The multi-bond dissociation dynamics of oxalyl bromide ((BrCO)2) has been investigated by DFT and CIS calculations. Upon the results, conclusion could be drawn that dissociation of C-Br bond of oxalyl bromide at t...The multi-bond dissociation dynamics of oxalyl bromide ((BrCO)2) has been investigated by DFT and CIS calculations. Upon the results, conclusion could be drawn that dissociation of C-Br bond of oxalyl bromide at the ground state (So) is of barfierless. After the absorption of a photon, (BrCO)2 is excited to the first excited state and one of its C-Br bonds is broken to yield Br ·* and BrCOCO· * free radicals. In addition, BrCOCO · * with high energy is apt to release energy, and ultimately, turns into BrCOCO ·of the ground state. The energy is adequate for BrCOCO· to break down into Br · and 2CO; at the same time the C-C and C-Br bonds of BrCOCO · free radicals dissociate.展开更多
In order to understand the function of TuR2, a candidate disease-resistance gene was isolated from cabbage, we transformed it into mustard (Brassicajuncea L. Linshicaoyaozi) which was susceptible to TuMV through Agr...In order to understand the function of TuR2, a candidate disease-resistance gene was isolated from cabbage, we transformed it into mustard (Brassicajuncea L. Linshicaoyaozi) which was susceptible to TuMV through Agrobacterium tumefacine-mediated method. Transgenic plants were detected by Southern blotting and Northern blotting. Our results confirmed that the TuR2 gene had been integrated into the mustard genome, and it showed different expression levels among primary transplants (T0). The primary transplants (T0) and the first progenies of transgenic plants (T1) were inoculated with TuMV in a greenhouse. The transgenic plants had high TuMV-resistance, whereas the serious virus disease symptom was observed in CK (no transformation plants). The TuR2 gene in the first progenies of transgenic plants (T1) showed dominant monogenic inheritance. Compared with CK, the progenies containing TuR2 gene had stronger resistance to TuMV. The TuR2 gene which was isolated from cabbage had the function of TuMV-resistance.展开更多
基金This research was financially supported by the Key Laboratory Foundation of Polymer Materials of Gansu Province
文摘The multi-bond dissociation dynamics of oxalyl bromide ((BrCO)2) has been investigated by DFT and CIS calculations. Upon the results, conclusion could be drawn that dissociation of C-Br bond of oxalyl bromide at the ground state (So) is of barfierless. After the absorption of a photon, (BrCO)2 is excited to the first excited state and one of its C-Br bonds is broken to yield Br ·* and BrCOCO· * free radicals. In addition, BrCOCO · * with high energy is apt to release energy, and ultimately, turns into BrCOCO ·of the ground state. The energy is adequate for BrCOCO· to break down into Br · and 2CO; at the same time the C-C and C-Br bonds of BrCOCO · free radicals dissociate.
基金supported by the National Natural Science Foundation of China(30270912)Postdoctoral Foundation of China(2003033410).
文摘In order to understand the function of TuR2, a candidate disease-resistance gene was isolated from cabbage, we transformed it into mustard (Brassicajuncea L. Linshicaoyaozi) which was susceptible to TuMV through Agrobacterium tumefacine-mediated method. Transgenic plants were detected by Southern blotting and Northern blotting. Our results confirmed that the TuR2 gene had been integrated into the mustard genome, and it showed different expression levels among primary transplants (T0). The primary transplants (T0) and the first progenies of transgenic plants (T1) were inoculated with TuMV in a greenhouse. The transgenic plants had high TuMV-resistance, whereas the serious virus disease symptom was observed in CK (no transformation plants). The TuR2 gene in the first progenies of transgenic plants (T1) showed dominant monogenic inheritance. Compared with CK, the progenies containing TuR2 gene had stronger resistance to TuMV. The TuR2 gene which was isolated from cabbage had the function of TuMV-resistance.