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铜/铅锌冶炼厂硫化砷渣的理化与环境特性 被引量:8
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作者 姚理为 闵小波 +7 位作者 徐慧 柯勇 王云燕 林璋 梁彦杰 刘德刚 许秋婧 何逾洋 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第7期1943-1955,共13页
以铜冶炼和铅锌冶炼产生的硫化砷渣为研究对象,采用XRD、Raman、SEM-EDD、TG-DTA、XPS和化学物相分析等检测手段研究其理化特性。采用毒性浸出程序(TCLP)、毒性浸出测试国家标准(CSLT)、三步连续浸提程序(BCR)和批次浸出实验(BLE)分析... 以铜冶炼和铅锌冶炼产生的硫化砷渣为研究对象,采用XRD、Raman、SEM-EDD、TG-DTA、XPS和化学物相分析等检测手段研究其理化特性。采用毒性浸出程序(TCLP)、毒性浸出测试国家标准(CSLT)、三步连续浸提程序(BCR)和批次浸出实验(BLE)分析硫化砷渣的环境稳定性。不同冶炼厂的硫化砷渣理化和环境特性具有明显的差异。物相组成和显微分析表明,ASS-I主要由超细的絮状颗粒组成,这种颗粒为粘附有无定型硫的无定型硫化砷。AAS-II主要组成为无定型硫化砷。两种来源的硫化砷渣中砷均为正三价,但是硫的价态组成则有所不同。同时,两种来源的硫化砷渣均具有热不稳定性。TCLP和CSLT结果表明,浸出液中砷和铅的浸出浓度超过了标准限值。超过5%和90%的砷以酸可溶态和可氧化态赋存,这解释了硫化砷渣砷浸出毒性高、环境活性强的原因。本研究为铜和铅锌冶炼企业的硫化砷渣的处置提供了全面的信息参考。 展开更多
关键词 硫化砷渣 重金属 理化特性 环境特性 浸出毒性
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含单质硫的硫化砷渣水热稳定化的过程及机理 被引量:1
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作者 徐慧 姚理为 +8 位作者 许秋婧 王云燕 闵小波 柯勇 罗永健 唐巾尧 彭思昂 张李敏 杜嘉丽 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第3期1041-1049,共9页
提出一种水热处理方法以稳定硫化砷渣。在最优条件(160℃、2h、液固比1:1、初始pH2)下,水热处理后As和Cd元素的浸出毒性分别由504.0和12.0 mg/L降低至1.23和0.03 mg/L。硫化砷渣的稳定化主要通过颗粒转化成块状的结构转变及As和Cd化学... 提出一种水热处理方法以稳定硫化砷渣。在最优条件(160℃、2h、液固比1:1、初始pH2)下,水热处理后As和Cd元素的浸出毒性分别由504.0和12.0 mg/L降低至1.23和0.03 mg/L。硫化砷渣的稳定化主要通过颗粒转化成块状的结构转变及As和Cd化学形态的转变来实现。此外,硫化砷渣中具有熔融和聚合特性的单质硫的存在极大促进其水热稳定化。 展开更多
关键词 水热稳定化 硫化砷渣 单质硫 结构转变
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Comparison of a minimally invasive osteosynthesis technique with conventional open surgery for transverse patellar fractures
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作者 li-wei yao Haijiao Mao +2 位作者 Wen-Wei Dong Ze-Ting Wu Qing Liu 《Chinese Journal of Traumatology》 CAS CSCD 2023年第5期261-266,共6页
Parpose:The study aims to compare the efficacy and safety of a new minimally invasive osteosynthesis technique with those of conventional open surgery for transverse patellar fractures.Methods:It was a retrospective s... Parpose:The study aims to compare the efficacy and safety of a new minimally invasive osteosynthesis technique with those of conventional open surgery for transverse patellar fractures.Methods:It was a retrospective study.Adult patients with closed transverse patellar fracture were included,and with open comminuted patellar fracture were excluded.These patients were divided into minimally invasive osteosynthesis technique(MIOT)group and open reduction and internal fixation(ORIF)group.Surgical time,frequency of intraoperative fluoroscopy,visual analogue scale score,flexion,extension,Lysholm knee score,infection,malreduction,implant migration and implant irritation in two groups were recorded and compared.Statistical analysis was performed by the SPsS software package(version 19).A p<0.05 indicated statistical significance.Results:A total of 55 patients with transverse patellar fractures enrolled in this study,the minimally invasive technique was performed in 27 cases,and open reduction was performed in 28 cases.The surgical time in the ORIF group was shorter than that in the MIOT group(p=0.033).The visual analogue scale scores in the MIOT group were significantly lower than those in the ORIF group only in the first month after surgery(p=0.015).Flexion was restored faster in the MIOT group than that in the ORIF group at one month(p=0.001)and three months(p=0.015).Extension was recovered faster in the MIOT group than that in the ORIF group at one month(p=0.031)and three months(p=0.023).The recorded Lysholm knee scores in the MIOT group were always greater than those in the ORIF group.Complications,such as infection,malreduction,implant migration,and implant irritation,occurred more frequently in the ORIF group.Conclusion:Compared with the ORIF group,the MIOT group reduced postoperative pain and had less complications and better exercise rehabilitation.Although it requires a long operation time,MIOT may be a wise choice for transverse patellar fractures. 展开更多
关键词 Minimally invasive technique Patellar fractures Open reduction internal fixation
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