Electronic devices that are transparent and flexible have a wide range of applications in the domains of vital sign parameter monitoring,health management,and so on.Ferroelectric memory is a revolutionary nonvolatile ...Electronic devices that are transparent and flexible have a wide range of applications in the domains of vital sign parameter monitoring,health management,and so on.Ferroelectric memory is a revolutionary nonvolatile memory that is ideal for data storage and processing in transparent flexible electronic systems.In this study,Ce-doped hafnium oxide ferroelectric thin film is manufactured on mica substrate by the chemical solution deposition with transparent indium tin oxide(ITO)thin films as the bottom electrodes.The transmittance of mica/ITO/Hf_(0.85)Ce_(0.15)O_(2)thin film is over 80%.The 2Pr of the transparent flexible Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film is increased by about 22.4%and the Ec is reduced by 26.7%compared with those of Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film grown on p+-Si substrate.The transparent flexible Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film can remain keeping good quality when being bent under±2.5 mm bending radius.Additionally,degradation of polarization,retention,and endurance performance was not obvious even at a bending radius of 5.0 mm after 104 bending cycles.This research provides a new strategy and an important experimental basis for the development and implementation of transparent flexible ferroelectric memories.展开更多
基金supported by the National Natural Science Foundation of China(Nos.11902285 and 12072307)the Department of Education Project of Hunan Province,China(Nos.21B0112 and 19A106)+2 种基金the Science and Technology Agency Project of Hunan Province,China(No.2020JJ5526)the China Postdoctoral Science Foundation(No.2019TQ0273)the Outstanding Youth Science Foundation of Hunan Province,China(No.2021JJ20041).
文摘Electronic devices that are transparent and flexible have a wide range of applications in the domains of vital sign parameter monitoring,health management,and so on.Ferroelectric memory is a revolutionary nonvolatile memory that is ideal for data storage and processing in transparent flexible electronic systems.In this study,Ce-doped hafnium oxide ferroelectric thin film is manufactured on mica substrate by the chemical solution deposition with transparent indium tin oxide(ITO)thin films as the bottom electrodes.The transmittance of mica/ITO/Hf_(0.85)Ce_(0.15)O_(2)thin film is over 80%.The 2Pr of the transparent flexible Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film is increased by about 22.4%and the Ec is reduced by 26.7%compared with those of Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film grown on p+-Si substrate.The transparent flexible Hf_(0.85)Ce_(0.15)O_(2)ferroelectric thin film can remain keeping good quality when being bent under±2.5 mm bending radius.Additionally,degradation of polarization,retention,and endurance performance was not obvious even at a bending radius of 5.0 mm after 104 bending cycles.This research provides a new strategy and an important experimental basis for the development and implementation of transparent flexible ferroelectric memories.