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A New Investigation of Mannich Reaction 被引量:1
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作者 li Yuan MOU Zi Yun liN +1 位作者 li ya zhu Xiao Tian liANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第6期471-474,共4页
During the synthesis of the derivatives of styryl ketonic Mannich bases, a side -product IM,other than the normal Mannich base MA, is obtained. Mannich reaction is further studied and the formation mechanism of produc... During the synthesis of the derivatives of styryl ketonic Mannich bases, a side -product IM,other than the normal Mannich base MA, is obtained. Mannich reaction is further studied and the formation mechanism of product IM is postulated and discussed on the basis of deuterium labelling. 展开更多
关键词 Mannich reaction side-product styryl ketonic Mannich bases MECHANISM
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SYNTHESIS OF 6-AMINO, 6-METHOXY AND 6-ETHOXY PURINENUCLEOSIDE DERIVATIVES 被引量:1
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作者 li ya zhu Xiao Tian liANG Tai Shun liN 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第8期601-604,共4页
A convenient route for the conversion of inosine to the corresponding 6-amino, 6-methoxy and 6-ethoxy derivatives is reported. This conversion can be achieved by ammoniation or etherification of the 6-pyridinium inter... A convenient route for the conversion of inosine to the corresponding 6-amino, 6-methoxy and 6-ethoxy derivatives is reported. This conversion can be achieved by ammoniation or etherification of the 6-pyridinium intermediate(3) which can be readily produced under mild reaction conditions. The chemistry and characterization of these compounds are presented, A plausible mechanism of the reaction is proposed. 展开更多
关键词 OCH SYNTHESIS OF 6-AMINO METHOXY AND 6-ETHOXY PURINENUCLEOSIDE DERIVATIVES
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Spectrometric study of α-methylene aromatic araminenone and aminoketone 被引量:1
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作者 li Yuan Mou Zi Yun lin +1 位作者 li ya zhu Xiao Tian liang 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第10期1253-1255,共3页
Thirteen α-methylene aromatic araminenone and four α-methylene aromatic aminoketones were prepared by modified Mannich reaction. On the basis of isotopic labeling, a plausible way of cleavage was proposed for the fo... Thirteen α-methylene aromatic araminenone and four α-methylene aromatic aminoketones were prepared by modified Mannich reaction. On the basis of isotopic labeling, a plausible way of cleavage was proposed for the formation of the M^+- 17 fragment peak in the MS of the α-methylene aromatic araminenone and aminoketones. The characteristic chemical shift of the olefinic protons in ^1H NMR is also discussed. 展开更多
关键词 α-Methylene aromatic araminenone and aminoketones Spectrometric study
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NEW METHOD OF SYNTHESIS OF 1-OXO-3-ACETONYL-DIHYDROBENZO(C)FURAN
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作者 li ya zhu Qi Dong ZHANG Xian Yu ZENG and Zi Yun liN(Institute of Materia Medica, Chinese Academy of Medical Sciences,Beijing 100050) 《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第1期43-44,共2页
o-Carboxybenzaldehyde (1)and acetone gave the Claisen-Schmidt condensation product, which readily cyclizes on acidification to give 1-oxo-3-acetonyl-dihydrobenzo [c]furan(4)in 68% yield. Other methyl ketones behaved s... o-Carboxybenzaldehyde (1)and acetone gave the Claisen-Schmidt condensation product, which readily cyclizes on acidification to give 1-oxo-3-acetonyl-dihydrobenzo [c]furan(4)in 68% yield. Other methyl ketones behaved similarly. 展开更多
关键词 OXO C)FURAN NEW METHOD OF SYNTHESIS OF 1-OXO-3-ACETONYL-DIHYDROBENZO
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Spectrometric Study of α-Phenylcinnamic Acids
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作者 Xin HE li Yuan MOU +2 位作者 Zi Yun liN li ya zhu Xiao Tian liANG (Institute of Materia Medica , Chinese Academy of Medical Sciences and Peking Union Medical College . Beijing 100050 ) 《Chinese Chemical Letters》 SCIE CAS CSCD 1997年第10期883-884,共2页
Fourteen substituted α-phenylcinnamic acids were prepared by the classical Perkin condensation. A plausible way of cleavage was involved in the formation of the specific fragment peaks in the MS of the α-phenylcinn... Fourteen substituted α-phenylcinnamic acids were prepared by the classical Perkin condensation. A plausible way of cleavage was involved in the formation of the specific fragment peaks in the MS of the α-phenylcinnamic acids . The characteristic chemical shift of the olefinic proton in HNMR is also discussed 展开更多
关键词 Spectrometric Study of Phenylcinnamic Acids
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Stereoselective Total Synthesis of Chrysanthemol
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作者 li Yuan MOU li ya zhu Xiao Tian liANG(Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100050) 《Chinese Chemical Letters》 SCIE CAS CSCD 1998年第10期929-930,共2页
Chrysanthemol, an active antiinflammatory sesquiterpene from Chrysanthemum indicum L., was synthesized in ten steps from R-(+)-carvone with an overall yield of 2.4%. The analytic data of the synthetic target compound ... Chrysanthemol, an active antiinflammatory sesquiterpene from Chrysanthemum indicum L., was synthesized in ten steps from R-(+)-carvone with an overall yield of 2.4%. The analytic data of the synthetic target compound was identical with that of natural chrysanthemol. 展开更多
关键词 crysanthemol stereoselective total synthesis
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