Aluminoxanes containing both ethyl and iso-butyl groups were synthesized by thehydrolysis of Al(C2H3)3 (TEA)/Al(i-C4H9)3 (TIBA) mixtures. The aluminoxane made from theTEA/TIBA mixture of molar ratio 7:3 showed cocatal...Aluminoxanes containing both ethyl and iso-butyl groups were synthesized by thehydrolysis of Al(C2H3)3 (TEA)/Al(i-C4H9)3 (TIBA) mixtures. The aluminoxane made from theTEA/TIBA mixture of molar ratio 7:3 showed cocatalyst activity of about five times as those ofethylaluminoxane or isobutylaluminoxane for ethylene polymerization catalyzed by Cp2ZrCl2. Thealuminoxane was characterized and the possible reasons for its high activity were discussed.展开更多
文摘Aluminoxanes containing both ethyl and iso-butyl groups were synthesized by thehydrolysis of Al(C2H3)3 (TEA)/Al(i-C4H9)3 (TIBA) mixtures. The aluminoxane made from theTEA/TIBA mixture of molar ratio 7:3 showed cocatalyst activity of about five times as those ofethylaluminoxane or isobutylaluminoxane for ethylene polymerization catalyzed by Cp2ZrCl2. Thealuminoxane was characterized and the possible reasons for its high activity were discussed.
