Two new ionone derivatives, rhododendrone A and rhododendronside, have been isolated from the alcoholic extract of the aerial parts of Rhododendron Przewalskii Maxim . The structures of the two compounds, (3R,6S)...Two new ionone derivatives, rhododendrone A and rhododendronside, have been isolated from the alcoholic extract of the aerial parts of Rhododendron Przewalskii Maxim . The structures of the two compounds, (3R,6S) -3-hydroxy- α -ionone 1 and 1,1,5-trimethyl-6-(3-hydroxyl)cyclohexene-5-yl-1- β-D -pyranoglucoside 2, have been elucidated on the basis of the spectroscopic analyses.展开更多
The crystal structure of 4-salicylideneamino-3-methyl-1,2,4-triazol-5-thione 1 (C10H10N4OS, Mr = 234.28) has been determined by single-crystal X-ray diffraction method. The crystal belongs to monoclinic, space group ...The crystal structure of 4-salicylideneamino-3-methyl-1,2,4-triazol-5-thione 1 (C10H10N4OS, Mr = 234.28) has been determined by single-crystal X-ray diffraction method. The crystal belongs to monoclinic, space group P21/n with a = 12.697(3), b = 7.4072(15), c = 12.750(3) , b = 117.68(3), V = 1061.85(4) 3, Z = 4, Dc = 1.465 g/cm3, m = 0.288 mm-1 and F(000) = 488. R = 0.0584 and wR = 0.1642 for 2660 unique reflections with 2130 observed ones (I > 2s(I)). The results confirmed that the configuration of the title compound at the azomethine C=N bond is E and 1 can be assigned as the thione tautomeric form. All atoms of the title compound are essentially coplanar.展开更多
基金Supported by the National Natural Science Foundation of China( No.2 0 2 75 0 2 0 ) and the Natural Science Foundation ofShandong Province( No.Z2 0 0 2 B0 2 )
文摘Two new ionone derivatives, rhododendrone A and rhododendronside, have been isolated from the alcoholic extract of the aerial parts of Rhododendron Przewalskii Maxim . The structures of the two compounds, (3R,6S) -3-hydroxy- α -ionone 1 and 1,1,5-trimethyl-6-(3-hydroxyl)cyclohexene-5-yl-1- β-D -pyranoglucoside 2, have been elucidated on the basis of the spectroscopic analyses.
基金The project was supported by the National Laboratory of Applied Organic Chemistry of Lanzhou University the NNSFC (20275020)+1 种基金 and the NSF of Shandong province (Z2002B02)
文摘The crystal structure of 4-salicylideneamino-3-methyl-1,2,4-triazol-5-thione 1 (C10H10N4OS, Mr = 234.28) has been determined by single-crystal X-ray diffraction method. The crystal belongs to monoclinic, space group P21/n with a = 12.697(3), b = 7.4072(15), c = 12.750(3) , b = 117.68(3), V = 1061.85(4) 3, Z = 4, Dc = 1.465 g/cm3, m = 0.288 mm-1 and F(000) = 488. R = 0.0584 and wR = 0.1642 for 2660 unique reflections with 2130 observed ones (I > 2s(I)). The results confirmed that the configuration of the title compound at the azomethine C=N bond is E and 1 can be assigned as the thione tautomeric form. All atoms of the title compound are essentially coplanar.
