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A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units
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作者 JingLinCHEN liyizhang ZhongNingCHEN 《Chinese Chemical Letters》 SCIE CAS CSCD 2005年第3期372-374,共3页
A novel dimeric complex [Ru3 (μ3-O)(μ-CH3COO)(CO)]2(μ-dppf)(μ-odppf)(dppf = 1, 1'-bis(diphenylphosphio)ferrocene, odppf = 1, 1'-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aecta... A novel dimeric complex [Ru3 (μ3-O)(μ-CH3COO)(CO)]2(μ-dppf)(μ-odppf)(dppf = 1, 1'-bis(diphenylphosphio)ferrocene, odppf = 1, 1'-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aectate cluster units was synthesized and characterized by X-ray crystallography. Compound 1 exhibits a cyclic structure formed by linkages of two triruthenium cluster units Ru3 (μ3-O)(μ-CH3COO)6(CO) through dppf and odppf ligands, respectively. The diameter of the molecular loop is ca. 1.0 nm. 展开更多
关键词 CARBOXYLATE crystal structure DIPHOSPHINE RUTHENIUM cluster complex.
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