Heterojunction composites were prepared by silane coupling agent grafting from synthesized graphitic carbon nitride(g-C_(3)N_(4))and commercially available zirconia(ZrO_(2)).The samples were characterized by X-ray dif...Heterojunction composites were prepared by silane coupling agent grafting from synthesized graphitic carbon nitride(g-C_(3)N_(4))and commercially available zirconia(ZrO_(2)).The samples were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),Fourier transform infrared(FT-IR)spectroscopy,UV-vis diffuse reflectance spectroscopy(DRS),photoluminescence(PL)spectroscopy,and electrochemical impedance spectroscopy(EIS).The photocatalytic activity of the composites was evaluated by the degradation of methylene blue(MB)under visible light irradiation.The results showed that heterojunction composites of g-C_(3)N_(4) and ZrO_(2) could be successfully prepared by coupling agent grafting.The optimal mass ratio of g-C_(3)N_(4) and ZrO_(2) was 2:1,with an activity that was 3.8 times higher than g-C_(3)N_(4) and 15.3 times higher than ZrO_(2).This was ascribed to the stronger light absorption,faster interfacial charge transfer,and lower photogenerated carrier recombination of the heterojunction composites.展开更多
BiVO4, BiVO4@C3N4 and BiVO4@C3N4@GO composite photo-catalysts were synthesized, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission elec...BiVO4, BiVO4@C3N4 and BiVO4@C3N4@GO composite photo-catalysts were synthesized, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), Fourier transform infrared spectroscopy (FT-IR), and Brunauer-Emmett-Teller (BET) surface area techniques. The photocatalytic activity was evaluated on the degradation of methylene blue (MB) under visible light irradiation, which denoted that the BiVO4@C3N4@GO ternary composite outperformed the binary composite BiVO4@C3N4 and BiVO4. Then the effects of catalyst dosage, initial pH value, and initial methylene blue concentration on the degradation process were investigated systematically. The improvement of visible-light photocatalytic degradation performance was attributed to the enhanced visible light absorption, larger surface area, higher adsorption ability, and prolonged lifetime of photo-generated electron-hole pairs. The recycle experiments results showed that the BiVO4@C3N4@GO composite had excellent photo-stability for MB photocatalytic degradation.展开更多
In this work, the removal of thiophene from simulated oil has been studied by using the adsorption, extraction and oxidation/adsorption methods, respectively. In the adsorptive desulfurization process, different comme...In this work, the removal of thiophene from simulated oil has been studied by using the adsorption, extraction and oxidation/adsorption methods, respectively. In the adsorptive desulfurization process, different commercial adsorbents were used to eliminate thiophene at ambient pressure and mild temperature, and the results showed that carbon powder had the best adsorption ability. In the extractive desulfurization process, the best desulfurization result was obtained when DMF is used. In the oxidative/adsorptive desulfurization procedure using synthesized potassium ferrate as the oxidant and phosphomolybdic acid solution as the catalyst, thiophene was oxidized and removed from hydrocarbons in combination with active carbon adsorption, and the residual sulfur content of simulated oil could be reduced to 15.3mg/L from the original level of 200mg/L, with the desulfurization rate reaching 92.3%.展开更多
基金Natural Science Foundation of Heilongjiang Province of China(LH2022E030)National Natural Science Foundation of China(21905042).
文摘Heterojunction composites were prepared by silane coupling agent grafting from synthesized graphitic carbon nitride(g-C_(3)N_(4))and commercially available zirconia(ZrO_(2)).The samples were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),Fourier transform infrared(FT-IR)spectroscopy,UV-vis diffuse reflectance spectroscopy(DRS),photoluminescence(PL)spectroscopy,and electrochemical impedance spectroscopy(EIS).The photocatalytic activity of the composites was evaluated by the degradation of methylene blue(MB)under visible light irradiation.The results showed that heterojunction composites of g-C_(3)N_(4) and ZrO_(2) could be successfully prepared by coupling agent grafting.The optimal mass ratio of g-C_(3)N_(4) and ZrO_(2) was 2:1,with an activity that was 3.8 times higher than g-C_(3)N_(4) and 15.3 times higher than ZrO_(2).This was ascribed to the stronger light absorption,faster interfacial charge transfer,and lower photogenerated carrier recombination of the heterojunction composites.
基金the Natural Science Foundation of Heilongjiang Province of China [QC2017005]the Province Postdoctoral Fund [LBH-Z15032]
文摘BiVO4, BiVO4@C3N4 and BiVO4@C3N4@GO composite photo-catalysts were synthesized, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), Fourier transform infrared spectroscopy (FT-IR), and Brunauer-Emmett-Teller (BET) surface area techniques. The photocatalytic activity was evaluated on the degradation of methylene blue (MB) under visible light irradiation, which denoted that the BiVO4@C3N4@GO ternary composite outperformed the binary composite BiVO4@C3N4 and BiVO4. Then the effects of catalyst dosage, initial pH value, and initial methylene blue concentration on the degradation process were investigated systematically. The improvement of visible-light photocatalytic degradation performance was attributed to the enhanced visible light absorption, larger surface area, higher adsorption ability, and prolonged lifetime of photo-generated electron-hole pairs. The recycle experiments results showed that the BiVO4@C3N4@GO composite had excellent photo-stability for MB photocatalytic degradation.
基金financially supported by the Science and Technology Program of the Department of Education,Heilongjiang Province(11531012)
文摘In this work, the removal of thiophene from simulated oil has been studied by using the adsorption, extraction and oxidation/adsorption methods, respectively. In the adsorptive desulfurization process, different commercial adsorbents were used to eliminate thiophene at ambient pressure and mild temperature, and the results showed that carbon powder had the best adsorption ability. In the extractive desulfurization process, the best desulfurization result was obtained when DMF is used. In the oxidative/adsorptive desulfurization procedure using synthesized potassium ferrate as the oxidant and phosphomolybdic acid solution as the catalyst, thiophene was oxidized and removed from hydrocarbons in combination with active carbon adsorption, and the residual sulfur content of simulated oil could be reduced to 15.3mg/L from the original level of 200mg/L, with the desulfurization rate reaching 92.3%.
