A novel Pd-catalyzed tandem reaction involving hydroallojnylation, isomerization, Diels-Alder cycloaddition and aromatization reaction to produce phthalan derivatives in moderate yields is reported. The reaction is at...A novel Pd-catalyzed tandem reaction involving hydroallojnylation, isomerization, Diels-Alder cycloaddition and aromatization reaction to produce phthalan derivatives in moderate yields is reported. The reaction is atom economical and occurs in a highly ordered fashion. The reaction mechanism is discussed.展开更多
基金The financial support from the National Natural Science Foundation of China(No.21302095)Research Fund for the Doctoral Program of Higher Education of China(No.20133221120003)+2 种基金Jiangsu Provincial NSFC(No.BK20130924)Foundation of Jiangsu Educational Committee of China(No.13KJB150019)supported by the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘A novel Pd-catalyzed tandem reaction involving hydroallojnylation, isomerization, Diels-Alder cycloaddition and aromatization reaction to produce phthalan derivatives in moderate yields is reported. The reaction is atom economical and occurs in a highly ordered fashion. The reaction mechanism is discussed.
