Micro-structural evolution and their effects on physical properties in different types of tectonically deformed coals

The macromolecular structure of tectonically deformed coals(TDC)may be determined by the deformation mechanisms of coal.Alterations of the macromolecular structure change the pore structure of TDC and thereby impact physical properties such as porosity and permeability.This study focuses on structure and properties of TDC from the Huaibei and Huainan coal mining areas of southern North China.Relationships between the macromolecular structure and the pore structure of TDC were analyzed using techniques such as X-ray diffraction,high-resolution transmission electron microcopy,and the low-temperature nitrogen adsorption.The results indicated that the directional stress condition can cause the arrangement of basic structural units(BSU)more serious and closer.And,the orientation is stronger in ductile deformed coal than in brittle deformed coal.Tectonic deformation directly influences the macromolecular structure of coal and consequently results in dynamic metamorphism.Because the size of BSU in brittle deformed coal increases more slowly than in ductile deformed coal,frictional heating and stress-chemistry of shearing areas might play a more important role,locally altering coal structure under stress,in brittle deformed coal.Strain energy is more significant in increasing the ductile deformation of coal.Furthermore,mesopores account for larger percentage of the nano-scale pore volume in brittle deformed coals,while mesopores volume in ductile deformed coal diminishes rapidly along with an increase in the proportion of micropores and sub-micropores.This research also approved that the deformations of macromolecular structures change nano-scale pore structures,which are very important for gas adsorption and pervasion space for gas.Therefore,the exploration and development potential of coal bed methane is promising for reservoirs that are subjected to a certain degree of brittle deformation(such as schistose structure coal,mortar structure coal and cataclastic structure coal).It also holds promise for TDC resulting from wrinkle structure coal of low ductile deformation and later superimposed by brittle deformation.Other kinds of TDC suffering from strong brittle-ductile and ductile deformation,such as scale structure coal and mylonitic structure coal,are difficult problems to resolve.

A New Parameter as an Indicator of the Degree of Deformation of Coals

The deformation of coal is effected by thermal effect, pressures and tectonic stress, and the tectonic stress is the principal influence factor. However, the proposition of a useful quantitative index that responds to the degree of deformation of coals quantitatively or semi-quantitatively has been a long-debated issue. The vitrinite reflectance ellipsoid, that is, the reflectance indication surface（RIS） ellipsoid is considered to be a strain ellipsoid that reflects the sum of the strain increment caused by stress in the process of coalification. It has been used to describe the degree of deformation of the coal, but the effect of the anisotropy on the RIS ellipsoid has not yet been considered with regards to non-structural factors. In this paper, Wei＇s parameter（ε） is proposed to express the deformation degree of the strain ellipsoid based on considering the combined influence of thermal effect, pressure and tectonic stress. The equation is as follows： ε=√[（ε_1-ε_0）~2＋（ε_2-ε_0）~2＋（ε_3-ε_0）~2]/3, where ε_1=lnR_（max）, ε_2=lnR_（int）, ε_3=lnR_（min）, and ε_0=（ε_1＋ε_2＋ε_3）/3. Wei＇s parameter represents the distance from the surface to the spindle of the RIS logarithm ellipsoid; thus, the degree of deformation of the strain ellipsoid is indicated quantitatively. The formula itself, meanwhile, represents the absolute value of the degree of relative deformation and is consequently suitable for any type of deformation of the strain ellipsoid. Wei＇s parameter makes it possible to compare degrees of deformation among different deformation types of the strain ellipsoid. This equation has been tested in four types of coal： highly metamorphic but weakly deformed coal of the southern Qinshui Basin, highly metamorphic and strongly deformed coal from the Tianhushan coal mining area of Fujian, and medium metamorphic and weakly or strongly deformed coal from the Huaibei Coalfield. The results of Wei＇s parameters are consistent with the actual deformation degrees of the coal reservoirs determined by other methods, which supports the effectiveness of this method. In addition, Wei＇s parameter is an important complement to the indicators of the degrees of deformation of coals, which possess certain theoretical significance and practical values.