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气固两相流内中空多孔催化剂性能的数值模拟 被引量:1
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作者 吴秋莹 孔令凯 +2 位作者 徐骥 葛蔚 袁绍军 《过程工程学报》 CAS CSCD 北大核心 2021年第7期774-785,共12页
气固流态化过程中流体和颗粒分别聚集,形成稀密两相,严重限制其传质效率和反应速率的提高。针对此问题,本工作设计了一种中空多孔结构的催化剂颗粒,通过模拟方法研究该颗粒对稀密两相气相传质与反应的影响,及其在稀密相间转换的时间尺... 气固流态化过程中流体和颗粒分别聚集,形成稀密两相,严重限制其传质效率和反应速率的提高。针对此问题,本工作设计了一种中空多孔结构的催化剂颗粒,通过模拟方法研究该颗粒对稀密两相气相传质与反应的影响,及其在稀密相间转换的时间尺度。结果表明,一定的流动强度时,在颗粒稀密相转换的时间尺度内,中空多孔结构的颗粒能够有效地在稀相存储反应气体,并在密相释放,为密相提供额外的反应气体,增强体系的整体反应效率。当催化反应速率高于传质速率时,在所研究的流动条件下中空多孔颗粒体系的反应效率比实心球形颗粒体系高出26.92%~29.55%。可以预见在稀密相分布更广的大型气固流化床反应器中,中空多孔结构的催化剂颗粒能够更为有效地提高反应器的整体效率。 展开更多
关键词 中空多孔催化剂 气固流态化 传质速率 反应速率 数值模拟
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Electro-elastic features of YBa3(PO_(4))3 and YbBa3(PO_(4))3 crystals with pure face-shear mode for acoustic wave sensor applications 被引量:1
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作者 Guangda Wu lingkai kong +4 位作者 Mengdi Fan Fapeng Yu Chao Jiang Xiufeng Cheng Xian Zhao 《Journal of Materiomics》 SCIE EI 2021年第4期828-836,共9页
The fundamental shear horizontal(SH0)waves have been proved to be a very useful method for nondestructive testing due to their non-dispersive characteristics.Currently,although several methods have been proposed to ge... The fundamental shear horizontal(SH0)waves have been proved to be a very useful method for nondestructive testing due to their non-dispersive characteristics.Currently,although several methods have been proposed to generate SH0 waves,it is still a challenge to obtain pure SH0 wave mode efficiently.Herein,in this study,non-centrosymmetric YBa3(PO_(4))3(YBP)and YbBa3(PO_(4))3(YbBP)crystals with pure face-shear mode were grown via the traditional Czochralski pulling method at temperatures above 1800℃.High resolution X-ray diffraction was carried out to evaluate the crystalline quality.Results showed that the YBP and YbBP crystals were of good quality,with the full width at half-maxima being on the order of 42.500 and 52.300,respectively.Moreover,the full set of electro-elastic constants for the YBP and YbBP crystals were determined and collated using a combination of impedance and pulse-echo methods.The piezoelectric coefficient(d14)of the YBP and YbBP crystals were determined to be 10.6 pC/N and 11.4 pC/N,respectively,corresponding to the electromechanical coupling coefficient(k14)equal to 15.4%and 15.9%,exhibiting large and pure face-shear vibration mode.Collectively,these results indicate that the YBP and YbBP crystals are promising for acoustic wave sensing application. 展开更多
关键词 YBa3(PO_(4))3 YbBa3(PO_(4))3 Pure face-shear mode Electro-elastic properties
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