A continuous melt suspension crystallization process has been presented for the purification of the phosphoric acid in this study, which is performed in the cascade of a mixed suspension mixed product removal (MSMPR) ...A continuous melt suspension crystallization process has been presented for the purification of the phosphoric acid in this study, which is performed in the cascade of a mixed suspension mixed product removal (MSMPR) crystallizer and a gravity wash column for the subsequent solid-liquid separation. Dynamic behavior in the crystallizer and role of reflux ration on the purification efficiency of column are studied in detail. A reasonable steady state with respect to the liquid phase is achieved after 2 to 3 hrs, which is followed by a solid-phase steady state in terms of the slurry density after 4 hrs. Reflux ratio is the effective parameter for separation and purification by the crystallization equipment from the influences of reflux ratio on the purity of product, the number of theoretical plates and the stability of the operations.展开更多
In this work, polypyrrole (PPy)/titanate (TN) composite nanorods were successfully synthesized using cetyl trimethyl-ammonium bromide (CTAB) as a structure-directing agent by in situ chemical oxidative polymerization....In this work, polypyrrole (PPy)/titanate (TN) composite nanorods were successfully synthesized using cetyl trimethyl-ammonium bromide (CTAB) as a structure-directing agent by in situ chemical oxidative polymerization. The structural characterization indicated that the new composite rods were core (TN)-shell (PPy) nanostructure with the average diameter in the range of 250-300 nm. Further, this semiconducting composite can be used as a dispersed phase in silicone oil for a new electrorheological (ER) fluid, and its ER behavior was investigated under steady and oscillatory shear. It was found that the PPy/TN fluid showed typical ER characteristics under an external electric field.展开更多
The Editor-in-Chief has retracted this article because it was published in error. Further peer review determined that the article is not suitable for publication in the Frontiers of Chemical Engineering in China. All ...The Editor-in-Chief has retracted this article because it was published in error. Further peer review determined that the article is not suitable for publication in the Frontiers of Chemical Engineering in China. All authors agree to this retraction.展开更多
Bioactive glasses (BGs) are ideal materials for macroporous scaffolds due to their excellent osteoconductive, osteoinductive, biocompatible and biodegradable properties, and their high bone bonding rates. Macroporou...Bioactive glasses (BGs) are ideal materials for macroporous scaffolds due to their excellent osteoconductive, osteoinductive, biocompatible and biodegradable properties, and their high bone bonding rates. Macroporous scaffolds made From BGs are in high demand for bone regeneration because they can stimulate vascularized bone ingrowth and they enhance bonding between scaffolds and surrounding tissues. Engineering BG/biopolymers (BP) composites or hybrids may be a good way to prepare macroporous scaffolds with excellent properties. This paper summarizes the progress in the past few years in preparing three-dimensional macroporous BG and BG/BP scaffolds for bone regeneration. Since the brittleness of BGs is a major problem in developing macroporous scaffolds and this limits their use in load bearing applications, the mechanical properties of macroporous scaffolds are particularly emphasized in this review.展开更多
文摘A continuous melt suspension crystallization process has been presented for the purification of the phosphoric acid in this study, which is performed in the cascade of a mixed suspension mixed product removal (MSMPR) crystallizer and a gravity wash column for the subsequent solid-liquid separation. Dynamic behavior in the crystallizer and role of reflux ration on the purification efficiency of column are studied in detail. A reasonable steady state with respect to the liquid phase is achieved after 2 to 3 hrs, which is followed by a solid-phase steady state in terms of the slurry density after 4 hrs. Reflux ratio is the effective parameter for separation and purification by the crystallization equipment from the influences of reflux ratio on the purity of product, the number of theoretical plates and the stability of the operations.
文摘In this work, polypyrrole (PPy)/titanate (TN) composite nanorods were successfully synthesized using cetyl trimethyl-ammonium bromide (CTAB) as a structure-directing agent by in situ chemical oxidative polymerization. The structural characterization indicated that the new composite rods were core (TN)-shell (PPy) nanostructure with the average diameter in the range of 250-300 nm. Further, this semiconducting composite can be used as a dispersed phase in silicone oil for a new electrorheological (ER) fluid, and its ER behavior was investigated under steady and oscillatory shear. It was found that the PPy/TN fluid showed typical ER characteristics under an external electric field.
文摘The Editor-in-Chief has retracted this article because it was published in error. Further peer review determined that the article is not suitable for publication in the Frontiers of Chemical Engineering in China. All authors agree to this retraction.
文摘Bioactive glasses (BGs) are ideal materials for macroporous scaffolds due to their excellent osteoconductive, osteoinductive, biocompatible and biodegradable properties, and their high bone bonding rates. Macroporous scaffolds made From BGs are in high demand for bone regeneration because they can stimulate vascularized bone ingrowth and they enhance bonding between scaffolds and surrounding tissues. Engineering BG/biopolymers (BP) composites or hybrids may be a good way to prepare macroporous scaffolds with excellent properties. This paper summarizes the progress in the past few years in preparing three-dimensional macroporous BG and BG/BP scaffolds for bone regeneration. Since the brittleness of BGs is a major problem in developing macroporous scaffolds and this limits their use in load bearing applications, the mechanical properties of macroporous scaffolds are particularly emphasized in this review.