The stress relaxation of semi-crystalline nylon 1010 cannot be fitted by the Kohlrausch-Williams-Watts formula when the experiments were performed at pre-yielding regime below the glass transition temperature.We study...The stress relaxation of semi-crystalline nylon 1010 cannot be fitted by the Kohlrausch-Williams-Watts formula when the experiments were performed at pre-yielding regime below the glass transition temperature.We study this problem and identify the two-step mechanism of stress relaxation.At short time scale,relaxation is fast,dominated by stress biased thermal fluctuation with a fixed short-range length scale(activation volume).At long time scale,relaxation is slow due to the emergence of a cooperative long-range length scale determined by the stress fluctuation.The cooperative length scale is proportional to the reciprocal of stress and the amplitude of stress fluctuation is the product of stress and activation volume.Based on this two-step mechanism,we propose a new kinetics equation to capture the stress relaxation effectively,where the short time relaxation is described by an Eyring-like local activation and the long-time relaxation is captured by a cooperative excitation process resorting to an extension from the random first order transition theory.Our equation fits the experimental data well and can serve as a model to guide the related experiments of relaxation processes in crystalline solids.展开更多
The thermo-oxidative aging behaviors of Nylon 1010 films were studied by various analytical methods,such as measuring the chromaticity,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break ...The thermo-oxidative aging behaviors of Nylon 1010 films were studied by various analytical methods,such as measuring the chromaticity,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break of the aged films.The thermo-oxidative aging plots of the results obtained via these various methods at different temperatures are subjected to the time-temperature superposition analysis,which are found to be well superposed.The b＊ values are used as X axis and the other results,i.e.,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break,are used as V axis,respectively.The relationship between the b values and the other results is obtained,from which we can derive the changes of physical and chemical properties at different b＊ values.Since the b＊ values can be quickly determined by using a portable spectrophotometer,the on-line evaluation of the thermo-oxidative aging of Nylon 1010 can be realized.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos.21873054,21774131 and 21544007)the National Natural Science Foundation of China (Nos.U1862205 and 51673110)China Petroleum & Chemical Corporation for financial support。
文摘The stress relaxation of semi-crystalline nylon 1010 cannot be fitted by the Kohlrausch-Williams-Watts formula when the experiments were performed at pre-yielding regime below the glass transition temperature.We study this problem and identify the two-step mechanism of stress relaxation.At short time scale,relaxation is fast,dominated by stress biased thermal fluctuation with a fixed short-range length scale(activation volume).At long time scale,relaxation is slow due to the emergence of a cooperative long-range length scale determined by the stress fluctuation.The cooperative length scale is proportional to the reciprocal of stress and the amplitude of stress fluctuation is the product of stress and activation volume.Based on this two-step mechanism,we propose a new kinetics equation to capture the stress relaxation effectively,where the short time relaxation is described by an Eyring-like local activation and the long-time relaxation is captured by a cooperative excitation process resorting to an extension from the random first order transition theory.Our equation fits the experimental data well and can serve as a model to guide the related experiments of relaxation processes in crystalline solids.
文摘The thermo-oxidative aging behaviors of Nylon 1010 films were studied by various analytical methods,such as measuring the chromaticity,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break of the aged films.The thermo-oxidative aging plots of the results obtained via these various methods at different temperatures are subjected to the time-temperature superposition analysis,which are found to be well superposed.The b＊ values are used as X axis and the other results,i.e.,relative viscosity,carbonyl index,UV absorbance at 280 nm and elongation at break,are used as V axis,respectively.The relationship between the b values and the other results is obtained,from which we can derive the changes of physical and chemical properties at different b＊ values.Since the b＊ values can be quickly determined by using a portable spectrophotometer,the on-line evaluation of the thermo-oxidative aging of Nylon 1010 can be realized.
