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Cyanide-bridged W~ⅤMn~Ⅲ single-chain magnet based on an octacoordinate [W(CN)_6(phen)]^- anion 被引量:2
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作者 LEE JinWuk lim kwangsoo +4 位作者 YOON JungHee RYU DaeWon KOO BongHo KOH EuiKwan HONG ChangSeop 《Science China Chemistry》 SCIE EI CAS 2012年第6期1012-1017,共6页
Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a wv(5d)-Mnm(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex featur... Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a wv(5d)-Mnm(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet. 展开更多
关键词 tungsten MANGANESE CYANIDE crystal structure single-chain magnet
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