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用标准加入法测定不同类型皮革中的禁用偶氮染料 被引量:1
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作者 Lars-Henric Ahlstrom Johan Raab +1 位作者 lennart mathiasson 龚英 《中国皮革》 CAS 北大核心 2008年第15期51-55,共5页
将基于微波萃取(MAE)和标准加入法的分析方法用于了牛革、绵羊革和山羊革中,禁用偶氮染料的测定。将溶于甲醇或水的偶氮染料在4个不同水平上应用标准加入法。偶氮染料是通过用连二亚硫酸钠和氯化锡(Ⅱ)还原染料所生成的有害胺类物质的... 将基于微波萃取(MAE)和标准加入法的分析方法用于了牛革、绵羊革和山羊革中,禁用偶氮染料的测定。将溶于甲醇或水的偶氮染料在4个不同水平上应用标准加入法。偶氮染料是通过用连二亚硫酸钠和氯化锡(Ⅱ)还原染料所生成的有害胺类物质的间接方法测得的。对比所得胺类物质的理论值进行准确度评估,同时还对比了未加入染料的革样通过外标校准法所得回收结果。标准加入法所提供的准确度远远高于外标校准法,并且对于大部分胺类物质的回收接近100%。由于使用甲醇或水作溶剂的标准加入法所得结果没有很大区别,因此将染料溶于甲醇这种标准加入法更好,这是因为在加入标准溶液后溶剂(甲醇)的蒸发更快。 展开更多
关键词 偶氮染料 芳香胺 皮革 微波萃取 标准加入
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Evaluation of Filter Material for Treatment of Different Types of Wastewater 被引量:1
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作者 Britt-Marie Svensson lennart mathiasson +1 位作者 lennart Martensson Pille Kangsepp 《Journal of Environmental Protection》 2011年第7期888-894,共7页
This paper presents an evaluation of the suitability of a mixed absorbent based on peat and carbon-containing ash for treatment of wastewaters, such as wastewater from professional car washes, landfill leachate and st... This paper presents an evaluation of the suitability of a mixed absorbent based on peat and carbon-containing ash for treatment of wastewaters, such as wastewater from professional car washes, landfill leachate and stormwater. This mixture is very attractive, since it is a low-cost material which has a capability to simultaneously remove inorganic as well as organic pollutants. Since any filter material eventually needs to be replaced either due to saturation of pollutants or reduced infiltration capacity, it is important that the residual can be handled at low cost and that the environment will be not impaired. The tested mixture, used in filter beds, showed low leaching values and high simultaneous removal efficiency of metals as Cu, Cd and Pb, non-polar organic compounds such as PCBs. Polar organic compounds as phenols were also efficiently removed by microbial and/or chemical degradation in the studied treatment plants with the filter bed acted as a biofilter. Filter material used for three years in a full-scale plant for leachate treatment and four years in treatment plants for wastewater from car washes, had sufficiently high energy content indicating that energy recovery is a good alternative for handling after its usage. Results show that the presented filter material is excellent for both small scale applications (e.g. treatment systems for car wash wastewater with capacity between 250 - 3000 m3 per year) as well as large-scale applications (e.g. filter systems for landfill leachates with capacity above 30,000 m3 per year). 展开更多
关键词 Wastewater Treatment Industrial Landfill Car Wash Batch Test Leaching Test PEAT Carbon-Containing Ash
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皮革中有害偶氮染料的测定:基于偶氮染料的裂解及采用现代萃取技术对相应致癌芳香胺的萃取
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作者 Oecili Sparr Eskilsson: Richard Dayidsson +1 位作者 lennart mathiasson 龚英(译) 《北京皮革(中外皮革信息版)(中)》 2008年第11期82-87,共6页
本文研究了用微波萃取(MAE)或超临界流体萃取(SFE)测定皮革中有害偶氮染料的可能性。在用SFE对皮革样品脱脂之后,通过MAE或SFE使偶氮染料还原裂解生成相应的芳香胺。其后,通过MAE或SFE萃取所得芳香胺,最后用液相色谱和二极管阵... 本文研究了用微波萃取(MAE)或超临界流体萃取(SFE)测定皮革中有害偶氮染料的可能性。在用SFE对皮革样品脱脂之后,通过MAE或SFE使偶氮染料还原裂解生成相应的芳香胺。其后,通过MAE或SFE萃取所得芳香胺,最后用液相色谱和二极管阵列检测方法测定。这些结果与德国DIN53316方法所得结果是可比的。这种基于常规溶剂萃取的标准方法已经在一些欧洲国家使用了。总体而言,用MAE和SFE方法所得的回收率更高一些。MAE和SFE这两种方法中加入样品的胺回收率均高于50%。MAE的平均回收率为62%,SFE(溶剂收集)为60%,而DIN方法为24%。对于天然皮革样品,回收率有所下降,特别是二氨基联苯。在这种情况,MAE、SFE和DIN方法的回收率分别为54%、38%和19%。对于所研究的胺而言,采用MAE和SFE的皮革样品的量极限为1mg/kg。实验室精度总体上优于10%,并随所考察的分析物不同而有所变化。相对于DIN方法,采用所提出的方法,使用的有毒有机溶剂的量减少,样品产量增加,并且所需要的手工劳动较少。 展开更多
关键词 超临界流体萃取 微波萃取 萃取方法 芳香的 偶氮染料
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