A safe and environmentally friendly cyaniding method has been developed to mitigate the toxic impacts of cyanide salts on the environment during conventional cyaniding. The method entails in-situ diffusion of nascent ...A safe and environmentally friendly cyaniding method has been developed to mitigate the toxic impacts of cyanide salts on the environment during conventional cyaniding. The method entails in-situ diffusion of nascent cyanide from mature cassava leaves into the surface of mild steel components via pack-cyaniding. Both high-temperature in-situ diffusion into austenite and low-temperature in-situ diffusion into ferrite were explored. Results from light and scanning electron microscopic studies showed that surface hardness of the steel components was substantially increased. The waste product was a harmless biodegradable organic compound that posed no disposal threats. This study is important for increasing the wear resistance of ferrous parts for a longer service life in application without polluting the environment.展开更多
This work reports a procedure for the fabrication of a complex mould using the technique of electroforming. This was with a view to finding a cheaper and less labour-intensive mould production route practicable locall...This work reports a procedure for the fabrication of a complex mould using the technique of electroforming. This was with a view to finding a cheaper and less labour-intensive mould production route practicable locally. A Plaster of Paris electroforming mandrel in the shape of a water bottle was produced and made electrically conducting with a layer of copper conducting paint. Considerations for electroform removal were made by applying a thin, chloroform-dissolvable epoxy layer beneath the conducting copper paint. Uniformity of deposition on the mandrel was accomplished with the construction of a special deposition bath with multiple copper anodes around its perimeter. The electroforming was done in the galvanostatic electro deposition mode for about 240 hrs in a 1 M Cu2SO4 bath with the deposition of elemental copper on the mandrel. Incidences of rising bath pH were mediated with concentrated H2SO4. A free-standing electroform representing the mould cavity was formed in the deposition. The product so formed was a reproduction of the net-shape of the mandrel exhibiting smooth surface finish. The electroforming was cast with an aluminum backing layer to complete its transformation into a split mould. The finished mould was comparable in appearance to the imported moulds in terms of appearance and reproduction of intricate surface patterns. The simplicity and low cost of this method significantly reduced the requirements for expensive instrumentation and highly skilled labour for mould production.展开更多
文摘A safe and environmentally friendly cyaniding method has been developed to mitigate the toxic impacts of cyanide salts on the environment during conventional cyaniding. The method entails in-situ diffusion of nascent cyanide from mature cassava leaves into the surface of mild steel components via pack-cyaniding. Both high-temperature in-situ diffusion into austenite and low-temperature in-situ diffusion into ferrite were explored. Results from light and scanning electron microscopic studies showed that surface hardness of the steel components was substantially increased. The waste product was a harmless biodegradable organic compound that posed no disposal threats. This study is important for increasing the wear resistance of ferrous parts for a longer service life in application without polluting the environment.
文摘This work reports a procedure for the fabrication of a complex mould using the technique of electroforming. This was with a view to finding a cheaper and less labour-intensive mould production route practicable locally. A Plaster of Paris electroforming mandrel in the shape of a water bottle was produced and made electrically conducting with a layer of copper conducting paint. Considerations for electroform removal were made by applying a thin, chloroform-dissolvable epoxy layer beneath the conducting copper paint. Uniformity of deposition on the mandrel was accomplished with the construction of a special deposition bath with multiple copper anodes around its perimeter. The electroforming was done in the galvanostatic electro deposition mode for about 240 hrs in a 1 M Cu2SO4 bath with the deposition of elemental copper on the mandrel. Incidences of rising bath pH were mediated with concentrated H2SO4. A free-standing electroform representing the mould cavity was formed in the deposition. The product so formed was a reproduction of the net-shape of the mandrel exhibiting smooth surface finish. The electroforming was cast with an aluminum backing layer to complete its transformation into a split mould. The finished mould was comparable in appearance to the imported moulds in terms of appearance and reproduction of intricate surface patterns. The simplicity and low cost of this method significantly reduced the requirements for expensive instrumentation and highly skilled labour for mould production.
