The rate performance of inertial guidance test equipment (IGTE) affects the performance testing of inertia devices and navigation systems. Periodic rate ripples caused by periodic disturbances have a great effect on t...The rate performance of inertial guidance test equipment (IGTE) affects the performance testing of inertia devices and navigation systems. Periodic rate ripples caused by periodic disturbances have a great effect on the rate performance of rotation test tables. The mechanism caused by the rate ripple in IGTE is analyzed. Based on the nonlinear self-adaptive control system approach, a control system scheme is proposed to eliminate the period disturbances for its uncertainty. Experimental results show that the periodic rate ripple can efficiently be controlled.展开更多
Many attempts have been made to control the regioselectivity for olefin poly- merization by varying the structures of ligands in catalysts. The regioselectivity of propylene polymerization was investigated by replacin...Many attempts have been made to control the regioselectivity for olefin poly- merization by varying the structures of ligands in catalysts. The regioselectivity of propylene polymerization was investigated by replacing a nitrogen atom in the Pd(II) diimine catalyst with an oxygen atom from density functional theory method at the B3LYP/LANL2DZ level. The results show that the 1,2-insertion becomes a rival mechanism to the 2,1-insertion when the nitrogen atom is replaced by the oxygen atom leading to an asymmetric environment in the catalyst, and that the steric effect in the asymmetrical catalyst plays an important part in the polymerization. The insertion barrier from 2-O is much higher than that from 2-N. A pyramid transition state was characterized for the catalyst to convert 2-O back to 2-N through internal rotation. The propylene prefers to coordinate at the opposite side of O in the catalyst. This is the driving force for the internal rotation. The results are significant for isotactic and syndiotactic polymerization.展开更多
Technical progress in the field of conversion of methanol into ethylene and propylene over the ZSM-5 catalyst was summarized. The economical analysis of the technology, the mechanism of chemical reaction and reaction ...Technical progress in the field of conversion of methanol into ethylene and propylene over the ZSM-5 catalyst was summarized. The economical analysis of the technology, the mechanism of chemical reaction and reaction kinetics were introduced. The factors including the effect of the operating conditions,the influence of catalyst preparation conditions and modification of ZSM-5 zeolite on the reaction and coke formation were also discussed.展开更多
文摘The rate performance of inertial guidance test equipment (IGTE) affects the performance testing of inertia devices and navigation systems. Periodic rate ripples caused by periodic disturbances have a great effect on the rate performance of rotation test tables. The mechanism caused by the rate ripple in IGTE is analyzed. Based on the nonlinear self-adaptive control system approach, a control system scheme is proposed to eliminate the period disturbances for its uncertainty. Experimental results show that the periodic rate ripple can efficiently be controlled.
基金This work was supported by the Natural Science Foundation of Heilongjiang Province (No. B0313) and Research Foundation of China University of Mining and Technology
文摘Many attempts have been made to control the regioselectivity for olefin poly- merization by varying the structures of ligands in catalysts. The regioselectivity of propylene polymerization was investigated by replacing a nitrogen atom in the Pd(II) diimine catalyst with an oxygen atom from density functional theory method at the B3LYP/LANL2DZ level. The results show that the 1,2-insertion becomes a rival mechanism to the 2,1-insertion when the nitrogen atom is replaced by the oxygen atom leading to an asymmetric environment in the catalyst, and that the steric effect in the asymmetrical catalyst plays an important part in the polymerization. The insertion barrier from 2-O is much higher than that from 2-N. A pyramid transition state was characterized for the catalyst to convert 2-O back to 2-N through internal rotation. The propylene prefers to coordinate at the opposite side of O in the catalyst. This is the driving force for the internal rotation. The results are significant for isotactic and syndiotactic polymerization.
文摘Technical progress in the field of conversion of methanol into ethylene and propylene over the ZSM-5 catalyst was summarized. The economical analysis of the technology, the mechanism of chemical reaction and reaction kinetics were introduced. The factors including the effect of the operating conditions,the influence of catalyst preparation conditions and modification of ZSM-5 zeolite on the reaction and coke formation were also discussed.
