General strategies leading to scale-span molecular self-assembly are of crucial importance in creating bulk supramolecular materials.Here,we report that under mechanical pressure,caking of the precipitatedmolecular se...General strategies leading to scale-span molecular self-assembly are of crucial importance in creating bulk supramolecular materials.Here,we report that under mechanical pressure,caking of the precipitatedmolecular self-assemblies led to bulk supramolecular films.Massive fabrication of supramolecular films became possible by employing a simple household noodle machine.The film could be endowed to acquire diversified functions by depositing various functional ingredients via coprecipitation.We expect that our current work opens up a new paradigm leading to large-scale functional solid molecular self-assembled materials.展开更多
基金the National Natural Science Foundation of China(NSFC 91856120,21573011,and 21633002).
文摘General strategies leading to scale-span molecular self-assembly are of crucial importance in creating bulk supramolecular materials.Here,we report that under mechanical pressure,caking of the precipitatedmolecular self-assemblies led to bulk supramolecular films.Massive fabrication of supramolecular films became possible by employing a simple household noodle machine.The film could be endowed to acquire diversified functions by depositing various functional ingredients via coprecipitation.We expect that our current work opens up a new paradigm leading to large-scale functional solid molecular self-assembled materials.
