The interface is crucial for perovskite solar cells(PSCs).However,voids at interfaces induced by the trapped hygroscopic dimethyl sulfoxide(DMSO)can reduce charge extraction and accelerate the film degradation,serious...The interface is crucial for perovskite solar cells(PSCs).However,voids at interfaces induced by the trapped hygroscopic dimethyl sulfoxide(DMSO)can reduce charge extraction and accelerate the film degradation,seriously damaging the efficiency and stability.In this work,4,4’-dinonyl-2,2’-dipyridine(DN-DP),a Lewis base with long alkyl chains is introduced to solve this problem.Theoretical calculated and experimental results confirm that the dipyridyl group on DN-DP can more strongly coordinate with Pb^(2+)than that of the S=O group on DMSO.The strong coordination effect plays a crucial role in removing the DMSO-based adduct and reducing the formation of voids.Due to the electron-donating properties of pyridine,the existence of DN-DP in the perovskite film can passivate the defects and optimize the energy level alignment of the perovskite configuration.The open-circuit voltage(VOC)of the DN-DP-based PSC is improved from 1.107 V(control device)to 1.153 V,giving rise to a power conversion efficiency(PCE)of24.02%.Furthermore,benefiting from the moisture resistance stemming from the hydrophobic nonyl group,the PCE retains 90.4%of the initial performance after 1000 h of storage in the ambient condition.展开更多
Air moisture is the key issue for perovskites which invades the films and accelerates the damage of devices. Here, polyvinylpyrrolidone(PVP) is introduced to the methylammonium lead iodide(MAPbI_(3)) perovskite precur...Air moisture is the key issue for perovskites which invades the films and accelerates the damage of devices. Here, polyvinylpyrrolidone(PVP) is introduced to the methylammonium lead iodide(MAPbI_(3)) perovskite precursor to control crystal growth and endow the devices with self-healing ability in a moisture environment. The strong C=O...ΗAΝ hydrogen bonding interactions between PVP and MAPbI_(3) was confirmed by nuclear magnetic resonance measurements. By introducing hydrogen bonding in the MAPbI_(3)-based PSCs, we form a compact perovskite film of excellent electronic quality with a power conversion efficiency(PCE) of up to 20.32%. Furthermore, the O...ΗAΝ hydrogen bonding interactions at the grain boundaries suppress the decomposition of methylammonium cations and improve the recyclable dissolution–recrystallization of perovskite. As a result, the MAPbI_(3)-PVP based cells exhibited striking moisture stability and self-healing behavior, with negligible decay in efficiency after 500 h of operation in high humidity(65% ± 5% relative humidity) and rapid recovering ability after their removal from the humid environment.展开更多
The electrochemical energy storage performance is greatly determined by the charge transfer and ion transportation occurring in the electrode materials.Therefore,the enhancement of electric conductivity and ionic mobi...The electrochemical energy storage performance is greatly determined by the charge transfer and ion transportation occurring in the electrode materials.Therefore,the enhancement of electric conductivity and ionic mobility is vital for high-performing and stable metal ion batteries.Here,we report the properties of oxygen vacancies(VO)and carbon co-doped TiO_(2) hollow spheres(HS-TiO_(2))and compared them with fully oxidized white TiO_(2) hollow spheres(W-TiO_(2)).Theoretical calculations and experimental results revealed that the introduction of carbon dopant and VO in anatase TiO_(2) reduced the bandgap and the existence of localized electrons,leading to a lower migration barrier of Li ions that promoted faster ion diffusion kinetics,enabling the HS-TiO_(2) with higher reversibility during the insertion and extraction of Li ions than the W-TiO_(2).This HS-TiO_(2) delivered superior lithium storage properties with a specific discharge capacity of 214.6 mAh g^(-1) for the 100th cycle at 200 mA g^(-1) and 116.3 mAh g^(-1) over 2000 cycles at a high rate of 2 A g^(-1).展开更多
CO oxidation has been performed on Co_(3)O_(4) nanobelts and nanocubes as model catalysts.The Co_(3)O_(4) nanobelts which have a predominance of exposed{011}planes are more active than Co_(3)O_(4) nanocubes with expos...CO oxidation has been performed on Co_(3)O_(4) nanobelts and nanocubes as model catalysts.The Co_(3)O_(4) nanobelts which have a predominance of exposed{011}planes are more active than Co_(3)O_(4) nanocubes with exposed{001}planes.Temperature programmed reduction of CO shows that Co_(3)O_(4) nanobelts have stronger reducing properties than Co_(3)O_(4) nanocubes.The essence of shape and crystal plane effect is revealed by the fact that turnover frequency of Co3+sites of{011}planes on Co_(3)O_(4) nanobelts is far higher than that of{001}planes on Co_(3)O_(4) nanocubes.展开更多
Semiconductor sensitized solar cells(SSSCs) are promising candidates for the third generation of cost-effective photovoltaic solar cells and it is important to develop a group of robust, environment-friendly and visib...Semiconductor sensitized solar cells(SSSCs) are promising candidates for the third generation of cost-effective photovoltaic solar cells and it is important to develop a group of robust, environment-friendly and visible-light-responsive semiconductor sensitizers. In this paper, we first synthesized bismuth vanadate(Bi VO4) quantum dots by employing facile successive ionic layer adsorption and reaction(SILAR) deposition technique, which we then used as a sensitizer for solar energy conversion. The preliminary optimised oxide SSSC showed an efficiency of 0.36%, nearly 2 orders of magnitude enhancement compared with bare Ti O2, due to the narrow bandgap absorption of Bi VO4 quantum dots and intimate contact with the oxide substrate. This result not only demonstrates a simple method to prepare Bi VO4 quantum dots based solar cells, but also provides important insights into the low bandgap oxide SSSCs.展开更多
The performance of dye-sensitized solar cells(DSCs) could be improved by using rationally designed mesoporous film structure for electron collection, dye adsorption and light scattering. The development of a novel dou...The performance of dye-sensitized solar cells(DSCs) could be improved by using rationally designed mesoporous film structure for electron collection, dye adsorption and light scattering. The development of a novel double layer film prepared by TiO_2 hierarchical submicrospheres and nanoparticles was reported in this article. The submicrospheres were composed of rutile nanorods of 10 nm diameter and the length of 150–250 nm, which facilitated fast electron transport, charge collection and light scattering. Using a double layer structure consisting of the 10 wt% film as a dye loading layer and the 50 wt% film as the light scattering layer, C101 sensitizer and liquid electrolyte, DSC yielded power conversion efficiency of 9.68% under 1 sun illumination.展开更多
基金supported by the National Key R&D Program of China(2019YFB1503200)the National Natural Science Foundation of China(52002105)+7 种基金the Key Research and Development Plan Project of Anhui Province(2022H11020014)the West Light Foundation of the Chinese Academy of Sciences(XAB2020YW11)the Collaborative Innovation Program of Hefei Science Center,CAS(2022HSC-CIP006)the Fundamental Research Funds for the Central Universities(JZ2021HGTB0105)the Hefei Institutes of Physical Science,Chinese Academy of Sciences Director’s Fund(YZJJ201902,YZJJZX202018)the Natural Science Foundation of Hebei Province(F2021208014)the Science and Technology Project of Hebei Education Department(QN2021063)the Science and Technology Research Project for the Colleges and Universities in Hebei Province(QN2022034)。
文摘The interface is crucial for perovskite solar cells(PSCs).However,voids at interfaces induced by the trapped hygroscopic dimethyl sulfoxide(DMSO)can reduce charge extraction and accelerate the film degradation,seriously damaging the efficiency and stability.In this work,4,4’-dinonyl-2,2’-dipyridine(DN-DP),a Lewis base with long alkyl chains is introduced to solve this problem.Theoretical calculated and experimental results confirm that the dipyridyl group on DN-DP can more strongly coordinate with Pb^(2+)than that of the S=O group on DMSO.The strong coordination effect plays a crucial role in removing the DMSO-based adduct and reducing the formation of voids.Due to the electron-donating properties of pyridine,the existence of DN-DP in the perovskite film can passivate the defects and optimize the energy level alignment of the perovskite configuration.The open-circuit voltage(VOC)of the DN-DP-based PSC is improved from 1.107 V(control device)to 1.153 V,giving rise to a power conversion efficiency(PCE)of24.02%.Furthermore,benefiting from the moisture resistance stemming from the hydrophobic nonyl group,the PCE retains 90.4%of the initial performance after 1000 h of storage in the ambient condition.
基金supported by the National Key Research and Development Program of China (2017YFE0133800)the National Natural Science Foundation of China (51961165106)+1 种基金the West Light Foundation of the Chinese Academy of Sciences(XAB2020YW11)European Union’s HORIZON 2020 Marie Curie Innovative Training Network 764787 MAESTRO project。
文摘Air moisture is the key issue for perovskites which invades the films and accelerates the damage of devices. Here, polyvinylpyrrolidone(PVP) is introduced to the methylammonium lead iodide(MAPbI_(3)) perovskite precursor to control crystal growth and endow the devices with self-healing ability in a moisture environment. The strong C=O...ΗAΝ hydrogen bonding interactions between PVP and MAPbI_(3) was confirmed by nuclear magnetic resonance measurements. By introducing hydrogen bonding in the MAPbI_(3)-based PSCs, we form a compact perovskite film of excellent electronic quality with a power conversion efficiency(PCE) of up to 20.32%. Furthermore, the O...ΗAΝ hydrogen bonding interactions at the grain boundaries suppress the decomposition of methylammonium cations and improve the recyclable dissolution–recrystallization of perovskite. As a result, the MAPbI_(3)-PVP based cells exhibited striking moisture stability and self-healing behavior, with negligible decay in efficiency after 500 h of operation in high humidity(65% ± 5% relative humidity) and rapid recovering ability after their removal from the humid environment.
基金supported by the Hefei Institutes of Physical Science,the Chinese Academy of Sciences Director’s Fund(grant nos.YZJJ201902 and YZJJZX202018)the National Natural Science Foundation of China(grant no.52002105)+5 种基金the Key Research and Development Plan Project of Anhui Province(grant no.2022H11020014)the West Light Foundation of the Chinese Academy of Sciences(grant no.XAB2020YW11)the collaborative Innovation Program of Hefei Science Center,CAS(grant no.2022HSC-CIP006)the Natural Science Foundation of Hebei Province(grant no.F2021208014)the Science and Technology Project of Hebei Education Department(grant no.QN2021063)the Science and Technology Research Project for the Colleges and Universities in Hebei Province(grant no.QN2022034).
文摘The electrochemical energy storage performance is greatly determined by the charge transfer and ion transportation occurring in the electrode materials.Therefore,the enhancement of electric conductivity and ionic mobility is vital for high-performing and stable metal ion batteries.Here,we report the properties of oxygen vacancies(VO)and carbon co-doped TiO_(2) hollow spheres(HS-TiO_(2))and compared them with fully oxidized white TiO_(2) hollow spheres(W-TiO_(2)).Theoretical calculations and experimental results revealed that the introduction of carbon dopant and VO in anatase TiO_(2) reduced the bandgap and the existence of localized electrons,leading to a lower migration barrier of Li ions that promoted faster ion diffusion kinetics,enabling the HS-TiO_(2) with higher reversibility during the insertion and extraction of Li ions than the W-TiO_(2).This HS-TiO_(2) delivered superior lithium storage properties with a specific discharge capacity of 214.6 mAh g^(-1) for the 100th cycle at 200 mA g^(-1) and 116.3 mAh g^(-1) over 2000 cycles at a high rate of 2 A g^(-1).
基金This work was supported by National Natural Science Foundation of China(NSFC)(Nos.10979031,20921001,and 90606006)the“973”State Key Project(No.2006CB932303)and the China Postdoctoral Science Foundation(No.20080440361).
文摘CO oxidation has been performed on Co_(3)O_(4) nanobelts and nanocubes as model catalysts.The Co_(3)O_(4) nanobelts which have a predominance of exposed{011}planes are more active than Co_(3)O_(4) nanocubes with exposed{001}planes.Temperature programmed reduction of CO shows that Co_(3)O_(4) nanobelts have stronger reducing properties than Co_(3)O_(4) nanocubes.The essence of shape and crystal plane effect is revealed by the fact that turnover frequency of Co3+sites of{011}planes on Co_(3)O_(4) nanobelts is far higher than that of{001}planes on Co_(3)O_(4) nanocubes.
基金We acknowledge the Steady High Magnetic Field Facility in High Magnetic Field Laboratory, Chinese Academy of Sciences for the EPR measurement. This work was supported by the National Natural Science Foundation of China (Nos. 21173228 and 61204075), and the National High-Tech Research and Development Program of China (No. 2015AA050602).
基金This work was supported by the National High-tech R&D Program of China (No. 2015AA050602), the External Cooperation Program of BIC, Chinese Academy of Sciences (No. GJHZ1607), the National Natural Science Foundation of China (Nos. U1205112, 51572080 and 21273242) and Natural Science Foundation of Anhui Province (No. 1508085SMF224).
基金supported by the National Basic Research Program of China(2011CBA00700)the National High Technology Research and Development Program of China(2011AA050527)the National Natural Science Foundation of China(21403247,21173228,21103197)
文摘Semiconductor sensitized solar cells(SSSCs) are promising candidates for the third generation of cost-effective photovoltaic solar cells and it is important to develop a group of robust, environment-friendly and visible-light-responsive semiconductor sensitizers. In this paper, we first synthesized bismuth vanadate(Bi VO4) quantum dots by employing facile successive ionic layer adsorption and reaction(SILAR) deposition technique, which we then used as a sensitizer for solar energy conversion. The preliminary optimised oxide SSSC showed an efficiency of 0.36%, nearly 2 orders of magnitude enhancement compared with bare Ti O2, due to the narrow bandgap absorption of Bi VO4 quantum dots and intimate contact with the oxide substrate. This result not only demonstrates a simple method to prepare Bi VO4 quantum dots based solar cells, but also provides important insights into the low bandgap oxide SSSCs.
基金supported by the External Cooperation Program of BIC, Chinese Academy of Sciences (GJHZ1607)the National Natural Science Foundation of China (51572080, 21403262)+1 种基金Zhejiang Provincial Natural Science Foundation of China (LR16F040002)International S&T Cooperation Program of Ningbo (2015D10021)
文摘The performance of dye-sensitized solar cells(DSCs) could be improved by using rationally designed mesoporous film structure for electron collection, dye adsorption and light scattering. The development of a novel double layer film prepared by TiO_2 hierarchical submicrospheres and nanoparticles was reported in this article. The submicrospheres were composed of rutile nanorods of 10 nm diameter and the length of 150–250 nm, which facilitated fast electron transport, charge collection and light scattering. Using a double layer structure consisting of the 10 wt% film as a dye loading layer and the 50 wt% film as the light scattering layer, C101 sensitizer and liquid electrolyte, DSC yielded power conversion efficiency of 9.68% under 1 sun illumination.