Plasmonic metal‐organic frameworks are composite nanoparticles comprising plasmonic metal nanoparticles(NPs)embedded within a metalorganic framework(MOF)matrix.As a result,not only the functionalities of the individu...Plasmonic metal‐organic frameworks are composite nanoparticles comprising plasmonic metal nanoparticles(NPs)embedded within a metalorganic framework(MOF)matrix.As a result,not only the functionalities of the individual components are retained,but synergistic effects additionally provide improved chemical and physical properties.Recent progress in plasmonic MOFs has demonstrated the potential for nanofabrication and various nanotechnology applications.Synthetic challenges toward plasmonic MOFs have been recently addressed,resulting in new opportunities toward practical applications,such as surface‐enhanced Raman scattering,therapy,and catalysis.The impact of key parameters(thermodynamic vs.kinetic)on the synthetic pathways of plasmonic MOFs is reviewed,while providing insight into related progress toward structure‐derived applications.展开更多
基金ACKNO WLED GM ENTS G.Zheng acknowledges the National Natural Science Foundation of China(Grant Number:21902148)Financial support was also provided by the Spanish Ministerio de Ciencia e Innovacion(Grant No.PID2019-108954R to I Pastoriza-Santos and J.Perez-Juste+1 种基金Grants No.MAT2017-86659-R and MDM-2017-0720 to L.M.Liz-Marzan)EU Horizon 2020 research and innovation programme under grant agreement no.883390(SERSing).
文摘Plasmonic metal‐organic frameworks are composite nanoparticles comprising plasmonic metal nanoparticles(NPs)embedded within a metalorganic framework(MOF)matrix.As a result,not only the functionalities of the individual components are retained,but synergistic effects additionally provide improved chemical and physical properties.Recent progress in plasmonic MOFs has demonstrated the potential for nanofabrication and various nanotechnology applications.Synthetic challenges toward plasmonic MOFs have been recently addressed,resulting in new opportunities toward practical applications,such as surface‐enhanced Raman scattering,therapy,and catalysis.The impact of key parameters(thermodynamic vs.kinetic)on the synthetic pathways of plasmonic MOFs is reviewed,while providing insight into related progress toward structure‐derived applications.
