The rise in the use of global polyester fiber contributed to strong demand of the Terephthalic acid(TPA).The liquid-phase catalytic oxidation of p-xylene(PX)to TPA is regarded as a critical and efficient chemical proc...The rise in the use of global polyester fiber contributed to strong demand of the Terephthalic acid(TPA).The liquid-phase catalytic oxidation of p-xylene(PX)to TPA is regarded as a critical and efficient chemical process in industry[1].PX oxidation reaction involves many complex side reactions,among which acetic acid combustion and PX combustion are the most important.As the target product of this oxidation process,the quality and yield of TPA are of great concern.However,the improvement of the qualified product yield can bring about the high energy consumption,which means that the economic objectives of this process cannot be achieved simultaneously because the two objectives are in conflict with each other.In this paper,an improved self-adaptive multi-objective differential evolution algorithm was proposed to handle the multi-objective optimization problems.The immune concept is introduced to the self-adaptive multi-objective differential evolution algorithm(SADE)to strengthen the local search ability and optimization accuracy.The proposed algorithm is successfully tested on several benchmark test problems,and the performance measures such as convergence and divergence metrics are calculated.Subsequently,the multi-objective optimization of an industrial PX oxidation process is carried out using the proposed immune self-adaptive multi-objective differential evolution algorithm(ISADE).Optimization results indicate that application of ISADE can greatly improve the yield of TPA with low combustion loss without degenerating TA quality.展开更多
The novel vertically standing Pt Se2 film on transparent quartz was prepared by selenization of platinum film deposited by the magnetron sputtering method, and an Nd:Lu VO4 passively mode-locked solid-state laser was ...The novel vertically standing Pt Se2 film on transparent quartz was prepared by selenization of platinum film deposited by the magnetron sputtering method, and an Nd:Lu VO4 passively mode-locked solid-state laser was realized by using the fabricated Pt Se2 film as a saturable absorber. The X-ray diffraction pattern and Raman spectrum of the film indicate its good crystallinity with a layered structure. The thickness of Pt Se2 film is measured to be 24 nm according to the cross-section height profile of the atomic force microscope image. Highresolution transmission electron microscopy images clearly demonstrate its vertically standing structure with an interlayer distance of 0.54 nm along the c-axis direction. The modulation depth(ΔT) and saturation fluence(Φs)of Pt Se2 film are measured to be 12.6% and 17.1 μJ∕cm2, respectively. The obtained mode-locked laser spectrum has a central wavelength of 1066.573 nm, with a 3 d B bandwidth of 0.106 nm. The transform limited pulse width of the mode-locked laser was calculated to be 15.8 ps. A maximum average output power of 180 m W with a working repetition rate of 61.3 MHz is obtained. To the best of our knowledge, this is the first report of the generation of ultrafast mode-locked laser pulses by using layered Pt Se2 as a saturable absorber.展开更多
LiFePO_(4)/C cathode materials were synthesized by a combination of co-precipitation and microwave heat-ing using polyethylene glycol(PEG)as a carbon resource and the influence of microwave heating time on the struc-t...LiFePO_(4)/C cathode materials were synthesized by a combination of co-precipitation and microwave heat-ing using polyethylene glycol(PEG)as a carbon resource and the influence of microwave heating time on the struc-ture and electrochemical performance of the materials was also discussed.The samples were characterized by X-ray diffraction(XRD),TEM,particle-size analysis and con-stant current charge-discharge experiment.The results show that the LiFePO_(4)/C heated for 9 min has a pure olive-type phase and excellent electrochemical perform-ance.The initial discharge capacities of this sample are 154.3,139.7,123.9 mAh/g at the rates 0.1C,0.2C,1C at room temperature,respectively,and after 20 cycles remain 152.3,134.3,118.5 mAh/g,respectively.展开更多
We study the exfoliation of ultrathin ReS2 nanosheets from the prepared ReS2 powder and their application to Q-switched Er-doped fiber laser.XRD,Raman,and XPS spectra confirm the successful preparation of the layered ...We study the exfoliation of ultrathin ReS2 nanosheets from the prepared ReS2 powder and their application to Q-switched Er-doped fiber laser.XRD,Raman,and XPS spectra confirm the successful preparation of the layered ReS2.SEM images show that the obtained ReS2 sheets have lateral size below 200 nm.The thickness of the ReS2 nanosheets is smaller than 5 nm according to the AFM results.ReS2/PVA film is applied as a saturable absorber in an Er-doped Q-switched fiber laser,and a minimum pulse duration of 2.4μs and an output power of 1.25 mW are obtained,indicating the potential application to Q-switched lasers.展开更多
基金Supported by the Shanghai Second Polytechnic University Key Discipline Construction-Control Theory & Control Engineering(No.XXKPY1609)the National Natural Science Foundation of China(61422303)+1 种基金Shanghai Talent Development Funding(H200-2R-15111)2017 Shanghai Second Polytechnic University Cultivation Research Program of Young Teachers(02)
文摘The rise in the use of global polyester fiber contributed to strong demand of the Terephthalic acid(TPA).The liquid-phase catalytic oxidation of p-xylene(PX)to TPA is regarded as a critical and efficient chemical process in industry[1].PX oxidation reaction involves many complex side reactions,among which acetic acid combustion and PX combustion are the most important.As the target product of this oxidation process,the quality and yield of TPA are of great concern.However,the improvement of the qualified product yield can bring about the high energy consumption,which means that the economic objectives of this process cannot be achieved simultaneously because the two objectives are in conflict with each other.In this paper,an improved self-adaptive multi-objective differential evolution algorithm was proposed to handle the multi-objective optimization problems.The immune concept is introduced to the self-adaptive multi-objective differential evolution algorithm(SADE)to strengthen the local search ability and optimization accuracy.The proposed algorithm is successfully tested on several benchmark test problems,and the performance measures such as convergence and divergence metrics are calculated.Subsequently,the multi-objective optimization of an industrial PX oxidation process is carried out using the proposed immune self-adaptive multi-objective differential evolution algorithm(ISADE).Optimization results indicate that application of ISADE can greatly improve the yield of TPA with low combustion loss without degenerating TA quality.
基金National Natural Science Foundation of China(NSFC)(61705044)One-Hundred Young Talents Program of Guangdong University of Technology(GDUT)(220413145)+1 种基金Research Grants Council,University Grants Committee(RGC,UGC)(GRF 152109/16E Poly U B-Q52T)Hong Kong Polytechnic University(Poly U)(G-YBVG)
文摘The novel vertically standing Pt Se2 film on transparent quartz was prepared by selenization of platinum film deposited by the magnetron sputtering method, and an Nd:Lu VO4 passively mode-locked solid-state laser was realized by using the fabricated Pt Se2 film as a saturable absorber. The X-ray diffraction pattern and Raman spectrum of the film indicate its good crystallinity with a layered structure. The thickness of Pt Se2 film is measured to be 24 nm according to the cross-section height profile of the atomic force microscope image. Highresolution transmission electron microscopy images clearly demonstrate its vertically standing structure with an interlayer distance of 0.54 nm along the c-axis direction. The modulation depth(ΔT) and saturation fluence(Φs)of Pt Se2 film are measured to be 12.6% and 17.1 μJ∕cm2, respectively. The obtained mode-locked laser spectrum has a central wavelength of 1066.573 nm, with a 3 d B bandwidth of 0.106 nm. The transform limited pulse width of the mode-locked laser was calculated to be 15.8 ps. A maximum average output power of 180 m W with a working repetition rate of 61.3 MHz is obtained. To the best of our knowledge, this is the first report of the generation of ultrafast mode-locked laser pulses by using layered Pt Se2 as a saturable absorber.
基金supported by Shanghai Leading Academic Discipline Project(No.B502).
文摘LiFePO_(4)/C cathode materials were synthesized by a combination of co-precipitation and microwave heat-ing using polyethylene glycol(PEG)as a carbon resource and the influence of microwave heating time on the struc-ture and electrochemical performance of the materials was also discussed.The samples were characterized by X-ray diffraction(XRD),TEM,particle-size analysis and con-stant current charge-discharge experiment.The results show that the LiFePO_(4)/C heated for 9 min has a pure olive-type phase and excellent electrochemical perform-ance.The initial discharge capacities of this sample are 154.3,139.7,123.9 mAh/g at the rates 0.1C,0.2C,1C at room temperature,respectively,and after 20 cycles remain 152.3,134.3,118.5 mAh/g,respectively.
基金Project supported by the Pearl River Talent Program of Guangdong Province,China(No.2017GC010278)the Science and Technology Program of Guangzhou,China(No.202002030027)+1 种基金the National Natural Science Foundation of China(No.61705044)the Distinctive Innovation Project of Regular Colleges in Guangdong Province,China(No.2018KTSCX052)。
文摘We study the exfoliation of ultrathin ReS2 nanosheets from the prepared ReS2 powder and their application to Q-switched Er-doped fiber laser.XRD,Raman,and XPS spectra confirm the successful preparation of the layered ReS2.SEM images show that the obtained ReS2 sheets have lateral size below 200 nm.The thickness of the ReS2 nanosheets is smaller than 5 nm according to the AFM results.ReS2/PVA film is applied as a saturable absorber in an Er-doped Q-switched fiber laser,and a minimum pulse duration of 2.4μs and an output power of 1.25 mW are obtained,indicating the potential application to Q-switched lasers.
