Amorphous （Nd,Pr）13Fe80Nb1B6 ribbons were crystallized at 670-730°C for 5-25 min to study the effects of isothermal crystallization on their behavior and magnetic properties. XRD results indicate that the isoth...Amorphous （Nd,Pr）13Fe80Nb1B6 ribbons were crystallized at 670-730°C for 5-25 min to study the effects of isothermal crystallization on their behavior and magnetic properties. XRD results indicate that the isothermal incubation time is 12, 5, and less than 5 min at 670, 700, and 730°C, respectively. High coercivities, with the maximum value of iHc = 1616 kA/m at 700°C for 19 min, measured by a physical property measurement system, are obtained in the crystallized ribbons. This is mainly attributed to the addition of Pr and Nb, because Pr2Fe14B has a higher anisotropic field than Nd2Fe14B, and Nb enriched in the grain boundary regions can not only reduce the exchange-coupling effects among hard grains, but also impede grain growth during the crystallization process. In addition, it should also be related to the characteristics of the furnace that the authors designed.展开更多
The effect of Cu addition on crystallization behavior and soft magnetic properties of Fe 84xP10C6 Cux (x= 0 1.15) alloys was investigated. Low-cost FePCCu nanocrystalline alloys dispersed with α-Fe phase with an aver...The effect of Cu addition on crystallization behavior and soft magnetic properties of Fe 84xP10C6 Cux (x= 0 1.15) alloys was investigated. Low-cost FePCCu nanocrystalline alloys dispersed with α-Fe phase with an average grain size of 15-35nm were obtained by appropriately annealing the melt-spun ribbons at 683K for 5min. The Fe 83.25P10C6Cu0.75 nanocrystalline alloy exhibits a high B s of 1.65T, low H c of 3.3A/m and high eat 1kHz of21 100, which is superior to the traditional FePC soft magnetic alloys. The core loss is as low as 0.32W/kg at1.0 T and 50Hz, which is 60% that of nonoriented Fe 6.5 mass% Si-steel. It is encouraging to synthesize this Fe-based nanocrystalline alloy with excellent soft-magnetic properties even using commercially industry-grade raw materials, which is promising for the future industrial applications.展开更多
A novel poly（ether sulfone） with oligoaniline pendants（PESOP） was prepared by KaCO3-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry（FTIR）, 1H nuclear magneti...A novel poly（ether sulfone） with oligoaniline pendants（PESOP） was prepared by KaCO3-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry（FTIR）, 1H nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）. The cyclic voltammetry（CV） curve of PESOP reveals the reversible electroactivity. In the electrochromism study, PESOP film exhibited good electroch- romic properties with a high contrast value, moderate switching time and acceptable coloration efficiency. After running 1000 cycles, the PESOP/indium-tin oxide（ITO） electrochromic device remained unchanged except for the drifting of base line, which certified its good electro-photo stability of the fabricated electrochromic device. Moreover, the polarization technique and electrochemical impedance spectroscopy（EIS） were used to study the anticorrosion performance of PESOP coatings on the cold rolled steel（CRS） in a 5%（mass fraction） NaCI solution. All the results indicate that the obtained PESOP is a competitive candidate as anticorrosion material.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.50801039and11074227)Natural Science Foundation of Zhejiang Province(No.Y4090022),Ningbo City(No.2012A610054)K.C.Wong Magna Fund in Ningbo University
基金supported by the National Natural Science Foundation of China (No. 50744014)the National Basic Research Foundation (No. 2004CCA04000)+3 种基金Science and Technology Department of Zhejiang Province (Nos. 2008C21046 and 2008C11086-1)the Natural Science Foundation of Zhejiang Province,China (No. Y406389)the Research and Development Program of Ningbo Bureau of Science and Technology (No. 2006B100054)K.C.Wong Magna Found in Ningbo University
文摘Amorphous （Nd,Pr）13Fe80Nb1B6 ribbons were crystallized at 670-730°C for 5-25 min to study the effects of isothermal crystallization on their behavior and magnetic properties. XRD results indicate that the isothermal incubation time is 12, 5, and less than 5 min at 670, 700, and 730°C, respectively. High coercivities, with the maximum value of iHc = 1616 kA/m at 700°C for 19 min, measured by a physical property measurement system, are obtained in the crystallized ribbons. This is mainly attributed to the addition of Pr and Nb, because Pr2Fe14B has a higher anisotropic field than Nd2Fe14B, and Nb enriched in the grain boundary regions can not only reduce the exchange-coupling effects among hard grains, but also impede grain growth during the crystallization process. In addition, it should also be related to the characteristics of the furnace that the authors designed.
基金supported by the National High Technology Research and Development Program of China ("863" Program) (Grant No.2009AA03Z214)the National Science Fund of China for Distinguished Young Scholars (Grant No. 50825103)+1 种基金the National Natural Science Foundation of China (Grant No. 51001112)the "Hundred of Talents Program" (Grant No. KGCX-2-YW-803) by Chinese Academy of Sciences
文摘The effect of Cu addition on crystallization behavior and soft magnetic properties of Fe 84xP10C6 Cux (x= 0 1.15) alloys was investigated. Low-cost FePCCu nanocrystalline alloys dispersed with α-Fe phase with an average grain size of 15-35nm were obtained by appropriately annealing the melt-spun ribbons at 683K for 5min. The Fe 83.25P10C6Cu0.75 nanocrystalline alloy exhibits a high B s of 1.65T, low H c of 3.3A/m and high eat 1kHz of21 100, which is superior to the traditional FePC soft magnetic alloys. The core loss is as low as 0.32W/kg at1.0 T and 50Hz, which is 60% that of nonoriented Fe 6.5 mass% Si-steel. It is encouraging to synthesize this Fe-based nanocrystalline alloy with excellent soft-magnetic properties even using commercially industry-grade raw materials, which is promising for the future industrial applications.
基金Supported by the National Natural Science Foundation of China（No.21104024）, the Jilin Province Science and Technology Department Project, China（No.20130522139JH）, the Functional Research Funds for the Central Universities, China（No. JCKY-QKJC07） and the Open Project of State Key Laboratory of Superhard Materials（Jilin University）, China（No.201403）.
文摘A novel poly（ether sulfone） with oligoaniline pendants（PESOP） was prepared by KaCO3-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry（FTIR）, 1H nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）. The cyclic voltammetry（CV） curve of PESOP reveals the reversible electroactivity. In the electrochromism study, PESOP film exhibited good electroch- romic properties with a high contrast value, moderate switching time and acceptable coloration efficiency. After running 1000 cycles, the PESOP/indium-tin oxide（ITO） electrochromic device remained unchanged except for the drifting of base line, which certified its good electro-photo stability of the fabricated electrochromic device. Moreover, the polarization technique and electrochemical impedance spectroscopy（EIS） were used to study the anticorrosion performance of PESOP coatings on the cold rolled steel（CRS） in a 5%（mass fraction） NaCI solution. All the results indicate that the obtained PESOP is a competitive candidate as anticorrosion material.
