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铁配合型镁合金缓蚀剂的阴极阻蚀机制
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作者 杨俊杰 王霖倩 +4 位作者 Carsten BLAWERT Sviatlana VLAMAKA Christian FEILER Mikhail LZHELUDKEVICH 李卫 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第5期1496-1506,共11页
研究阴极缓蚀剂(3-甲基水杨酸盐,3-MeSA)对含铁纯镁腐蚀性能的影响。高铁杂质颗粒成分、腐蚀表面形貌以及3-MeSA分子结构特征为揭示含铁镁合金的腐蚀行为及3-MeSA的阴极型阻蚀机理提供了实验与理论依据。研究结果表明:含铁杂质颗粒中含... 研究阴极缓蚀剂(3-甲基水杨酸盐,3-MeSA)对含铁纯镁腐蚀性能的影响。高铁杂质颗粒成分、腐蚀表面形貌以及3-MeSA分子结构特征为揭示含铁镁合金的腐蚀行为及3-MeSA的阴极型阻蚀机理提供了实验与理论依据。研究结果表明:含铁杂质颗粒中含有固溶态硅,而Fe/Si比可能是导致不同局部腐蚀形态差异的主要原因。虽然3-MeSA能在镁基体上形成吸附层,但其阻蚀机制主要归因于其螯合从富铁颗粒中自腐蚀释放Fe^(2+)/Fe^(3+)的能力,阻止被还原的铁物质再次沉积至腐蚀金属表面。 展开更多
关键词 富铁杂质 铁配合剂 阴极型缓蚀剂 量子化学计算
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Corrosion and discharge performance of Mg-9%Al-2.5%Pb alloy as anode for seawater activated battery 被引量:2
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作者 Min DENG Ri-chu wang +2 位作者 Yan FENG Nai-guang wang lin-qian wang 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第8期2144-2151,共8页
To obtain a new kind of Mg?Al?Pb alloy anode material with low content of Pb, the corrosion and discharge behavior of Mg?9%Al?2.5%Pb (hereafter in mass fraction) alloy were investigated by immersion tests and electroc... To obtain a new kind of Mg?Al?Pb alloy anode material with low content of Pb, the corrosion and discharge behavior of Mg?9%Al?2.5%Pb (hereafter in mass fraction) alloy were investigated by immersion tests and electrochemical techniques, and compared with those of Mg?6%Al?5%Pb alloy. The results indicate that Mg?9%Al?2.5%Pb alloy exhibits a lower self-corrosion rate and higher utilization efficiency in contrast with Mg?6%Al?5%Pb alloy because of the higher content of Al. As the result of the decrease of Pb content, the discharge activity of Mg?9%Al?2.5%Pb alloy is relatively weaker but still meets the requirement of anode. These results reveal that Mg?9%Al?2.5%Pb alloy with a low content of Pb can serve as a good candidate for the anode material used in seawater activated battery. 展开更多
关键词 Mg.Al.Pb alloy anode material self-corrosion rate utilization efficiency discharge activity
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