A series of aromatic imines were reduced to corresponding amines in excellent yields by 2-phenyl-N. N-dimethylbenzimidazoline (PDMBI) photochemically in the presence of magnesium perchloride (Mg(ClO4)(2)). A Mg2+ medi...A series of aromatic imines were reduced to corresponding amines in excellent yields by 2-phenyl-N. N-dimethylbenzimidazoline (PDMBI) photochemically in the presence of magnesium perchloride (Mg(ClO4)(2)). A Mg2+ mediated photoinduced electron transfer mechanism was proposed.展开更多
A photochemical desilylation reaction with nearly quantilative yield and excellent selectivity between silyl alkyl ether and silyl enol ether is reported.
基金The authors thank the National Natural Science Foundation of China (Grant No. 29972018) for financial support.
文摘A series of aromatic imines were reduced to corresponding amines in excellent yields by 2-phenyl-N. N-dimethylbenzimidazoline (PDMBI) photochemically in the presence of magnesium perchloride (Mg(ClO4)(2)). A Mg2+ mediated photoinduced electron transfer mechanism was proposed.
基金the National Natural Science Foundation of China (Grant No. 29972018) for financial support.
文摘A photochemical desilylation reaction with nearly quantilative yield and excellent selectivity between silyl alkyl ether and silyl enol ether is reported.
