This work deals with the degradation of AZ31 and AZ91 magnesium alloys when they are exposed to three types of physiological media for seven days at 37°C:Ringer's,Hanks\and simulated body fluid(SBF)solutions....This work deals with the degradation of AZ31 and AZ91 magnesium alloys when they are exposed to three types of physiological media for seven days at 37°C:Ringer's,Hanks\and simulated body fluid(SBF)solutions.A combination of immersions tests and surface characterisation methods were employed to evaluate the attack on the surface,and the stability of the formed corrosion product layers for each alloy/electrolyte system.Measurements of the Mg-ion released into the electrolytes were also carried out in order to be correlated with the degradation of the alloys.Electrochemical impedance spectroscopy(EIS)and potentiodynamic polarisation(PDP)techniques were employed to compare the performance of the alloys in these different aggressive electrolytes.According to the obtained results,the Mg-alloys exposed to Hanks'media were the less affected,which fact was attributed to a higher stability of the corrosion products layer formed in this medium,in comparison of those formed in Ringer's and SBF solutions.In add让ion,the corrosion damage was lower for AZ91 than for AZ31 alloy in all environments due to its higher Al content.The mass loss rates calculated from both immersion tests and electrochemical methods followed the same trend for comparative purposes between alloys.展开更多
This work presents a simple method to functionalise the surface of AZ31 magnesium alloy by applying a duplex MgF_(2)/chitosan coating,which improves its corrosion resistance and provides it with some antibacterial per...This work presents a simple method to functionalise the surface of AZ31 magnesium alloy by applying a duplex MgF_(2)/chitosan coating,which improves its corrosion resistance and provides it with some antibacterial performance.First,the effect of three chitosan solutions with different concentrations on the growth of the bacteria Klebsiella pneumoniae in nutritive medium(TSB)was evaluated by absorbance kinetics experiments,where the chitosan solution at 2%(m/V)was selected for the coating preparation.Before coating application,the AZ31 substrate was pretreated with hydrofluoric acid for 48 hours in order to form a MgF_(2)conversion layer.Subsequently,the coating was applied to the pretreated substrate through the dry-casting method.Samples of the alloy in each surface condition(bare,pretreated,and pretreated+coated with chitosan)were exposed to simulated body fluid(SBF)for 21 days at 37°C,with the solution renewed every 24 hours and the wastes stored.The surfaces were characterised by SEM-EDS,and XPS after the immersion tests,whereas the stored solutions were employed to measure the change in the Mg-ions concentration.Electrochemical impedance spectroscopy and potentiodynamic polarisation were performed in each surface condition to compare their corrosion resistance in SBF.The antibacterial activity of the functionalised surfaces was evaluated by the plate counting method and compared with bare samples.All results were correlated and demonstrate that the modified surface of AZ31 achieved a higher corrosion resistance when it was exposed to SBF,as well as a reduction of the bacterial growth during in vitro tests.展开更多
文摘This work deals with the degradation of AZ31 and AZ91 magnesium alloys when they are exposed to three types of physiological media for seven days at 37°C:Ringer's,Hanks\and simulated body fluid(SBF)solutions.A combination of immersions tests and surface characterisation methods were employed to evaluate the attack on the surface,and the stability of the formed corrosion product layers for each alloy/electrolyte system.Measurements of the Mg-ion released into the electrolytes were also carried out in order to be correlated with the degradation of the alloys.Electrochemical impedance spectroscopy(EIS)and potentiodynamic polarisation(PDP)techniques were employed to compare the performance of the alloys in these different aggressive electrolytes.According to the obtained results,the Mg-alloys exposed to Hanks'media were the less affected,which fact was attributed to a higher stability of the corrosion products layer formed in this medium,in comparison of those formed in Ringer's and SBF solutions.In add让ion,the corrosion damage was lower for AZ91 than for AZ31 alloy in all environments due to its higher Al content.The mass loss rates calculated from both immersion tests and electrochemical methods followed the same trend for comparative purposes between alloys.
基金CONACYT for his scholarship as a Ph.D.student at CINVESTAV-IPN
文摘This work presents a simple method to functionalise the surface of AZ31 magnesium alloy by applying a duplex MgF_(2)/chitosan coating,which improves its corrosion resistance and provides it with some antibacterial performance.First,the effect of three chitosan solutions with different concentrations on the growth of the bacteria Klebsiella pneumoniae in nutritive medium(TSB)was evaluated by absorbance kinetics experiments,where the chitosan solution at 2%(m/V)was selected for the coating preparation.Before coating application,the AZ31 substrate was pretreated with hydrofluoric acid for 48 hours in order to form a MgF_(2)conversion layer.Subsequently,the coating was applied to the pretreated substrate through the dry-casting method.Samples of the alloy in each surface condition(bare,pretreated,and pretreated+coated with chitosan)were exposed to simulated body fluid(SBF)for 21 days at 37°C,with the solution renewed every 24 hours and the wastes stored.The surfaces were characterised by SEM-EDS,and XPS after the immersion tests,whereas the stored solutions were employed to measure the change in the Mg-ions concentration.Electrochemical impedance spectroscopy and potentiodynamic polarisation were performed in each surface condition to compare their corrosion resistance in SBF.The antibacterial activity of the functionalised surfaces was evaluated by the plate counting method and compared with bare samples.All results were correlated and demonstrate that the modified surface of AZ31 achieved a higher corrosion resistance when it was exposed to SBF,as well as a reduction of the bacterial growth during in vitro tests.
