粉煤灰和硅粉对混凝土强度影响的试验研究

混凝土是指由胶凝材料将骨料胶结成整体的工程复合材料的统称,而自混凝土应用到土木工程中,人们就不断尝试通过各个途径提高混凝土的强度和耐久性,在此通过在混凝土中加入粉煤灰和硅粉来替代部分水泥。通过对照试验,采用控制变量的方法,取用计划对照掺量的粉煤灰、硅粉,并通过对照实验和控制变量分析出各个掺量的粉煤灰、硅粉对混凝土的工作性、抗压强度、劈拉强度、抗弯拉强度等的影响。对照结果表明:粉煤灰和硅粉都可不同程度的改善混凝土的工作性能。粉煤灰对混凝土的影响主要在强度增长的后期;而硅粉则与粉煤灰不同,主要影响在强度增长的前期,后期则显缓慢,但定量的硅粉却能使混凝土具有更好的抗折强度和抗冲击耐磨性。

Effect of reduction-oxidation treatment on the properties of VSb_3W-Al_2O_3 catalyst for propane ammoxidation

VSb3W-Al2O3 catalysts for propane ammoxidation were prepared by the conventional slurry method and new slurry method,namely,the reduction-oxidation slurry method.The effect of preparation methods on the physicochemical properties of VSb3W-Al2O3 catalysts were studied by N2 adsorption,XRD,XPS and Raman spectroscopy,and their catalytic performance for the ammoxidation of propane to acrylonitrile were tested.Compared with the VSb3W-Al2O3 catalyst prepared by the conventional slurry method,the VSb3W-Al2O3 catalyst prepared by the reduction-oxidation slurry method exhibited better propane conversion and acrylonitrile selectivity.This is due to that the reduction-oxidation treatment was advantageous for obtaining low valence state vanadium and high valence state antimony to form more rutile SbVO4,which is a vital active phase for propane ammoxidation.