A self-assembled, （H20）38 cluster stabilized by a mono-nuclear copper（H） complex 1 namely { [Cu（phen）2（CO3）].7H2O} is characterized by X-ray diffraction studies. The adjacent （H2O）38 clusters connect togethe...A self-assembled, （H20）38 cluster stabilized by a mono-nuclear copper（H） complex 1 namely { [Cu（phen）2（CO3）].7H2O} is characterized by X-ray diffraction studies. The adjacent （H2O）38 clusters connect together resulting in an infinite 2D water layer structure. The water morphology is stable at room temperature, but upon thermal decomposition, the water loss is irreversible. C 2009 Cai Hua Zhou. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
基金supported by the Natural Science Foundation of Shaanxi Province(No.07JK439).
文摘A self-assembled, （H20）38 cluster stabilized by a mono-nuclear copper（H） complex 1 namely { [Cu（phen）2（CO3）].7H2O} is characterized by X-ray diffraction studies. The adjacent （H2O）38 clusters connect together resulting in an infinite 2D water layer structure. The water morphology is stable at room temperature, but upon thermal decomposition, the water loss is irreversible. C 2009 Cai Hua Zhou. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
