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高强度银纳米线/聚丙烯酰胺复合水凝胶的制备及导电性能研究 被引量:4
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作者 丁晶晶 剧芳 +2 位作者 刘春华 唐龙祥 朱元元 《高分子学报》 SCIE CAS CSCD 北大核心 2022年第8期942-951,共10页
近年来,导电水凝胶作为一种功能聚合物软材料在柔性电子器件领域显示出广泛的应用前景,因此发展高强度导电水凝胶的合成方法在基础和应用研究中均具有重要的价值.本文提出了一种制备高强度导电水凝胶的简便方法,利用银-硫配位作用实现... 近年来,导电水凝胶作为一种功能聚合物软材料在柔性电子器件领域显示出广泛的应用前景,因此发展高强度导电水凝胶的合成方法在基础和应用研究中均具有重要的价值.本文提出了一种制备高强度导电水凝胶的简便方法,利用银-硫配位作用实现一维银纳米线(AgNWs)与含硫有机聚合物的有效复合,在提高水凝胶强度的同时,赋予其高的导电性.具体制备步骤如下:首先通过1-烯丙氧基-2,3-环硫丙烷的开环聚合得到侧基带乙烯基的线性聚硫醚(P1),通过巯-烯click反应引入足够量的羧基,赋予其水溶性.修饰后的线性聚硫醚(P2)与一维AgNWs通过银-硫配位作用制备复合交联剂(AgNWs@P2).该交联剂与丙烯酰胺(Am)单体以过硫酸钾(KPS)为引发剂,在水溶液中进行自由基聚合制备银纳米线/聚丙烯酰胺复合水凝胶(AgNWs/PAm composite hydrogel, AC gel).高分辨场发射扫描电子显微镜的测试证实,AgNWs与P2在水凝胶中实现了纳米尺寸上的复合.刚性AgNWs的引入赋予水凝胶优异的力学强度,其拉伸应变和断裂强度可达到~4500%和~2.2 MPa.该水凝胶具有高导电性(σ=0.44 S/m),且在拉伸过程中,电阻变化与水凝胶的形变线性相关,具有很好的循环稳定性.该水凝胶材料表现出的稳定电阻响应能力为新一代柔性电子器件的发展提供了材料基础. 展开更多
关键词 水凝胶 银硫配位 纳米复合 导电
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Sedimentary environment and model for lacustrine organic matter enrichment:lacustrine shale of the Early Jurassic Da’anzhai Formation,central Sichuan Basin,China 被引量:3
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作者 Zheng-Lu Xiao Shi-Jia Chen +8 位作者 Shao-Ming Zhang Rui Zhang Zhi-Yong Zhu Jun-Gang Lu Yong Li Xiang-Dong Yin long-xiang tang Zhang-Hao Liu Zong-Hui Lin 《Journal of Palaeogeography》 SCIE CSCD 2021年第4期584-601,共18页
Based on the analysis of element geochemistry and total organic carbon(TOC),this study investigates the main factors controlling organic matter(OM)enrichment,reconstructs the evolution process of the sedimentary envir... Based on the analysis of element geochemistry and total organic carbon(TOC),this study investigates the main factors controlling organic matter(OM)enrichment,reconstructs the evolution process of the sedimentary environment,and proposes a dynamic OM enrichment model of the Jurassic Da’anzhai(D)Formation,Sichuan Basin.The results indicate that the Sichuan Basin was generally dominated by a warm and oxidizing sedimentary environment,but with some peculiarities,such as a hotter climate in the D1 member and more anoxic lake water in the D2a member.The sedimentary evolution of the Da’anzhai Formation can be divided into a fluctuating sedimentary stage,a stable sedimentary stage and a reef-building stage.The D2a member showed the strongest hypoxia,the weakest weathering,the largest amount of terrestrial inputs,and the highest TOC content.The TOC is positively correlated with reducing conditions and terrestrial inputs,negatively correlated with weathering.Based on these findings,it is suggested that the global climate in the Early Jurassic period had a complex regional effect and the global oceanic anoxic events of the Toarcian did not spread to the Sichuan Basin.Thus,the anoxic deep water,high terrestrial inputs,and weak weathering were conducive to rapid deposition and preservation of lacustrine OM. 展开更多
关键词 Lacustrine shale Early Jurassic Toarcian Organic matter enrichment model Da’anzhai Formation Sichuan Basin
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