高精度测定水中氧同位素组成对于了解区域和全球水文气候变化过程具有重要意义.近年来,随着测试技术的不断发展,稳定同位素比值质谱(质谱法)和波长扫描光腔衰荡光谱(光谱法)技术均被证明可以获得高精度的水中三氧同位素指标(^(17)O-exce...高精度测定水中氧同位素组成对于了解区域和全球水文气候变化过程具有重要意义.近年来,随着测试技术的不断发展,稳定同位素比值质谱(质谱法)和波长扫描光腔衰荡光谱(光谱法)技术均被证明可以获得高精度的水中三氧同位素指标(^(17)O-excess).本研究在国内率先建立了高精度水三氧同位素测试新技术,使用质谱和光谱两种技术测量多个国际标准水样三氧同位素组成,并将数据与已有研究结果对比.结果表明,两种测试技术的精度均能够达到低于10 per meg(1 per meg=10^(-6)),但在样品需求量、测试效率、受外界干扰程度等方面各有优劣.使用质谱法测试GISP的标准化值为δ^(18)O_(VSMOW-SLAP)=-24.82‰±0.04‰、δ^(17)O_(VSMOW-SLAP)=-13.16‰±0.03‰、^(17)O-excess=21±6 per meg(1σ);使用光谱法测定的GISP的标准值为δ^(18)O_(VSMOW-SLAP)=-24.80‰±0.03‰、δ^(17)O_(VSMOW-SLAP)=-13.15‰±0.02‰、^(17)O-excess=26±8 per meg(1σ).两种技术的测定值均与IAEA推荐值或已有研究结果在误差范围内一致.对于USGS 45和USGS 47的测定结果与已有数据或推荐值接近,特别是两者之间大于20per meg的^(17)O-excess值的差异也与已有研究结果一致.本研究使用两种技术测试中国不同气候区的冬夏季节降水,结果显示两种技术所测同一样品的值均具有良好的一致性,并初步观测到不同季节降水样品的^(17)O-excess值的变化,为利用三氧同位素指标研究水文循环过程提供重要的技术支撑.展开更多
The widely accepted“Milankovitch theory”explains insolation-induced waxing and waning of the ice sheets and their effect on the global climate on orbital timescales.In the past half century,however,the theory has of...The widely accepted“Milankovitch theory”explains insolation-induced waxing and waning of the ice sheets and their effect on the global climate on orbital timescales.In the past half century,however,the theory has often come under scrutiny,especially regarding its“100-ka problem.”Another drawback,but the one that has received less attention,is the“monsoon problem,”which pertains to the exclusion of monsoon dynamics in classic Milankovitch theory even though the monsoon prevails over the vast low-latitude(30N to30S)region that covers half of the Earth’s surface and receives the bulk of solar radiation.In this review,we discuss the major issues with the current form of Milankovitch theory and the progress made at the research forefront.展开更多
文摘高精度测定水中氧同位素组成对于了解区域和全球水文气候变化过程具有重要意义.近年来,随着测试技术的不断发展,稳定同位素比值质谱(质谱法)和波长扫描光腔衰荡光谱(光谱法)技术均被证明可以获得高精度的水中三氧同位素指标(^(17)O-excess).本研究在国内率先建立了高精度水三氧同位素测试新技术,使用质谱和光谱两种技术测量多个国际标准水样三氧同位素组成,并将数据与已有研究结果对比.结果表明,两种测试技术的精度均能够达到低于10 per meg(1 per meg=10^(-6)),但在样品需求量、测试效率、受外界干扰程度等方面各有优劣.使用质谱法测试GISP的标准化值为δ^(18)O_(VSMOW-SLAP)=-24.82‰±0.04‰、δ^(17)O_(VSMOW-SLAP)=-13.16‰±0.03‰、^(17)O-excess=21±6 per meg(1σ);使用光谱法测定的GISP的标准值为δ^(18)O_(VSMOW-SLAP)=-24.80‰±0.03‰、δ^(17)O_(VSMOW-SLAP)=-13.15‰±0.02‰、^(17)O-excess=26±8 per meg(1σ).两种技术的测定值均与IAEA推荐值或已有研究结果在误差范围内一致.对于USGS 45和USGS 47的测定结果与已有数据或推荐值接近,特别是两者之间大于20per meg的^(17)O-excess值的差异也与已有研究结果一致.本研究使用两种技术测试中国不同气候区的冬夏季节降水,结果显示两种技术所测同一样品的值均具有良好的一致性,并初步观测到不同季节降水样品的^(17)O-excess值的变化,为利用三氧同位素指标研究水文循环过程提供重要的技术支撑.
基金supported by the NationalNatural Science Foundation ofChina(41888101 and 42150710534).
文摘The widely accepted“Milankovitch theory”explains insolation-induced waxing and waning of the ice sheets and their effect on the global climate on orbital timescales.In the past half century,however,the theory has often come under scrutiny,especially regarding its“100-ka problem.”Another drawback,but the one that has received less attention,is the“monsoon problem,”which pertains to the exclusion of monsoon dynamics in classic Milankovitch theory even though the monsoon prevails over the vast low-latitude(30N to30S)region that covers half of the Earth’s surface and receives the bulk of solar radiation.In this review,we discuss the major issues with the current form of Milankovitch theory and the progress made at the research forefront.
