploited in a variety of wide applications. 展开更多
关键词 Optical fiber multi-core fiber fiber optic sensor fiber optic interferometer
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Highly sensitive torsion sensor based on triangular-prism-shaped long-period fiber gratings 被引量:3
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作者 Senyu Wang Yiwei Ma +8 位作者 Xiaoyang Li Yang Yi Cuiting Sun Jingyu Lin Chengguo Tong Yuxiang Li Tao Geng Weimin Sun libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2021年第4期28-31,共4页
We propose and investigate a compact optical fiber sensor that aims to measure the torsion in both amount and direction with high sensitivity.This sensor is configured by a triangular-prism-shaped long-period fiber gr... We propose and investigate a compact optical fiber sensor that aims to measure the torsion in both amount and direction with high sensitivity.This sensor is configured by a triangular-prism-shaped long-period fiber grating,which is fabricated by the high frequency CO_(2) laser polished method.The unique design of the triangular-shaped structure breaks the rotational symmetry of the optical fiber and provides high sensitivity for torsion measurement.In preliminary experiments,the torsion response of the sensor achieves a good stability and linearity.The torsion sensitivity is 0.54 nm/(rad/m),which renders the proposed structure a highly sensitive torsion sensor. 展开更多
关键词 long-period fiber grating torsion sensor CO_(2)laser etched method
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High sensitivity cascaded helical-core fiber SPR sensors 被引量:2
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作者 Xianbin Wang Hongchang Deng libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2021年第9期7-12,共6页
The distributed optical fiber surface plasmon resonance(SPR)sensors have attracted wide attention in biosensing and chemical sensing applications.However,due to the limitation of their sensing structure,it is difficul... The distributed optical fiber surface plasmon resonance(SPR)sensors have attracted wide attention in biosensing and chemical sensing applications.However,due to the limitation of their sensing structure,it is difficult to adjust their res-onant wavelength and sensitivity.Here,novel and flexible cascaded helical-core fiber[HCF)SPR sensors are proposed theoretically and experimentally for distributed sensing applications.It is shown that the resonant wavelength and sensitivity of the sensors can be conveniently controlled by adjusting the twist pitch of the helical core.A high sensitivity of 11,180 nm/RIU for refractive-index measurement ranging from 1.355 to 1.365 is realized experimentally when the twist pitch of the helical core is 1.5 mm.It is worth noting that the sensitivity can be further improved by reducing the twist pitch.For example,the sensitivity of the sensor with a twist pitch of 1.4 mm can theoretically exceed 20,000 nm/RIU.This work opens up a new way to implement multi-parameter or distributed measurement,especially to establish sensing networks integrated in a single-core fiber or a multi-core fiber. 展开更多
关键词 helical-core fiber surface plasmon resonance distributed optical fiber sensor whispering gallery modes
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Review of Optical Fiber Sensor Network Technology Based on White Light Interferometry 被引量:2
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作者 Wenchao LI Yonggui yuan +1 位作者 Jun YANG libo yuan 《Photonic Sensors》 SCIE EI CAS CSCD 2021年第1期31-44,共14页
Optical fiber sensor networks(OFSNs)provide powerful tools for large-scale buildings or long-distance sensing,and they can realize distributed or quasi-distributed measurement of temperature,strain,and other physical ... Optical fiber sensor networks(OFSNs)provide powerful tools for large-scale buildings or long-distance sensing,and they can realize distributed or quasi-distributed measurement of temperature,strain,and other physical quantities.This article provides some optical fiber sensor network technologies based on the white light interference technology.We discuss the key issues in the fiber white light interference network,including the topology structure of white light interferometric fiber sensor network,the node connection components,and evaluation of the maximum number of sensors in the network.A final comment about further development prospects of fiber sensor network is presented. 展开更多
关键词 Optical fiber sensor white light interference optical fiber sensor network(OFSN) multiplexed sensing system
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Simultaneous evaluation of two branches of a multifunctional integrated optic chip with an ultra-simple dual-channel configuration 被引量:2
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作者 Yonggui yuan Chuang Li +8 位作者 Jun Yang Ai Zhou Shuai Liang Zhangjun Yu Bing Wu Feng Peng Yu Zhang Zhihai Liu libo yuan 《Photonics Research》 SCIE EI 2015年第4期115-118,共4页
We propose an ultra-simple dual-channel configuration for simultaneously evaluating two branches of a multifunctional integrated optic chip(MFIOC). In the configuration, the MFIOC is employed as a beam splitter to con... We propose an ultra-simple dual-channel configuration for simultaneously evaluating two branches of a multifunctional integrated optic chip(MFIOC). In the configuration, the MFIOC is employed as a beam splitter to construct the demodulation interferometer together with a 2 × 2 fiber coupler. Interference happens between polarization modes traveling through different channels of the MFIOC. The cross-couplings of each channel are respectively characterized by the interference peaks which distribute on opposite sides of the central interference peak. Temperature responses of the MFIOC are experimentally measured from-40°C to 80°C. Results show that the proposed configuration can achieve simultaneous dual-channel transient measurements with resolution of-90 d B and dynamic range of 90 d B. In addition, the two channels of the configuration have consistent measuring performance, and the two branches of the MFIOC have different responses to temperature variation. 展开更多
关键词 ting In PM length Simultaneous evaluation of two branches of a multifunctional integrated optic chip with an ultra-simple dual-channel configuration
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A new phase-shifted long-period fiber grating for simultaneous measurement of torsion and temperature 被引量:1
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作者 Cuiting Sun Ran Wang +10 位作者 Xiren Jin Zemin Wang Weiliang Liu Shuo Zhang Yiwei Ma Jingyu Lin Yue Li Tao Geng Weimin Sun Zhongquan Qu libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2020年第2期39-43,共5页
A novel phase-shifted long-period fiber grating(PS-LPFG)for the simultaneous measurement of torsion and temperature is described and experimentally demonstrated.The PS-LPFG is fabricated by inserting a pretwisted stru... A novel phase-shifted long-period fiber grating(PS-LPFG)for the simultaneous measurement of torsion and temperature is described and experimentally demonstrated.The PS-LPFG is fabricated by inserting a pretwisted structure into the long-period fiber grating(LPFG)written in single-mode fiber(SMF).Experimental results show that the torsion sensitivities of the two dips are?0.114 nm/(rad/m)and?0.069 nm/(rad/m)in the clockwise direction,and?0.087 nm/(rad/m)and?0.048 nm/(rad/m)in the counterclockwise direction,respectively.The temperature sensitivities of the two dips are 0.057 nm/℃ and 0.051 nm/℃,respectively.The two dips of the PS-LPFG exhibit different responses to torsion and temperature.Simultaneous measurement of torsion and temperature can be implemented using a sensor.The feasibility and stabilization of simultaneous torsion and temperature measurement have been confirmed,and hence this novel PS-LPFG demonstrates potential for fiber sensing and engineering applications. 展开更多
关键词 phase-shifted long-period FIBER GRATING pre-twisted structure SINGLE-MODE FIBER SIMULTANEOUS measurement TORSION temperature
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Single fiber dual-functionality optical tweezers based on graded-index multimode fiber 被引量:2
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作者 Zhihai Liu Tong Wang +7 位作者 Yaxun Zhang Xiaoyun Tang Peikun Liu Yu Zhang Xinghua Yang Jianzhong Zhang Jun Yang libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2018年第5期87-91,共5页
We propose and demonstrate single fiber dual-functionality optical tweezers based on a graded-index multimode fiber. By using the multi-angle fiber grinding and polishing technology, we fabricate the multimode fiber t... We propose and demonstrate single fiber dual-functionality optical tweezers based on a graded-index multimode fiber. By using the multi-angle fiber grinding and polishing technology, we fabricate the multimode fiber tip to be a special tapered shape, contributing to focus the outgoing beam with a large intensity gradient for the first functionality--three-dimensional contactless trapping of a microparticle. By adjusting the radial direction offset between the lead-in single mode fiber and the graded-index multimode fiber, we perform the second functionality--axial shift of the trapped microparticle with respect to the fiber tip without need of moving the fiber probe itself. It is convenient for practical applications, The theoretical and experimental results about the relationship between the radial offset and the equilibrium positions of the microparticle have the good consistency. Tailoring the trap and axial shift of the microparticle based on the graded-index multimode fiber provides convenient avenues for fiber optical tweezers a~)Dlied in practical researches. 展开更多
关键词 MMF Single fiber dual-functionality optical tweezers based on graded-index multimode fiber
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In-fiber integrated optics: an emerging photonics integration technology [Invited] 被引量:1
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作者 Xiaotong Zhang Tingting yuan +5 位作者 Xinghua Yang Chunying Guan Jun Yang Zhihai Liu Hongchang Deng libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2018年第11期14-21,共8页
In-fiber integrated optics is an attempt to use silica fiber as a substrate, integrating various optical paths or optical components into a single fiber, to build a functional optical device or component, and to reali... In-fiber integrated optics is an attempt to use silica fiber as a substrate, integrating various optical paths or optical components into a single fiber, to build a functional optical device or component, and to realize a micro optical system, achieving various functions. In-fiber integrated optics is expected to he a new branch of photonics integration. This integration technique enables convenient light beams control and manipulation inside in one fiber. It also provides a research platform with micro and nano scale for interaction between light wave and microfluidic materials. In this review, we briefly summarize the main ideas and key technologies of the in-fiber integrated optics by series integration examples. 展开更多
关键词 Beam manipulation Integrated optics Light beams Optical components Silica fibers
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Intelligent all-fiber device: storage and logic computing 被引量:1
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作者 Zhihai Liu Siying Cheng +7 位作者 Yu Zhang Wei Jin Xiang Li Yaru Li Yaxun Zhang Xinghua Yang Jianzhong Zhang libo yuan 《Photonics Research》 SCIE EI CAS CSCD 2022年第2期357-363,共7页
The typical functions of the optical fiber are communication and sensing. However, the fiber functions need to extend to meet the requirements of the development of artificial intelligence. This paper achieves an all-... The typical functions of the optical fiber are communication and sensing. However, the fiber functions need to extend to meet the requirements of the development of artificial intelligence. This paper achieves an all-fiber device with storage and logic computing functions using a single-mode fiber and Ge_(2)Sb_(2)Te_(5)(GST) material.We use the pulse amplitude modulation(the switching energy is about 50 nJ) to switch the GST state for performing the eight-level data storage(3-bit). The all-fiber memory device has the advantages of high optical contrast(about 38%), good reversibility, and high repeatability. We implement the all-optical logic operations(“AND”and “OR”) by using two memory cells in series and parallel. For the first time, we use the single-mode optical fiber to realize storage and computing functions, and this intelligent fiber has tremendous application potential in intelligent optical fiber communication and portends a new paradigm for brain-like computing. 展开更多
关键词 FIBER COMPUTING mode
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Dual-channel microfluidic sensor based on side-hole fiber with two long-period fiber gratings
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作者 Yu Zhang Yongzhi Li +6 位作者 Chao Liu Zhihai Liu Yaxun Zhang Xinghua Yang Jianzhong Zhang Jun Yang libo yuan 《Chinese Optics Letters》 SCIE EI CAS CSCD 2020年第2期1-4,共4页
We propose and demonstrate a dual-channel microfluidic sensor based on a side-hole fiber(SHF)with two longperiod fiber grating(LPFG)structures.There are two air holes in the SHF,which are natural microfluidic channels... We propose and demonstrate a dual-channel microfluidic sensor based on a side-hole fiber(SHF)with two longperiod fiber grating(LPFG)structures.There are two air holes in the SHF,which are natural microfluidic channels.We fabricate two LPFGs(long-period gratings LPG-A and LPG-B)in the SHF with the resonance wavelengths of 1268.7 nm and 1385.8 nm,respectively.Results show that the refractive index sensitivities of LPG-A and LPG-B are?76.0 nm/RIU and?71.1 nm/RIU,respectively.One can measure the refractive index of liquid samples in two channels simultaneously.The proposed dual-channel microfluidic sensor has advantages of good linearity response,fluidic technology compatibility,and easy light input/output coupling and system integration,which helps the sensor to have a potential application in environmental detection and food safety detection. 展开更多
关键词 long-period GRATING OPTICAL FIBER SENSOR refractive INDEX measurement
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Photoisomerization,assembling and fluorescence photoswitching behaviors of a water-soluble stiff-stilbene with cucurbit[7]uril
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作者 Liangru Yang Yixin Li +5 位作者 Haifan Zhang Changming Tian Qiaohong Cao Yongmei Xiao libo yuan Guoxing Liu 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第8期184-188,共5页
Photoresponsive supramolecular systems have merited extensive attention for their applications in materials science and life science.Here,we synthesized a water-soluble stiff-stilbene molecular photoswitch,exhibiting ... Photoresponsive supramolecular systems have merited extensive attention for their applications in materials science and life science.Here,we synthesized a water-soluble stiff-stilbene molecular photoswitch,exhibiting outstanding photoisomerization reaction between its(E)-and(Z)-configurations upon irradiation at distinct light.The photoswitch can assemble with cucurbit[7]uril(CB[7])to form a superior fluorescent supramolecular complex(compared to the only guest)with excellent water solubility,which manifested dramatic photoluminescence enhancement caused by restriction of intramolecular rotation and remained good photochromic characteristics.Furthermore,introduction of CB[7]influence photoreaction quantum yield(Φ)of the stiff-stilbene,leading to reduction ofΦ_(E→Z) and increase ofΦ_(Z→E) of the stiff-stilbene.Importantly,the photoadjustable supramolecular assembly can act as a fluorescence switch,and the phototunable guest further selectively modulate G-quadruplex structure of Tel22 upon light irradiation or with addition of CB[7].The study provides a new simple way for accurately regulating photochromic properties of molecular switches and developing smart materials with potential applications in controlled modulation of G-quadruplex,targeted biological imaging and so on. 展开更多
关键词 Supramolecular assemble Photoreponse Stiff-stilbene uril Fluorescence photoswitch Host-guest complexation
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