期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
手性5,5′-双(二苯基磷)-4,4′-二-1,3-苯并二噁唑的合成工艺
1
作者 李云飞 周铎 +3 位作者 赵顺伟 孙敏青 张垚 陈辉 《合成材料老化与应用》 2020年第5期45-47,24,共4页
将4-溴-1,2-亚甲二氧基苯与金属镁反应得到格式试剂后再与二苯基次膦酰氯进行反应,合成亚甲二氧基苯基膦酰,碘代后经乌尔曼偶联形成双二苯基膦酰结构,经过手性拆分后得到5,5'-双(二苯基磷酰)-4,4'-二-1,3-苯并二噁唑,最后用三... 将4-溴-1,2-亚甲二氧基苯与金属镁反应得到格式试剂后再与二苯基次膦酰氯进行反应,合成亚甲二氧基苯基膦酰,碘代后经乌尔曼偶联形成双二苯基膦酰结构,经过手性拆分后得到5,5'-双(二苯基磷酰)-4,4'-二-1,3-苯并二噁唑,最后用三氯硅烷还原后得到对空气稳定手性配体的(R)-(+)-5,5'-双(二苯基磷)-4,4'-二-1,3-苯并二噁唑。其结构经过核磁进行了表征。 展开更多
关键词 手性配体 合成 偶联 手性拆分 还原
下载PDF
Quantitative Roughness Analysis of Post-harvest Agaricus bisporus by Atomic Force Microscopy 被引量:4
2
作者 YANGHong-Shun FENGGuo-Ping +1 位作者 ANHong-Jie liyun-fei 《Acta Botanica Sinica》 CSCD 2004年第10期1249-1255,共7页
The moisture loss degree is important in determining the quality of post-harvest mushroom (Agaricus bisporus (Lange) Sing). Quantitative roughness analyzed by atomic force microscopy (AFM) was proposed to denote the d... The moisture loss degree is important in determining the quality of post-harvest mushroom (Agaricus bisporus (Lange) Sing). Quantitative roughness analyzed by atomic force microscopy (AFM) was proposed to denote the degree of shrinkage, with arithmetic average roughness (Ra) and root mean square roughness (Rq) as parameters, The initial value of Ra was (30.035±1.839)nm, while those of 2℃, 25℃ and dynamic temperature on the 2nd day were (40.139±3.359) nm, (54.393±13.534) nm and (41.197±6.555) nm, respectively. There is a similar tendency for the results of Ra and Rq Both values of roughness increased in duration of storage and with increasing temperatures. The three-dimensional profile of the pileus epicutis could signify the process of water evaporation intuitionally. The tendency was in accordance with the roughness results, especially for the earlier stage of the storage (0-2 d). The outcome of roughness analysis could signify the differences of storage conditions. It was shown that the roughness measured by atomic force microscopy effectively reflected the moisture loss degree of the mushroom pileus epicutis during post-harvest storage. 展开更多
关键词 原子力显微镜 伞菌属 蘑菇 采收 湿度
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部