本研究建立了AMS(Accelerator mass spectrum,加速器质谱)测定海水中129 I的气载分离制样方法:对加入载体的海水样品进行氧化还原处理,在加热的条件下将生成的单质碘吹出,并使用吸收装置吸收,后经阴离子交换树脂富集纯化,最后生成用于AM...本研究建立了AMS(Accelerator mass spectrum,加速器质谱)测定海水中129 I的气载分离制样方法:对加入载体的海水样品进行氧化还原处理,在加热的条件下将生成的单质碘吹出,并使用吸收装置吸收,后经阴离子交换树脂富集纯化,最后生成用于AMS分析的AgI沉淀,本方法全程回收率50%~70%,在相对密闭的体系中进行,减少了碘的损失,相对于萃取-反萃取的制样方法具有可操作性强,避免有机试剂使用等优点,可用于固态、液态和气态样品中129 I的AMS分析制样。展开更多
The long-lived isotope ^(53)Mn cosmogenically produced in situ is a very useful indicator for geochronological dating.A new ^(53)Mn accelerator−mass-spectrometry(AMS)measurement method is developed based on the HI-13 ...The long-lived isotope ^(53)Mn cosmogenically produced in situ is a very useful indicator for geochronological dating.A new ^(53)Mn accelerator−mass-spectrometry(AMS)measurement method is developed based on the HI-13 Tandem Accelerator andΔE−Q3D detection system at China Institute of Atomic Energy.The performance of ^(53)Cr isobar separation and suppression is tested by a series of ^(53)Mn standards and commercial MnO samples.The results show that theΔE−Q3D detection system brought about an overall suppression factor of more than 107 for the interfering isobar ^(53)Cr.展开更多
文摘本研究建立了AMS(Accelerator mass spectrum,加速器质谱)测定海水中129 I的气载分离制样方法:对加入载体的海水样品进行氧化还原处理,在加热的条件下将生成的单质碘吹出,并使用吸收装置吸收,后经阴离子交换树脂富集纯化,最后生成用于AMS分析的AgI沉淀,本方法全程回收率50%~70%,在相对密闭的体系中进行,减少了碘的损失,相对于萃取-反萃取的制样方法具有可操作性强,避免有机试剂使用等优点,可用于固态、液态和气态样品中129 I的AMS分析制样。
基金the National Natural Science Foundation of China under Grant Nos 11075221 and 10705054.
文摘The long-lived isotope ^(53)Mn cosmogenically produced in situ is a very useful indicator for geochronological dating.A new ^(53)Mn accelerator−mass-spectrometry(AMS)measurement method is developed based on the HI-13 Tandem Accelerator andΔE−Q3D detection system at China Institute of Atomic Energy.The performance of ^(53)Cr isobar separation and suppression is tested by a series of ^(53)Mn standards and commercial MnO samples.The results show that theΔE−Q3D detection system brought about an overall suppression factor of more than 107 for the interfering isobar ^(53)Cr.
