Introduction Nitrites,as a powerful kind of oxidizing agent,can oxidize ferrous ions(Fe^(2+))to ferric ions(Fe^(3+)),triggering the conversion of normal hemoglobin(Hb)to methemoglobin(MetHb),which loses its ability to...Introduction Nitrites,as a powerful kind of oxidizing agent,can oxidize ferrous ions(Fe^(2+))to ferric ions(Fe^(3+)),triggering the conversion of normal hemoglobin(Hb)to methemoglobin(MetHb),which loses its ability to carry oxygen,resulting in hypoxia in tissues and death in severe cases.展开更多
Photoinduced electron transfer process is a crucial step in photooxidation to obtain synthetic chemicals. How- ever, the driving forces of electron transfer as priority in all have been rarely studied in stepwise deta...Photoinduced electron transfer process is a crucial step in photooxidation to obtain synthetic chemicals. How- ever, the driving forces of electron transfer as priority in all have been rarely studied in stepwise detail. Herein, we report a series of BODIPY derivatives with an emphasis on the intramolecular charge transfer, enhancing the key step of photoinduced electron transfer process and photooxidation performances. A series of novel BODIPY photosensitizers （B-1--B-5） were prepared, wherein diethylamine amino of B-3 as charge injection group was conjugated to the 2,6-diiodo-styryl-BODIPY, and the electron transfer impetus was enhanced 1.6 times due to its more negative redox potentials. These results were also confirmed by the DFT/TDDFT calculation. Without pure oxygen, B-3 still can exhibit an exceptional performance in photoxidative aromatization of 1,4-DHP under mild condition. After irradiation for 28 rain, the conversion rate came to 98.2%.展开更多
基金supported by the Fundamental Research Funds for the Central Universities (grant number:2042022kf1096).
文摘Introduction Nitrites,as a powerful kind of oxidizing agent,can oxidize ferrous ions(Fe^(2+))to ferric ions(Fe^(3+)),triggering the conversion of normal hemoglobin(Hb)to methemoglobin(MetHb),which loses its ability to carry oxygen,resulting in hypoxia in tissues and death in severe cases.
基金We thank the support of National Natural Science Foundation of China （Grant 21302224, 51172285, 21176259, 51303212, 51303202）, China Postdoctoral Science Foundation （2014M560590, 2015T80758）, Fundamental Research Funds for the Central Universities （15CX05010A）, Shandong Provincial Natural Science Foundation （ZR2013BQ028, ZR2013EMQ013）, Project of Science and Technology Program for Basic Research of Qingdao （14-2-4-47-jch） and the State Key Laboratory of Fine Chemicals （KF 1203）.
文摘Photoinduced electron transfer process is a crucial step in photooxidation to obtain synthetic chemicals. How- ever, the driving forces of electron transfer as priority in all have been rarely studied in stepwise detail. Herein, we report a series of BODIPY derivatives with an emphasis on the intramolecular charge transfer, enhancing the key step of photoinduced electron transfer process and photooxidation performances. A series of novel BODIPY photosensitizers （B-1--B-5） were prepared, wherein diethylamine amino of B-3 as charge injection group was conjugated to the 2,6-diiodo-styryl-BODIPY, and the electron transfer impetus was enhanced 1.6 times due to its more negative redox potentials. These results were also confirmed by the DFT/TDDFT calculation. Without pure oxygen, B-3 still can exhibit an exceptional performance in photoxidative aromatization of 1,4-DHP under mild condition. After irradiation for 28 rain, the conversion rate came to 98.2%.
