To promote the application of edge com-puting in wireless blockchain networks,this paper presents a business ecosystem,where edge comput-ing is introduced to assist blockchain users in imple-menting the mining process...To promote the application of edge com-puting in wireless blockchain networks,this paper presents a business ecosystem,where edge comput-ing is introduced to assist blockchain users in imple-menting the mining process.This paper exploits re-source trading and miner competition to enable se-cure and efficient transactions in the presented busi-ness ecosystem.The resource trading problem is for-mulated as a Stackelberg game between miner candi-dates and edge computing servers,where computing,caching,and communication resources are jointly op-timized to maximize the potential profit.Partial of-floading is introduced to further enhance the system performance when compared with the existing work.We analyze the existence and uniqueness of the Nash equilibrium and Stackelberg equilibrium.Based on the optimization result,winners are selected from the set of miner candidates by bidding and constitute the mining network.Simulation results demonstrate that the proposal is able to improve the social welfare of blockchain miners,thus stimulating more blockchain users to join the mining network.展开更多
The two-dimensional electron gas(2DEG)generated at the LaAlO3/SrTiO3 interface has been in the focus of oxides re-search since its first discovery.Although oxygen vacancies play an important role in the generation of ...The two-dimensional electron gas(2DEG)generated at the LaAlO3/SrTiO3 interface has been in the focus of oxides re-search since its first discovery.Although oxygen vacancies play an important role in the generation of the insulator-to-metal transition of the SrTiO3 bare surface,their contribution at the LaAlO3/SrTiO3 interface remains unclear.In this work,we investigated a LaAlO3/SrTiO3 heterostructure with regional distribution of defect-based localized polar sites at the interface.Using static and time-resolved threshold photoemission electron microscopy,we prove that oxygen vacan-cies are induced near those polar sites,resulting in the increase of carrier density of the 2DEG states.In addition,oxy-gen-related surface states were uncovered,which we attributed to the release of lattice oxygen during the formation of oxygen vacancies.Such effects are mainly found spatially located around the defect sites at the buried interface,while other regions remain unaffected.Our results confirm that the itinerant electrons induced by oxygen vacancies can coex-ist with the charge transfer mechanism in the LaAlO3/SrTiO3 heterostructure,together leading to the formation of the metallic interface.These observations provide fundamental insights into the nature of LaAlO3/SrTiO3 interface based 2DEG and unique perspectives for potential applications.展开更多
Controlling the structure formation of molecules on surfaces is fundamental for creating molecular nanostructures with tailored properties and functionalities and relies on tuning the subtle balance between intermolec...Controlling the structure formation of molecules on surfaces is fundamental for creating molecular nanostructures with tailored properties and functionalities and relies on tuning the subtle balance between intermolecular and molecule-surface interactions.So far,however,reliable rules of design are largely lacking,preventing the controlled fabrication of self-assembled functional structures on surfaces.In addition,while so far many studies focused on varying the molecular building blocks,the impact of systematically adjusting the underlying substrate has been less frequently addressed.Here,we elucidate the potential of tailoring the mesoscopic island shape by tuning the interactions at the molecular level.As a model system,we have selected the molecule dimolybdenum tetraacetate on three prototypical surfaces,Cu(111),Au(111)and CaF2(111).While providing the same hexagonal geometry,compared to Cu(111),the lattice constants of Au(111)and CaF2(111)differ by a factor of 1.1 and 1.5,respectively.Our high-resolution scanning probe microscopy images reveal molecular-level information on the resulting islands and elucidate the molecular-level design principles for the observed mesoscopic island shapes.Our study demonstrates the capability to tailor the mesoscopic island shape by exclusively tuning the substrate lattice constant,in spite of the very different electronic structure of the substrates involved.This work provides insights for developing general design strategies for controlling molecular mesostructures on surfaces.展开更多
Thraustochytrids are a group of unicellular marine heterotrophic protists,and have long been known for their biotechnological potentials in producing squalene,polyunsaturated fatty acids(PUFAs)and other bioactive prod...Thraustochytrids are a group of unicellular marine heterotrophic protists,and have long been known for their biotechnological potentials in producing squalene,polyunsaturated fatty acids(PUFAs)and other bioactive products.There are less than a hundred known strains from diverse marine habitats.Therefore,the discovery of new strains from natural environments is still one of the major limitations for fully exploring this interesting group of marine protists.At present,numerous attempts have been made to study thraustochytrids,mainly focusing on isolating new strains,analyzing the diversity in specific marine habitats,and increasing the yield of bioactive substances.There is a lack of a systematic study of the culturable diversity,and cultivation strategies.This paper reviews the distribution and diversity of culturable thraustochytrids from a range of marine environments,and describes in detail the most commonly used isolation methods and the control of culture parameters.Furthermore,the perspective approaches of isolation and cultivation for the discovery of new strains are discussed.Finally,the future directions of novel marine thraustochytrid research are proposed.The ultimate goal is to promote the awareness of biotechnological potentials of culturable thraustochytrid strains in industrial and biomedical applications.展开更多
基金This work was supported by National Natural Science Foundation of China(No.62271368,No.62201421)National Natural Science Foundation of Shaanxi Province(No.2021JQ-206)+1 种基金Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110084)China Postdoctoral Science Foundation(No.2018M640960,No.2019T120879).
文摘To promote the application of edge com-puting in wireless blockchain networks,this paper presents a business ecosystem,where edge comput-ing is introduced to assist blockchain users in imple-menting the mining process.This paper exploits re-source trading and miner competition to enable se-cure and efficient transactions in the presented busi-ness ecosystem.The resource trading problem is for-mulated as a Stackelberg game between miner candi-dates and edge computing servers,where computing,caching,and communication resources are jointly op-timized to maximize the potential profit.Partial of-floading is introduced to further enhance the system performance when compared with the existing work.We analyze the existence and uniqueness of the Nash equilibrium and Stackelberg equilibrium.Based on the optimization result,winners are selected from the set of miner candidates by bidding and constitute the mining network.Simulation results demonstrate that the proposal is able to improve the social welfare of blockchain miners,thus stimulating more blockchain users to join the mining network.
基金supported by the National Key Research and Development Program of China under Grant Nos.2018YFB2200403 and 2018YFA0704404the National Natural Science Foundation of China under Grant Nos.61775003,11734001,91950204,11527901+1 种基金Beijing Municipal Science&Technology Commission No.Z191100007219001support by the Deutsche Forschungsgemeinschaft(DFG,German Research Foundation)-TRR 173-268565370(projects A02).
文摘The two-dimensional electron gas(2DEG)generated at the LaAlO3/SrTiO3 interface has been in the focus of oxides re-search since its first discovery.Although oxygen vacancies play an important role in the generation of the insulator-to-metal transition of the SrTiO3 bare surface,their contribution at the LaAlO3/SrTiO3 interface remains unclear.In this work,we investigated a LaAlO3/SrTiO3 heterostructure with regional distribution of defect-based localized polar sites at the interface.Using static and time-resolved threshold photoemission electron microscopy,we prove that oxygen vacan-cies are induced near those polar sites,resulting in the increase of carrier density of the 2DEG states.In addition,oxy-gen-related surface states were uncovered,which we attributed to the release of lattice oxygen during the formation of oxygen vacancies.Such effects are mainly found spatially located around the defect sites at the buried interface,while other regions remain unaffected.Our results confirm that the itinerant electrons induced by oxygen vacancies can coex-ist with the charge transfer mechanism in the LaAlO3/SrTiO3 heterostructure,together leading to the formation of the metallic interface.These observations provide fundamental insights into the nature of LaAlO3/SrTiO3 interface based 2DEG and unique perspectives for potential applications.
文摘Controlling the structure formation of molecules on surfaces is fundamental for creating molecular nanostructures with tailored properties and functionalities and relies on tuning the subtle balance between intermolecular and molecule-surface interactions.So far,however,reliable rules of design are largely lacking,preventing the controlled fabrication of self-assembled functional structures on surfaces.In addition,while so far many studies focused on varying the molecular building blocks,the impact of systematically adjusting the underlying substrate has been less frequently addressed.Here,we elucidate the potential of tailoring the mesoscopic island shape by tuning the interactions at the molecular level.As a model system,we have selected the molecule dimolybdenum tetraacetate on three prototypical surfaces,Cu(111),Au(111)and CaF2(111).While providing the same hexagonal geometry,compared to Cu(111),the lattice constants of Au(111)and CaF2(111)differ by a factor of 1.1 and 1.5,respectively.Our high-resolution scanning probe microscopy images reveal molecular-level information on the resulting islands and elucidate the molecular-level design principles for the observed mesoscopic island shapes.Our study demonstrates the capability to tailor the mesoscopic island shape by exclusively tuning the substrate lattice constant,in spite of the very different electronic structure of the substrates involved.This work provides insights for developing general design strategies for controlling molecular mesostructures on surfaces.
基金This work was partially supported by National Science Foundation of China[91751115(GW)and 31670044(GW)]Natural Science Foundation of Hebei Province[D2019204215(QW)].The views expressed herein are those of the authors,and do not represent the views of the funding agencies or any of its subagencies.
文摘Thraustochytrids are a group of unicellular marine heterotrophic protists,and have long been known for their biotechnological potentials in producing squalene,polyunsaturated fatty acids(PUFAs)and other bioactive products.There are less than a hundred known strains from diverse marine habitats.Therefore,the discovery of new strains from natural environments is still one of the major limitations for fully exploring this interesting group of marine protists.At present,numerous attempts have been made to study thraustochytrids,mainly focusing on isolating new strains,analyzing the diversity in specific marine habitats,and increasing the yield of bioactive substances.There is a lack of a systematic study of the culturable diversity,and cultivation strategies.This paper reviews the distribution and diversity of culturable thraustochytrids from a range of marine environments,and describes in detail the most commonly used isolation methods and the control of culture parameters.Furthermore,the perspective approaches of isolation and cultivation for the discovery of new strains are discussed.Finally,the future directions of novel marine thraustochytrid research are proposed.The ultimate goal is to promote the awareness of biotechnological potentials of culturable thraustochytrid strains in industrial and biomedical applications.