Spherical macroporous adsorbents with active sites capable of hydrogen bonding adsorption based on urea-formaldehyde condensed polymer were synthesized via reversed suspension polymerization. The properties of the obt...Spherical macroporous adsorbents with active sites capable of hydrogen bonding adsorption based on urea-formaldehyde condensed polymer were synthesized via reversed suspension polymerization. The properties of the obtained adsorbent were also investigated in detail. The results showed that the water permeability could be improved by adding hydroxyl-containing organic compound moiety into the adsorbent. The specific surface area and average pore diameter of these adsorbents increased while the porosity first increased then decreased with the increase of the amount of the added hydroxyl-containing compound.展开更多
A rapid method has been developed for rapid sample clean-up in the determination of the pharmocologically active terpenoid including ginkgolide A, B. C and bilobalide in ginkgo biloba leaves extracts (GBE). The extrac...A rapid method has been developed for rapid sample clean-up in the determination of the pharmocologically active terpenoid including ginkgolide A, B. C and bilobalide in ginkgo biloba leaves extracts (GBE). The extracts are dissolved in 7% of ethanol aqueous solution and then purified by a highly selective polymeric absorbent solid-phase chromatographic column. After being concentrated, the separated terpenoids with no phenolic disturbance are determined by highperformance liquid chromatography on a Nova-Pak C18 column with methanol-water (30:70) as effluent and refractive index defection. The recovery of the method is about 95% and the new method saves more time than the conventional two-column purification method.展开更多
The relationship between the adsorption properties for the active components of ginkgo leaves and the structure of the adsorbents based on urea-formaldehyde condensed polymers was investigated .The results revealed th...The relationship between the adsorption properties for the active components of ginkgo leaves and the structure of the adsorbents based on urea-formaldehyde condensed polymers was investigated .The results revealed that these adsorbents showed very hjgh adsorption selectivity for both flavonol glycosides and terpene lactones contained in ginkgo leaves. Thus, an adsorption separation procedure for purification of ginkgo leaves extracts was developed.展开更多
Absorption of phenol, catechol and resorcinol. which vary in their ability to interact with the adsorbent through hydrogen bond, were used to investigate the adsorption mechanistic interaction. The adsorption enthalpi...Absorption of phenol, catechol and resorcinol. which vary in their ability to interact with the adsorbent through hydrogen bond, were used to investigate the adsorption mechanistic interaction. The adsorption enthalpies of the above mentioned compound onto the adsorbent were calculated and thermodynamic analysis was carried out. The results showed the adsorbent with the lowest adsorption enthalpies for the sorbate such as catechol with intermolecular hydrogen bond also display the lowest adsorption affinity On the other hand the more of the groups available for hydrogen bond interaction. the higher of the adsorption affinity These observations support the contention that phenol adsorption is driven predominantly by specific interaction of the solute with active sites on the surface of the adsorbent.展开更多
基金uported by the National Natural Science Foundation of China !(Grant No. 29574164)
文摘Spherical macroporous adsorbents with active sites capable of hydrogen bonding adsorption based on urea-formaldehyde condensed polymer were synthesized via reversed suspension polymerization. The properties of the obtained adsorbent were also investigated in detail. The results showed that the water permeability could be improved by adding hydroxyl-containing organic compound moiety into the adsorbent. The specific surface area and average pore diameter of these adsorbents increased while the porosity first increased then decreased with the increase of the amount of the added hydroxyl-containing compound.
基金Supported by the National Natural Science Foundation of China !(Grant No. 29574164)
文摘A rapid method has been developed for rapid sample clean-up in the determination of the pharmocologically active terpenoid including ginkgolide A, B. C and bilobalide in ginkgo biloba leaves extracts (GBE). The extracts are dissolved in 7% of ethanol aqueous solution and then purified by a highly selective polymeric absorbent solid-phase chromatographic column. After being concentrated, the separated terpenoids with no phenolic disturbance are determined by highperformance liquid chromatography on a Nova-Pak C18 column with methanol-water (30:70) as effluent and refractive index defection. The recovery of the method is about 95% and the new method saves more time than the conventional two-column purification method.
基金Supported by the National Natural Science Foundation of China !(Grant No. 29574164).
文摘The relationship between the adsorption properties for the active components of ginkgo leaves and the structure of the adsorbents based on urea-formaldehyde condensed polymers was investigated .The results revealed that these adsorbents showed very hjgh adsorption selectivity for both flavonol glycosides and terpene lactones contained in ginkgo leaves. Thus, an adsorption separation procedure for purification of ginkgo leaves extracts was developed.
基金Supported by the National Natural Science Foundation of China !(Grant No. 29574164 and 29974015)
文摘Absorption of phenol, catechol and resorcinol. which vary in their ability to interact with the adsorbent through hydrogen bond, were used to investigate the adsorption mechanistic interaction. The adsorption enthalpies of the above mentioned compound onto the adsorbent were calculated and thermodynamic analysis was carried out. The results showed the adsorbent with the lowest adsorption enthalpies for the sorbate such as catechol with intermolecular hydrogen bond also display the lowest adsorption affinity On the other hand the more of the groups available for hydrogen bond interaction. the higher of the adsorption affinity These observations support the contention that phenol adsorption is driven predominantly by specific interaction of the solute with active sites on the surface of the adsorbent.