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九龙江沉积物主要组分对四环素类抗生素吸附性能对比 被引量:4
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作者 李宗宸 魏群山 +4 位作者 罗专溪 徐龙凤 刘亚男 颜昌宙 柳建设 《生态环境学报》 CSCD 北大核心 2016年第10期1714-1720,共7页
沉积物作为一种重要的水体环境介质,因其复杂的组成结构和时空差异性而具有巨大的研究前景,抗生素滥用引起的环境污染同样引起了广泛关注。四环素类抗生素(TCs)形态结构复杂,能够以多种方式被沉积物吸附。为了更深入地了解四环素... 沉积物作为一种重要的水体环境介质,因其复杂的组成结构和时空差异性而具有巨大的研究前景,抗生素滥用引起的环境污染同样引起了广泛关注。四环素类抗生素(TCs)形态结构复杂,能够以多种方式被沉积物吸附。为了更深入地了解四环素类抗生素在河流中的迁移转化规律,以四环素和土霉素作为研究对象,采用选择性萃取方法分离出九龙江沉积物中起主要吸附作用的组分(铁氧化物、锰氧化物、有机质)并获得各组分的含量,运用等温平衡吸附法在TCs与沉积物质量比为0.01~0.06范围内进行吸附试验,利用Langmuir和Freundlich吸附等温方程拟合吸附过程并进行统计分析,从而研究各组分对TCs的吸附特征、能力和吸附贡献量。结果表明,沉积物及其主要组分对TCs的吸附过程特征符合Langmuir吸附等温方程,相关系数达0.95以上;沉积物中各组分对TCs的吸附能力大小顺序为锰氧化物>有机质>铁氧化物>残渣态;各组分对TCs的绝对吸附贡献量大小顺序为锰氧化物>残渣态>铁氧化物>有机质。其中,锰氧化物在沉积物中所占比例较小,只有0.05%,却对TCs的吸附贡献率最大(56%),所采集的九龙江典型沉积物对TCs的吸附起最主要和关键作用的组分是锰氧化物。不同地理位点的沉积物理化性质差异很大,对TCs的吸附能力与锰氧化物含量有一定的相关性,这验证了前述结论。 展开更多
关键词 四环素 九龙江 沉积物 主要组分 吸附
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海洋环境中微塑料的生态毒性效应研究进展 被引量:5
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作者 王丽媛 罗专溪 +1 位作者 颜昌宙 郭建华 《环境科学与技术》 CAS CSCD 北大核心 2019年第S02期76-82,共7页
微塑料由于颗粒小难去除分布广等特性,成为日益备受关注的一种新型污染物,尤其是在海洋环境中。该文参考了近年来国内外关于微塑料的报道,从来源、分布以及其对生态系统的影响等方面综述了微塑料在海洋环境中的生态毒性效应。其中对生... 微塑料由于颗粒小难去除分布广等特性,成为日益备受关注的一种新型污染物,尤其是在海洋环境中。该文参考了近年来国内外关于微塑料的报道,从来源、分布以及其对生态系统的影响等方面综述了微塑料在海洋环境中的生态毒性效应。其中对生态系统的影响主要包括:对动植物造成损伤、随营养级积累、释放和吸附有毒物质、微生物载体等四方面。并提出后续关注方向,如加强纤维与轮胎细颗粒等类型微塑料、微塑料与其它污染物联合吸附暴露风险以及从源头防控策略等方面研究。 展开更多
关键词 微塑料 海洋环境 生态毒性 载体
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《环境保护与可持续发展》远程教学实践 被引量:2
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作者 林惠荣 闫钰 +3 位作者 胡恭任 于瑞莲 罗专溪 翁铂森 《广东化工》 CAS 2021年第4期223-225,共3页
新型冠状肺炎疫情以来,为了响应教育部“停课不停教、停课不停学”的号召,全国各大高校陆续开展远程课程教育。依托于互联网技术的远程混合式教学模式作为一种新型的教学形式得到迅速的发展,并大大推进了高等教育的信息化进程。环境保... 新型冠状肺炎疫情以来,为了响应教育部“停课不停教、停课不停学”的号召,全国各大高校陆续开展远程课程教育。依托于互联网技术的远程混合式教学模式作为一种新型的教学形式得到迅速的发展,并大大推进了高等教育的信息化进程。环境保护与可持续发展是我校面向不同专业、不同国籍本科生开设的一门通识选修课程。本文探讨了本校环境保护与可持续发展团队在新冠疫情防控期间,基于中国大学MOOC和腾讯会议直播建立的环境保护与可持续发展远程混合式教学模式,为进一步推动本课程的教学模式、教学内容和教学方法的改革,提高教学质量和教学效果提供新思路。 展开更多
关键词 环境保护与可持续发展 混合式教学 远程教学
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Stormwater Runoff Pollution in a Rural Township in the Hilly Area of the Central Sichuan Basin,China 被引量:1
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作者 luo zhuanxi WANG Tao +2 位作者 GAO Meirong TANG Jialiang ZHU Bo 《Journal of Mountain Science》 SCIE CSCD 2012年第1期16-26,共11页
Stormwater runoff in rural townships has a high potential for water quality impairment but little information is available on strormwater runoff pollution from rural townships.To investigate the characteristics of run... Stormwater runoff in rural townships has a high potential for water quality impairment but little information is available on strormwater runoff pollution from rural townships.To investigate the characteristics of runoff pollution in a rural township,a catchment(2.32 ha) in Linshan Township,Sichuan,China was selected to examine runoff and quality parameters including precipitation,flow rate,and total nitrogen(TN),dissolved nitrogen(DN),total phosphorus(TP),dissolved phosphorus(DP),particulate phosphorus(PP),chemical oxygen demand(COD) and suspended solid(SS) in 12 rainfall events occurring between June 2006 and July 2007.Results show that the annual pollutant loads were 47.17 kg ha-1 for TN,6.64 kg ha-1 for TP,1186 kg ha-1 for COD,and 4297 kg ha-1 for SS.DN and PP were the main forms of nitrogen and phosphorus in stormwater runoff.TP,COD and SS showed medium mass first flushes,in which nearly 40% of the total pollutant masses were transported by the first 30% of total flow volume.The peak of pollutant concentration appeared before the peak of runoff due to the first flush of accumulative pollutants in impervious areas and drainage ditches.The EMC values of TN,TP,DN and PP were negatively correlated to the maximum rainfall intensity,precipitation,total flow volume,and runoff duration(P<0.05,n=12),while EMC of COD and SS were not related to any rainfall characteristics.The FF30(FF,First Flush) for TN,TP,COD and SS were positively correlated to the maximum rainfall intensity(P<0.05,n=12),and TP was also positively correlated to the average rainfall intensity(P<0.05,n=12),indicating that the magnitude of first flush increased with the rainfall intensity in the Linshan Township. 展开更多
关键词 First flush Pollutant EMC Storm water Runoff Load
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苯-砷共存对铜绿微囊藻的毒性和砷累积效应
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作者 陈艳 王振红 +1 位作者 罗专溪 黄明强 《闽南师范大学学报(自然科学版)》 2022年第1期68-76,共9页
为更好地认识微量有机污染物苯和砷联合暴露中蓝藻的生长及砷累积效应,探究了水环境中0.1 mg/L苯存在时铜绿微囊藻对砷酸盐(As(Ⅴ))的适应性以及藻体砷累积和对环境中有机物(TOC)及藻毒素(MCs)含量的影响.结果表明,0.1 mg/L苯存在时铜... 为更好地认识微量有机污染物苯和砷联合暴露中蓝藻的生长及砷累积效应,探究了水环境中0.1 mg/L苯存在时铜绿微囊藻对砷酸盐(As(Ⅴ))的适应性以及藻体砷累积和对环境中有机物(TOC)及藻毒素(MCs)含量的影响.结果表明,0.1 mg/L苯存在时铜绿微囊藻对As(Ⅴ)的适应性.显著降低,主要表现为高浓度As(Ⅴ)(1000.0 mg/L)显著降低藻体光密度(OD_(680))与叶绿素a(Chl-a)及实际光合产率(Yield).由OD_(680)、Chl-a、Yield得到0.1 mg/L苯环境下铜绿微囊藻对As(Ⅴ)的96 h半致死浓度(IC_(50))表现为Chl-a<OD_(680)<Yield,且由Chl-a得到的96 h IC_(50)为2.23×10^(3) mg/L,最大允许毒物浓度(MATC)为316.23 mg/L.Chl-a可做为敏感指标观测0.1 mg/L苯含砷水体中该藻的生长.微量苯(0.1 mg/L)存在时铜绿微囊藻通过增加TOC的释出来适应砷毒性,且显著降低该藻在1.0和1000.0 mg/LAs(Ⅴ)浓度下MCs的释出含量.微量苯的存在可促进铜绿微囊藻胞内As的累积,并使1.0 mg/LAs(Ⅴ)作用下MCs的释出以及0.1和1.0 mg/LAs(Ⅴ)作用下TOC的释出显著降低,而As(Ⅴ)的添加降低了0.1 mg/L苯环境下藻体TOC及MCs的含量.研究结果对深入了解实际水环境中微量有机苯与无机砷污染共存时的微藻砷去除及生态风险具有重要意义. 展开更多
关键词 铜绿微囊藻 砷酸盐 IC_(50) 藻毒素 砷累积
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Distributive Characteristics of Metallic Nano-particles in China's Urban Water Bodies and their Ecological Risks
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作者 GAO Yang luo zhuanxi XIA Jun 《Bulletin of the Chinese Academy of Sciences》 2012年第1期99-103,共5页
Engineering nano-materials & their impact on human health or environmental security constitute a newly emerging R&D hot spot and a key problem now urgently waiting for its solution in supporting the sustainabi... Engineering nano-materials & their impact on human health or environmental security constitute a newly emerging R&D hot spot and a key problem now urgently waiting for its solution in supporting the sustainability of China's nano-science and related technology development. At present, water bodies in Chinese cities have been seriously polluted by metallic nano-particles (MNPs) while related monitoring data are found woefully lacking throughout the country. Based on the above understanding, this article gives a round-up explanation on distributive characteristics of MNPs in the river mouths or water bodies of Chinese cities, their ecological hazards as well as our research in this regard, providing some inspiring ideas and data for control over this scourge. In addition, our exploration probes the discharge traits of MNPs themselves and the mechanism underlying its impact on water pollution. 展开更多
关键词 metallic nano-particles (MNPs) water body pollution in cities ecological risks
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氮磷比对有机磷环境中微藻砷代谢的生态风险效应
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作者 赵曜 柳彩霞 +2 位作者 杨轶丹 罗专溪 王振红 《微生物学报》 CAS CSCD 北大核心 2023年第3期1230-1242,共13页
【目的】探究了以单酯磷D-葡萄糖-6-磷酸二钠(D-glucose-6-disodium phosphate,GP)为唯一磷源时含砷(As5+)水体中不同氮磷质量比对铜绿微囊藻(Microcystis aeruginosa)生长及砷代谢和微囊藻毒素(microcystins,MCs)释出的影响。【方法】... 【目的】探究了以单酯磷D-葡萄糖-6-磷酸二钠(D-glucose-6-disodium phosphate,GP)为唯一磷源时含砷(As5+)水体中不同氮磷质量比对铜绿微囊藻(Microcystis aeruginosa)生长及砷代谢和微囊藻毒素(microcystins,MCs)释出的影响。【方法】将氮磷饥饿状态的藻细胞于含砷水体中不同氮磷比条件下进行实验,通过测定藻细胞密度(OD680)、叶绿素a(chlorophyll a,Chla)、实际光合产率(Yield)、超氧化物歧化酶(superoxide dismutase,SOD)、砷的存在形态以及微囊藻毒素含量,分析该藻在砷胁迫下的生理响应以及砷代谢机制。【结果】氮磷饥饿状态藻细胞对较高GP水平(0.1 mg/L)下的低氮磷比有更好的适应性,较低GP水平(0.02 mg/L)下的高氮磷比能显著促进培养初期藻细胞的OD680、Chla和Yield;SOD在培养初期与末期受氮磷比影响显著。GP环境下铜绿微囊藻经8 d培养后氮磷比为10:0.1介质中的砷表现为以亚砷酸盐(As^(3+))为主,占水体总砷(total arsenic,TAs)含量的78.8%,其余氮磷比环境中仍以As^(5+)为主,藻体砷形态则均以As^(5+)为主,氮磷比为1:0.1时有机砷占藻体TAs比例最高。藻细胞砷代谢受GP水平影响显著,较高GP环境(0.1 mg/L)下砷的代谢总量也更高,氮磷比为10:0.1时砷代谢以As^(5+)的还原和As^(3+)释出为主,低GP环境下(0.02 mg/L)砷代谢的甲基化水平提高。介质中MCs的含量与GP水平有关,较高GP的低氮磷比水体中MCs含量最低。【结论】研究结果对全面了解有机磷源含砷水体中藻华暴发及砷生态风险的科学管控具有重要意义。 展开更多
关键词 有机磷 氮磷比 铜绿微囊藻 砷形态 藻毒素
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Using water isotopes and hydrogeochemical evidences to characterize groundwater age and recharge rate in the Zhangjiakou area,North China 被引量:3
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作者 ZHANG Qinghua luo zhuanxi +3 位作者 LU Wen HARALD Zepp ZHAO Yufeng TANG Jialiang 《Journal of Geographical Sciences》 SCIE CSCD 2020年第6期935-948,共14页
Despite the increasing depletion of the groundwater at the Zhangjiakou aquifer system in the northwest of Beijing-Tianjin-Hebei region,little information is available on the hydrological process of groundwater in this... Despite the increasing depletion of the groundwater at the Zhangjiakou aquifer system in the northwest of Beijing-Tianjin-Hebei region,little information is available on the hydrological process of groundwater in this region.In this study,we utilized water isotopes composition(51sO,5D and 3H)of groundwater,river and precipitation to identify the characteristics of hydrochemistry,groundwater age and recharge rates in different watersheds of the Zhangjiakou area.Results showed that the river water and groundwater could be characterized as HCO3-Mg Na,HCO3 CI-Na and HCO3-Mg Na,HCO3 CI-Na,HCO3 CI-Na Mg types,respectively.The 5D and 5180 values in precipitation were linearly correlated,which is similar to the Global Meteorological Water Line(GMWL).Furthermore,the decreasing values of the 6D and 5180 from precipitation to surface water and groundwater indicate that groundwater is mainly recharged by atmospheric precipitation.In addition,the variation of 3H concentration with depth suggests that groundwater shallower than around 100 m is generally modern water.In contrast,groundwater deeper around 100 m is a mixture of modern and old waters,which has longer residence times.Groundwater showed a relatively low tritium concentration in the confined aquifers,indicating the groundwater recharged might be relatively old groundwater of over 60 years.The flow velocity of the groundwater in the study area varied from 1.10 to 2.26 m/a,and the recharge rates ranged from 0.034 to 0.203 m/a.The obtained findings provide important insights into understanding the groundwater recharge sources and hydrochemistry in the Zhangjiakou area,in turn developing a sustainable groundwater management plan. 展开更多
关键词 hydrogen and oxygen isotopes tritium isotope water cycle GROUNDWATER Zhangjiakou
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